ISSN:
0040-5744
Schlagwort(e):
Key words: Hydrosilation reaction
;
Catalyst
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Summary. The reactions of ethylene with silane, chlorosilane, fluorosilane, and dichlorosilane, and of propylene with silane are considered using ab initio electronic structure calculations. At both the MP2 and MP4 levels of theory with both DZP and TZP quality basis sets, the energy barriers for all reactions are found to be in excess of 50 kcal/mol.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF01113864
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