ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. Thermolysis of doubly substituted aliphatic-aromatic triazenes proceeds through the formation of $$\overline {C_6 H_5 NH..R} S$$ radical pairs (RP) in the initial stages of the reaction (R is an alkyl radical). C6H5NH.R 2. It is suggested mat thermolysis of methyl- and ethylphenyltriazenes leads to the formation of 1-methyl-2-imino-3,5-cyclohexadiene and 1-ethyl-2-imino-3,5-cylcohexadiene, unusual compounds resulting from the recombination of ethyl and methyl radicals with anil radicals. 3. Interference of1H and13C CPN effects in the $$\overline {C_6 H_5 NH..R} S,\overline {C_6 H_5 NH..R} F$$ and $$\overline {R..R} FRP's$$ was observed in the thermolysis of benzyl- and tert-butylphenyltriazenes. 4. A value has been obtained for the anil radical g factor.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01179452
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