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  • Chemistry  (2)
  • consolidation
  • Wiley-Blackwell  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 921-926 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Random walks are used to examine dispersion between miscible fluids in one-dimensional, prefractal porous medium. Mixing in such media is anomalous and several nonlocal theories have been proposed to describe this non-Fickian characteristic. This work simulates dispersion via a random walk in a prefractal media by incorporation local and spatially nonlocal effects and compares the results with laboratory experiments. Results suggest that nonlocal models fit experimental data better than local models.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 2112-2122 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The transport of moisture in shrinking food gels during drying is studied based on a novel thermomechanical theory accounting for a structural transition in the material - from the rubbery to the galssy state - during drying. The proposed theory is applied to the drying of a model cylindrical starch-gluten gel system. The predicted drying characteristics depend on the Deborah number, a ratio of the characteristic relaxation time to the characteristic diffusion time. At low Deborah numbers, drying is Fickian. At intermediate and high Deborah numbers, however, drying is non-Fickian, leading to an apparent mass-transfer shutdown, which is a result of surface dryout and skin/shell formation. Based on a time-dependent surface boundary condition, the model proposes that surface drying is not only a function of the Biot number but also a function of the “Shell” number, a ratio of the Deborah and Biot numbers. The model is verified by comparing its predictions with experimental data from drying of starch-gluten gels at 22.5 and 40°C. The model predictions agree with experimental data and capture the observed sigmoidal shape of the experimental drying curves in the saturated flow regime. The predicted moisture profiles show shell formation and growth during drying, compatible with the experimental moisture profiles from the literature.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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