ISSN:
0749-1581
Keywords:
Tin-tin coupling constants
;
Hyperconjugation
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Multinuclear NMR data (1 H, 13 C, 119 Sn) have been obtained for almost all possible isomers of the composition Me3Sn(C3Hm)SnMe3 (m = 2, 4, 6) and Me3Sn(C4Hn)SnMe3 (n = 0, 2, 4, 6, 8). The coupling constants xJ(Sn, Sn) (x = 4, 5) are not linearly related to the corresponding coupling constants xJ(H, H), but are particularly large when tin-carbon bonds can interact hyperconjugatively with carbon-carbon double or triple bonds.
Additional Material:
5 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260251010
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