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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 76 (1964), S. 794-794 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 81 (1969), S. 172-182 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Konformation der Aldosen in Lösung und die Zusammensetzung der Gleichgewichtsmischungen, die sich beim Lösen dieser Zucker in Wasser bilden, sind NMR-spektroskopisch bestimmt worden. Berechnungen auf der Basis nichtbindender Wechselwirkungen und des anomeren Effekts gestatten eine Erklärung der beobachteten Konformationen und eine approximative Vorhersage des α/β-Verhältnisses der Pyranosen im Gleichgewicht sowie des Ausmaßes der Anhydridbildung bei Zuckern in saurer Lösung. In manchen Fällen sind die Furanose- beständiger als die Pyranoseformen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 8 (1969), S. 157-166 
    ISSN: 0570-0833
    Keywords: Conformation of sugars ; Carbohydrates ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The conformations of the aldoses in solution, and the compositions of the equilibrium mixtures formed from aldoses after dissolution in water, have been determined by NMR spectroscopy. Calculations based on non-bonded interactions and on the anomeric effect account for the observed conformations, and allow an approximate prediction of the α:β ratio of pyranoses in equilibrium and of the extent of anhydride formation from sugars in acid solution. In certain circumstances the furanose forms are more stable than the pyranose forms.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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