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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Wood science and technology 28 (1994), S. 209-218 
    ISSN: 1432-5225
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Summary The features of the reaction between sitka spruce wood and non-formaldehyde reagents, i. e. glyoxal, glutaraldehyde, and dimethylol dihydroxy ethyleneurea (DMDHEU), were investigated from the aspects of moisture adsorption and bending creep properties. To the moisture adsorption data, Hailwood-Horrobin adsorption equation was applied, and whole adsorbed water was separated into hydrated water and dissolved water which correspond to monolayer and multilayer adsorption, respectively. In the treatments with non-formaldehyde reagents, the decrease of equilibrium moisture content was mainly attributed to the decrease of dissolved water, but not largely to that of hydrated water. This suggested that the reagent in the multilayer adsorption region contributed pronouncedly to suppress the moisture adsorption by the bulking and cross-linking effects, but that the reagent in the monolayer adsorption region did not considerably. The creep deformation and remaining strain of the specimens treated with glyoxal and glutaraldehyde were as small as those of formaldehyde treatment. Also by the DMDHEU treatment, creep deformation was restrained to some extent. The eminent creep restraint effect by these treatments showed the formation of cross-linkings, although the crosslinkings were not stable to the drastic water leaching.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Effect of starting particle size on hot-pressing of magnesium oxide (MgO) powder was examined using seven kinds of MgO powders prepared by a vapour-phase oxidation process; the average primary particle sizes were 11, 25, 32, 44, 57, 107 and 261 nm. These compressed powders (compacts) were hot-pressed at a temperature between 900 and 1300°C. The densifications of these compacts during the hot-pressing proceeded via (i) the sintering of primary particles within secondary particles and the rearrangement of secondary particles/grains (900°C), (ii) the gradual grain growth controlled by the pore migration (900∼1100°C) and (iii) the rapid grain growth due to the active mass transfer (1300°C); the grain sizes of MgO compacts hot-pressed at and below 1100°C were 〈1 μm, while those at 1300°C attained 20∼30 μm. The transluscent compact with the relative density of 99.7% could be obtained when the compressed powder with the average primary particle size of 44 nm was hot-pressed at a temperature as low as 1100°C for 1 h.
    Type of Medium: Electronic Resource
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