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  • 1
    Electronic Resource
    Electronic Resource
    High-resolution nmr study of yeast tRNACUALeu and the native and denatured conformers of yeast tRNAUUGLeuSubmitted by BFR in partial fulfillment of the requirements for the Ph.D. degree in chemistry at the University of California, Riverside. (1976)
    New York : Wiley-Blackwell
    Biopolymers 15 (1976), S. 325-336 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The high-resolution nmr spectrum of baker's yeast tRNACUALeu, a recently sequenced non-denaturable tRNA, has been compared with the spectra of the native and denatured conformers of the closely related species tRNAUUGLeu. Because of the presence of many common base pairs in the different tRNA's, it is possible to assign most of the low-field resonances to specific secondary-structure base pairs. A comparison of the observed positions of the various resonances with those predicted by a semiempirical ring-current shift theory shows a root-mean-square deviation of 0.14, 0.11, and 0.12 ppm for tRNAUUGLeu (native), and tRNAUUGLeu (denatured), respectively. These results support the ring-current shift theory currently used to interpret the low-field nmr spectra of the tRNA molecules. Differences between the predicted and observed positions of some resonances provide new evidence for higher order effects such as shifts from second nearest neighbors, anomalous shifts exerted by G·U base pairs, and tertiary-structure effects. A model that was previously proposed for the denatured conformer of tRNAUUGLeu is also supported.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1976.360150210
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  • 2
    Electronic Resource
    Electronic Resource
    Kinetics of the renaturation of yeast tRNA3Leu (1977)
    New York : Wiley-Blackwell
    Biopolymers 16 (1977), S. 1557-1566 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Yeast tRNA3Leu is one of several tRNA molecules which can adopt a stable, biologically inactive, denatured conformation. The circular dichroism of the native and denatured conformers differs, providing the basis for the present study of the mechanism for the renaturation process. Conversion of the denatured structure to the native takes place in two steps: a rapid change occurring immediately on addition of Mg++, followed by a slower, strongly temperature-dependent step which returns the molecule to its biologically active state. Optimal kinetic data for the second step could be obtained at 285 nm. Analysis of the time dependence of Δε285 by the Guggenheim method demonstrated that this step follows first-order kinetics. The temperature dependence of the rate constants over the range 32-41°C yielded the following parameters for the rate-limiting step: Ea = 69 kcal/mole, ΔH
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1977.360160714
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  • 3
    Electronic Resource
    Electronic Resource
    Finite element representation and pressure stiffness in shell stability analysis (1979)
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 14 (1979), S. 1413-1420 
    Details
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In the light of recent contributions by Batoz1 and Hibbitt,2 two aspects of finite element formulations for shell stability analysis are examined. The first is the consistency of the shell strain-displacement equations employed; the second is the proper representation of ‘follower forces’ - pressures that are always normal to the deforming surface. Numerical studies of an arch indicate that improper representation of either of these factors can have a significant effect on predicted buckling loads. Numerical studies of an arch indicate that improper representation of either of these factors can have a significant effect on predicted bukling loads.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/nme.1620140912
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  • 4
    Electronic Resource
    Electronic Resource
    Effectiveness of linear bifurcation analysis for predicting the nonlinear stability limits of structures (1986)
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 23 (1986), S. 831-846 
    Details
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: As an effort to predict effectively the actual collapse load of a structure, a series of numerical studies on the stability of shell structures are made. The difference in formulation between the two types of linear buckling loads, the classical and the fully linearized, is first demonstrated. Their correlations with respect to the actual stability limit of the structure are compared, and finally the two types of critical load approximations are obtained at various stages of a nonlinear analysis to study the pattern of convergence to the actual collapse load. It is found that the fully linearized buckling analysis, when combined with nonlinear analysis, can serve as a useful tool for prediction of the stability limit of a structure. While for most types of structures the approximation is within engineering accuracy, the rate of convergence of the extrapolated critical load also gives some insight to the accuracy of the approximation.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/nme.1620230506
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  • 5
    Electronic Resource
    Electronic Resource
    Heat capacities for atactic polystyrene of narrow molecular weight distribution to 360°K. (1968)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 6 (1968), S. 849-860 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Precise heat capacity values are reported over the temperature range from 10 to 360°K. for a sample of atactic polystyrene having a narrow molecular weight distribution. This sample was taken from the stock from which National Bureau of Standards Standard Sample 705, Narrow Molecular Weight Distribution Polystyrene, was established. Data are reported for the sample as received, and after an annealing procedure. At temperatures below about 60°K. a systematic difference comparable with the limits of experimental precision appears between the values obtained for the present sample as received and after the annealing, although at higher temperatures the values for the two conditions showed no systematic difference beyond the limits of precision of the measurements. At temperatures above 100°K., previously published values for atactic polystyrene samples of various molecular weight distributions and for isotactic polystyrene agree within about 0.5% of the values from this investigation. At temperatures below 100°K. significant heat capacity differences appear, especially between values for the atactic and the isotactic isomers, and even between atactic samples of different molecular weight distribution.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1968.160060505
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  • 6
    Electronic Resource
    Electronic Resource
    Polymerization of isobutylene by the adamantane bromide-diethylaluminum chloride catalyst system (1987)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 3127-3141 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Isobutylene has been polymerized in a continuous stirred tank reactor using a catalyst system comprised of 1-bromoadamantane and diethylaluminum chloride. The polymerization was carried out in hexane solvent at -15 to -27°C and gave 100% conversion to polyisobutylene (PIB) of 1000-3000 Mw. The results of pyrolysis-gas chromatography-mass spectrometry analyses are consistent with a mechanism involving the formation of the adamantyl cabocation and its addition to an isobutylene molecule to initiate polymerization. 13C-NMR analyses show that the PIB products contain R2C—CR2 and R2C—CHR olefin types. Information on the nature of these olefins and the route to their formation has been developed.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1987.080251116
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  • 7
    Electronic Resource
    Electronic Resource
    Letters to the editor (1986)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1405-1406 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690320830
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  • 8
    Electronic Resource
    Electronic Resource
    Copolyesters. I. Sequence distribution of poly(butylene terephthalate-co-adipate) copolyesters determined by 400 MHz NMR (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 40 (1990), S. 1053-1057 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1990.070400537
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  • 9
    Electronic Resource
    Electronic Resource
    Competitive adsorption of water-soluble polymers on attapulgite clay (1991)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 43 (1991), S. 1293-1299 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The individual, competitive, and displacement adsorption of polyvinyl alcohol (PVOH), hydroxyethyl cellulose (HEC), and hydroxypropylmethyl cellulose (HPMC) in aqueous solution onto an attapulgite clay has been systematically studied. For the individual adsorption experiments, the amount of polymer adsorbed at equilibrium decreased in the order PVOH, HEC, HPMC. In the competitive adsorption experiments, the adsorption level of each polymer is diminished by the presence of a competing polymeric species. Binary mixtures of a cellulosic polymer (HEC or HPMC) with PVOH result in a substantial reduction in the amount of cellulosic polymer adsorbed. In the displacement adsorption studies, the sequential addition of HEC or HPMC is not able to displace previously adsorbed PVOH molecules to any appreciable extent. However, the addition of PVOH to previously equilibrated HEC/clay or HPMC/clay suspensions results in a large amount of the adsorbed cellulosic polymer being displaced by PVOH, especially under conditions of high surface coverage. These results indicate that PVOH is preferentially adsorbed on the clay surface and the strength of attachment to the surface is greater for PVOH than for either cellulosic polymer.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1991.070430710
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  • 10
    Electronic Resource
    Electronic Resource
    Constancy of the shift-up point in two temperature-sensitive mammalian cell lines that arrest in G1This work was supported by USPHS Grant GM 22359 from the National Institute for General Medical Sciences. (1978)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Cellular Physiology 96 (1978), S. 15-21 
    Details
    ISSN: 0021-9541
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Two cell cycle-specific temperature sensitive (ts) mutants of mammalian cell lines, AF8 and K12, are known to arrest in G1 when shifted to the non-permissive temperature. We have determined the entry into S of both AF8 and K12 cells in five different growth conditions, namely: (1) quiescent sparse cultures stimulated to proliferate by serum; (2) quiescent dense cultures stimulated by serum; (3) quiescent sparse cultures stimulated by trypsinization and replating; (4) quiescent, dense cultures stimulated by trypsinization and replating; and (5) mitotic cells collected by mitotic detachment. In addition, for each cell line and for each different growth condition, we have determined the shift-up time, i.e., the time at which a shift-up to the nonpermissive temperature no longer prevents the entry of cells into S. In no case did K12 or AF8 enter S at the nonpermissive temperature. At the permissive temperature, the average time of entry into S varied in different growth conditions, and so did the shift-up time. However, in both cell lines, the distance of the average shift-up time from the average time of entry into S was remarkably constant, regardless of the growth conditions, i.e., 1.8 hours in K12 and 8.6 hours in AF8.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jcp.1040960103
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