ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The composition, stability, and structure of palladium(II) chloride complexes in hydrochloric acid media have been determined using nuclear-magnetic relaxation, magnetochemical methods, and Rayleigh light scattering. The predominant form in solution for palladium(II) concentrations greater than 0.005 moles/liter is the octahedral Pd6Cl12 or Pd6Cl14 2−, which has antiferromagnetic properties in contrast with the paramagnetic properties of the mononuclear aquachloride. The polarizability anisotropy of Pd-Cl bonds with terminal and bridging chlorine atoms has been determined.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00958828
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