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Copolymerization of N-(4-carboxyphenyl)maleimide with acrylonitrile and the properties of its membrane (2000)

Chiang, Wen-Yen ; Ding, Fan-Chun

Springer

Journal of polymer research 7 (2000), S. 251-255

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ISSN: 1572-8935

Keywords: N-(4-Carboxyphenyl)maleimide ; Acrylonitrile ; Monomer reactivity ratios ; Q, e Scheme ; Pervaporation

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: Abstract N-(4-Carboxyphenyl)maleimide (N-4-CPMI, M1) was copolymerized with acrylonitrile (AN, M2) to prepare the copolymer. The monomer reactivity ratios and Alfrey-Price Q, e values were determined as r1 = 0.56, r2 = 0.84, Q 1 = 2.0, Q 2 = 0.6 and e 1 = 2.06, e 2 = 1.2. The membrane of copolymer containing 0.25% CPMI had a good tensile property (67.3 MPa). The 0.75 mole% membrane had an excellent selectivity factor (α = 45.3).

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/s10965-006-0127-7

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