ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Since 1926 investigations of the Dushman reaction have relied mainly upon “constant-rate” measurements, usually by instrumental methods. Since about that time, the confusion surrounding this venerable reaction has been growing. In part, the confusion arises because the reaction involves reactive intermediate species that have not been studied directly - and may never be. Alternative detailed mechanisms have been assumed with little restraint. One of these, which is built around H2I2O3, has been explored by computer with promising results. The mechanism seems capable of reducing the confusion now attending the Dushman reaction and others related to it.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550110703
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