Publication Date:
2016-06-12
Description:
Article Palladium catalyzed allylic substitution reactions typically proceed via an outer sphere mechanism, yielding predominately linear products. Here, the authors report an inner sphere process for the allylic substitution of ketone enolates, giving branched products with up to three contiguous stereocentres. Nature Communications doi: 10.1038/ncomms11806 Authors: Da-Chang Bai, Fei-Le Yu, Wan-Ying Wang, Di Chen, Hao Li, Qing-Rong Liu, Chang-Hua Ding, Bo Chen, Xue-Long Hou
Electronic ISSN:
2041-1723
Topics:
Biology
,
Chemistry and Pharmacology
,
Natural Sciences in General
,
Physics
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