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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 60 (1995), S. 191-196 
    ISSN: 1432-0630
    Keywords: PACS: 61.80.Ba; 63.20. ; e; 78.47.+p
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract.  We analyze the femtosecond instability of the diamond lattice of silicon and GaAs, which is induced by a dense electron–hole plasma after excitation by a very intense laser pulse. We obtain that the electron–hole plasma causes an instability of both transverse acoustic and longitudinal optical phonons. So, within less than 200 fs, the atoms are displaced more than 1 A˚ from their equilibrium position. The gap between the conduction and the valence band then vanishes and the symmetries of the diamond structure are destroyed, which has important effects on the optical reflectivity and second-harmonic generation. After that, the crystal melts very rapidly because of the high kinetic energy of the atoms. Note that this is in good agreement with recent experiments done on Si and GaAs using a pump laser to excite a dense electron–hole plasma and a probe laser to observe the resulting changes in the atomic and electronic str ucture.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 60 (1995), S. 191-196 
    ISSN: 1432-0630
    Keywords: 61.80.Ba ; 63.20.-e ; 78.47.+p
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract We analyze he femtosecond instability of the chamond lattice of silicon and GaAs, which is induced by a dense electron-hole plasma after excitation by a very imense laser pulse. We obtain that the electron-hole plasma causes an instability of both transverse acoustic and longitudinal optical phonons. So, within less than 200fs, the atoms are displaced more than 1 Å from their equilibrium position. The gap between the conduction and the valence band then vanishes and the symmetries of the diamond structure are destroyed, which has important effects on the optical reflectivity and second-harmonic generation. After that, the crystal melts very rapidly because of the high kinetic energy of the atoms. Note that mis is in good agreement with recent experiments done on Shand GaAs using a pump laser to excite a dense electron hole plasma and a probe laser to observe the resulting changes in the atomic and electronic structure.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 19 (1991), S. 215-217 
    ISSN: 1434-6079
    Keywords: 33.10 −a ; 31.50. +w
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The static and dynamical polarizabilities of the Hg-dimer are calculated by using a Hubbard Hamiltonian to describe the electronic structure. The Hamiltonian is diagonalized exactly within a subspace of second-quantized electronic states from which only multiply ionized atomic configurations have been excluded. With this approximation we can describe the most important electronic transitions including the effect of charge fluctuations. We analyze the polarizability as a function of the intraatomic Coulomb interaction which represents the repulsion between electrons. We obtain that this interaction results in strong electronic correlations in the excited states and increases the first excitation energy of the dimer by 0.8 eV in comparison to a calculation which neglects correlations, resulting in a better agreement with the experiment.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 12 (1989), S. 365-367 
    ISSN: 1434-6079
    Keywords: 36.40.+d
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract To study the transition from van der Waals to metallic bonding we calculate the size dependence of the ionization energy and 5d→6p autoionization energy of Hg n -clusters using a parametrized LCAO model. Our results are in good qualitative agreement with experiment. Comparison with experimental results suggests that electron correlations play an important role for the transition from localized (van der Waals-like) to delocalized (covalent or metallic) electronic states occuring in Hg n atn≃13–19.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 25 (1992), S. 87-94 
    ISSN: 1434-6079
    Keywords: 36.40. + d
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We present a simplified theory for the electronic shell structure of large metallic clusters by extending the semiclassical analysis by Gutzwiller, Balian and Bloch. Thus analytical results are given for the shell effect in the Fermi energy and cohesive energy. In particular, results for the temperature dependence of the shell structure are given. New results are presented for the shell structure in the ionization potential and photoyield and for the existence of electronic- versus atomic shell structure as a function of cluster size and temperature. We obtain good quantitative agreement with previous numerical calculations and with experiments on Na clusters.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 20 (1991), S. 53-55 
    ISSN: 1434-6079
    Keywords: 36.40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An exact theory for excess electrons in clusters of rare gas atoms is limited to small sizes,n 〈 20, because of many body polarization interactions which make it necessary to solve a large system of linear equations. We present a simple dielectric screening approximation, which avoids this difficulty and which is in very good agreement with the exact calculation. This approximation can be used to examine the excitation energies of excess electrons and exciton energies in large clusters. A new atomic structure is proposed for a cluster of 12 Xe atoms, resulting in an increased binding energy for the excess electron, which is larger than the electron affinity of a cluster of 13 atoms. This might explain the relatively large abundance of Xe 12 − observed in the experiment.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 28 (1993), S. 169-175 
    ISSN: 1434-6079
    Keywords: 42.65.K ; 36.40 ; 73.35
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We calculate the nonlinear optical properties of small metallic spheres using electromagnetic theory and assuming that the local response of the conduction electrons is the same as for a plane surface. Electromagnetic Mie-resonances cause a strong increase of the second and higher harmonics in the reflected light. Detailed results are given for the second and third harmonic generation, its dependence on the frequency and polarization of the incident light, and on the cluster size. An enhancement of the second harmonic generation by a factor of about 5000 is obtained for small spherical metallic clusters. This is in good agreement with experiments on artificially roughened metal surfaces.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 31 (1994), S. 287-289 
    ISSN: 1434-6079
    Keywords: 36.40 ; 33.10
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The electronic shell structure of spherical and circular potential wells of finite depth is examined as an extension of the work of Balian and Bloch. We obtain analytical expressions for the electronic density of states, which are in good agreement with numerical results. The position of the maxima and minima in the density of states depends strongly on the depth of the potential via the quantummechanical scattering phases. For circular discs the oscillating structure in the density of states shows a different supershell pattern than for spheres. This is a consequence of the difference in the effective quantummechanical multiplicity of closed paths, which determine the oscillating structure.
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  • 9
    Publication Date: 1995-01-01
    Print ISSN: 0947-8396
    Electronic ISSN: 1432-0630
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Springer
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  • 10
    Publication Date: 1995-02-01
    Print ISSN: 0947-8396
    Electronic ISSN: 1432-0630
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Springer
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