ISSN:
1572-8854
Keywords:
aluminum
;
chromium
;
acetylacetonate
;
disorder
;
solid solution
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The molecular structure of a solid solution of Al(acac)3 and Cr(acac)3 has been determined. The Al:Cr ratio as determined by refinement of occupancy and anisotropic displacement parameters was determined to be 91.6:8.4%. The unit cell parameters for Al0.916Cr0.084(acac)3 are smaller and the M-O distances are intermediate compared to those in the pure compounds, Crystal data: monoclinic, P21/c, a = 13.989(3), b = 7.539(2), c = 16.307(3) Å, β = 98.82(3)°, V = 1699.6(6), Z = 4.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1009554301560
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