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  • Chemistry  (2)
  • Numerical Methods and Modeling  (1)
  • Astrophysics
  • Wiley-Blackwell  (3)
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  • Wiley-Blackwell  (3)
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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 126 (1969), S. 73-86 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The synthesis of 4-vinylbiphenyl and 11-vinyl-p-terphenyl was performed by a simple synthetic route. By reaction of the corresponding alcohols with methanesulfonyl chloride in pyridine the vinyl compounds could be prepared by a one step reaction.Investigation of the radical copolymerisation of the monomers with styrene showed a favoured incorporation of 4-vinylbiphenyl and 12-vinyl-p-terphenyl into the polymer chain in contrast to the behaviour of 11-vinyl-p-terphenyl.
    Notes: Für die Darstellung von 4-Vinyldiphenyl und 11-Vinyl-p-terphenyl wurden einfache, verallgemeinerungsfähige Synthesen ausgearbeitet. Durch Umsetzung entsprechender Carbinole mit Methansulfonsäurechlorid in Pyridin gelang die Darstellung der Vinylverbindungen in einer einstufigen Reaktion.Die Untersuchung der radikalischen Copolymerization der Monomeren mit Styrol ergab bei 4-Vinyldiphenyl und 12-Vinyl-p-terphenyl einen bevorzugten Einbau in die Polymerketten, während 11-Vinyl-p-terphenyl nur in untergeordnetem Maße in Polystyrolketten eingebaut wurde.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 562 (1988), S. 73-86 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Redox Reactions in Condensed Oxide Systems. VIII. On the Mechanism of Spinel Formation in the System ZnxMn3-xO4Spinel formation has been studied in sandwich arrangements of ZnO/Mn3O4 and ZnO/α-Mn2O3 ceramic disks measuring the chemical diffusion coefficients by chemical analyses and with micro probe. The reaction with α-Mn2O3 yields ZnxMn1-xIIMn2IIIO4 (0 〈 x ≤ 1) accompanied by O2 evolution in the front. On the other hand, in accordance with the phase diagram Zn(Znx-1Mnx-1IVMn4-2xIII)O4(1 〈 x 〈 1.5) is formed by oxygen contamination at the side neighboured to ZnO. The reaction rate of ZnO with Mn3O4 is increasing when the O2 partial pressure is increasing from normal atmosphere to pure oxygen yielding values which characterize the reaction of ZnO with α-Mn2O3. Migrating of ZnO into Mn3O4 or α-Mn2O3 only is observed for the reaction in the air, while in pure oxygen reversal diffusion of manganese oxide into the ZnO pellet takes place in part, too.
    Notes: Die Spinellbildung wird an Sinterpreßlingen von ZnO/Mn3O4 und ZnO/α-Mn2O3 durch Ermittlung der chemischen Diffusionskoeffizienten untersucht. Dazu werden analytische Bestimmungen und Messungen des Konzentrationsprofils mit Hilfe der Mikrosonde ausgeführt. Bei der Umsetzung mit α-Mn2O3 verläuft die Entstehung von ZnxMn1-xIIMn2IIIO4 (0 〈 x ≤ 1) in der Reaktionsfront unter O2-Abspaltung. Auf der an ZnO angrenzenden Seite bildet sich in Übereinstimmung mit dem Phasendiagramm unter O2-Aufnahme Zn(Zn1-xMnx-1IVMn4-2xIII)O4(1 〈 x 〈 1,5). Unter reinem Sauerstoff wird die Reaktionsgeschwindigkeit von ZnO mit Mn3O4 gegenüber der Umsetzung an der Luft auf Werte erhöht, die etwa auch für die Reaktion von ZnO mit α-Mn2O3 zutreffen. An der Luft wird stets nur die Einwanderung von ZnO in Mn3O4 bzw. α-Mn2O3 beobachtet, unter reinem Sauerstoff dagegen partiell auch Transport von Manganoxid in das Zinkoxid.
    Additional Material: 9 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 28 (1998), S. 719-736 
    ISSN: 0271-2091
    Keywords: front tracking ; mesh adaptation ; finite element method ; Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A numerical model is developed for the simulation of moving interfaces in viscous incompressible flows. The model is based on the finite element method with a pseudo-concentration technique to track the front. Since a Eulerian approach is chosen, the interface is advected by the flow through a fixed mesh. Therefore, material discontinuity across the interface cannot be described accurately. To remedy this problem, the model has been supplemented with a local mesh adaptation technique. This latter consists in updating the mesh at each time step to the interface position, such that element boundaries lie along the front. It has been implemented for unstructured triangular finite element meshes. The outcome of this technique is that it allows an accurate treatment of material discontinuity across the interface and, if necessary, a modelling of interface phenomena such as surface tension by using specific boundary elements. For illustration, two examples are computed and presented in this paper: the broken dam problem and the Rayleigh-Taylor instability. Good agreement has been obtained in the comparison of the numerical results with theory or available experimental data. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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