ISSN:
1573-9171
Keywords:
dienones
;
phosphorylation
;
desoxychlorination
;
methoxylation
;
hydrolysis
;
phosphorus(v) derivatives
;
solid-phase functionalization on the surface of chromatographic adsorbents
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The reaction of 2,6-dibenzylidenecyclohexanone with PCl5 occursvia the sequential stages of desoxychlorination and substitutional phosphorylation to form (after oxidation, methoxylation, and hydrolysis on the surface of the chromatographic SiO2 adsorbent) organophosphorus products of the 1-(a-chloro-, a-hydroxy-, or α-alkoxy)benzyl-2-chloro-3-(α-(dimethylphosphoryl)benzylidene)cyclobex-1-ene series.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01433987
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