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  • 1
    Publication Date: 2013-04-01
    Description: [1]  This article addresses the correction for aerosol effects in near-simultaneous multi-angle observations acquired by the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) aboard the Mars Reconnaissance Orbiter. In the targeted mode, CRISM senses the surface of Mars using 11 viewing angles, which allow it to provide unique information on the scattering properties of surface materials. In order to retrieve these data, however, appropriate strategies must be used to compensate the signal sensed by CRISM for aerosol contribution. This correction is particularly challenging as the photometric curve of these suspended particles is often correlated with the also anisotropic photometric curve of materials at the surface. This article puts forward an innovative radiative transfer-based method named Multi-angle Approach for Retrieval of Surface Reflectance from CRISM Observations (MARS-ReCO). The proposed method retrieves photometric curves of surface materials in reflectance units after removing aerosol contribution. MARS-ReCO represents a substantial improvement regarding previous techniques as it takes into consideration the anisotropy of the surface, thus providing more realistic surface products. Furthermore, MARS-ReCO is fast and provides error bars on the retrieved surface reflectance. The validity and accuracy of MARS-ReCO is explored in a sensitivity analysis based on realistic synthetic data. According to experiments, MARS-ReCO provides accurate results (up to 10% reflectance error) under favorable acquisition conditions. In the companion article, photometric properties of Martian materials are retrieved using MARS-ReCO and validated using in situ measurements acquired during the Mars Exploration Rovers mission.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 2
    Publication Date: 2013-04-01
    Description: [1]  The present article proposes an approach to analyze the photometric properties of the surface materials from multi-angle observations acquired by the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) on-board the Mars Reconnaissance Orbiter. We estimate photometric parameters using Hapke's model in a Bayesian inversion framework. This work also represents a validation of the atmospheric correction provided by the Multi-angle Approach for Retrieval of Surface Reflectance from CRISM Observations (MARS-ReCO) proposed in the companion article. The latter algorithm retrieves photometric curves of surface materials in reflectance units after removing the aerosol contribution. This validation is done by comparing the estimated photometric parameters to those obtained from in situ measurements by Panoramic Camera instrument at the Mars Exploration Rover (MER) Spirit and MER Opportunity landing sites. Consistent photometric parameters with those from in situ measurements are found, demonstrating that MARS-ReCO gives access to accurate surface reflectance. Moreover, the assumption of a non-Lambertian surface as included in MARS-ReCO is shown to be significantly more precise to estimate surface photometric properties from space in comparison to methods based on a Lambertian surface assumption. In the future, the presented method will allow us to map from orbit the surface bidirectional reflectance and the related photometric parameters in order to characterize the Martian surface.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 3
    Publication Date: 2012-04-15
    Description: The granulation procedure of a catalyst powder is a crucial step in designing a high-quality catalyst granulate for industrial applications. New granulation processes have been developed that make it possible to form granulates with a very narrow particle size distribution and high sphericity. The innovative granulation techniques offer a great potential to produce layered catalysts with inert cores and an active shell. The novel spherical granules consist of an inexpensive inert core coated with an active catalyst material. New core shell granules with an accurately designed spherical geometry have been synthesized and compared to conventional homogeneous spherical granules of the same shape. The conversion of methanol to olefins has been used as a test reaction to validate the efficiency of these promising granulates. Layered spherical granulates consisting of an inexpensive inert core and a catalytically active zeolite shell were synthesized via a spray granulation technique. These novel granulates showed a better performance in methanol to olefin conversion than conventional homogeneous granulates. Improved conversion efficiency could be demonstrated for synthesized as well as for commercial catalysts.
    Print ISSN: 0930-7516
    Electronic ISSN: 1521-4125
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley
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  • 4
    Publication Date: 2012-03-14
    Description: The granulation procedure of a catalyst powder is a crucial step in designing a high-quality catalyst granulate for industrial applications. New granulation processes have been developed that make it possible to form granulates with a very narrow particle size distribution and high sphericity. The innovative granulation techniques offer a great potential to produce layered catalysts with inert cores and an active shell. The novel spherical granules consist of an inexpensive inert core coated with an active catalyst material. New core shell granules with an accurately designed spherical geometry have been synthesized and compared to conventional homogeneous spherical granules of the same shape. The conversion of methanol to olefins has been used as a test reaction to validate the efficiency of these promising granulates. Layered spherical granulates consisting of an inexpensive inert core and a catalytically active zeolite shell were synthesized via a spray granulation technique. These novel granulates showed a better performance in methanol to olefin conversion than conventional homogeneous granulates. Improved conversion efficiency could be demonstrated for synthesized as well as for commercial catalysts.
    Print ISSN: 0930-7516
    Electronic ISSN: 1521-4125
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley
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  • 5
    Publication Date: 2017-10-05
    Description: Numerous lines of observational evidence suggest that Earth's tropical belt has expanded over the past 30–40 years. It is natural to expect that this poleward displacement should be associated with drying on the poleward margins of the subtropics, but it is less clear to what degree the drying should be zonally symmetric. This study tests the degree to which poleward motion of the Hadley cell boundary is associated with changes in local precipitation or sea level pressure, and the degree to which those changes are zonally symmetric. Evidence from both reanalysis data and global climate models reveals that the local changes associated with Hadley cell expansion are mostly confined to certain centers of action which lie primarily over oceans. Consequently, the tropical expansion measured by zonally averaged variables is not associated with systematic drying over subtropical land regions, as is often assumed.
    Print ISSN: 0094-8276
    Electronic ISSN: 1944-8007
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 6
    Publication Date: 2019
    Description: Abstract Numerous observational studies have found that the Hadley cells are expanding poleward in both the Northern and Southern Hemispheres, and model results suggest that such expansion is likely to continue throughout this century as a result of global warming. This has led to concerns that the subtropical dry zones may also shift poleward. However, precipitation changes associated with Hadley cell width are zonally asymmetric—especially in the Northern Hemisphere—suggesting that a more regional focus may give a clearer picture of these changes. In this study, we consider the influence of the Northern Hemisphere subtropical highs on summertime precipitation in North America, and contrast this with the influence of Hadley cell expansion. Specifically, we consider the North Pacific and North Atlantic subtropical highs (NPSH and NASH, respectively), and define, for each of these, three indices representing longitude, latitude, and strength. We find that short‐term (monthly) precipitation variability over North America has comparable sensitivities to all six indices. However, for projections of 21st century climate change, North American summertime precipitation trends are driven more strongly by the longitudes of the highs than by their latitudes or strengths. Since the Hadley cells are defined with zonal‐mean quantities, much of the impact of these subtropical high shifts cannot be captured by Hadley cell metrics.
    Print ISSN: 2169-897X
    Electronic ISSN: 2169-8996
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 1 (1892), S. 353-359 
    ISSN: 0863-1778
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 2 (1892), S. 235-254 
    ISSN: 0863-1778
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 3 (1893), S. 421-427 
    ISSN: 0863-1778
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 9 (1895), S. 418-433 
    ISSN: 0863-1778
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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