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  • Articles  (7)
  • Gas chromatography  (4)
  • 34A45
  • 41A21
  • minimum degrees
  • rationality
  • Springer  (7)
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  • Articles  (7)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 20 (1985), S. 371-375 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Flame photometric detector ; Sulphur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The effect of experimental conditions such as gas flow rates, detector and column temperatures on sulphur response are discussed. It is concluded that the response of the flame photometric detector is affected by the O/H ratio and the total gas flow. Column temperature has an important influence upon S2 emission. It is shown that the sulphur response of the FPD is dependent on the compound containing the sulphur.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1572-9265
    Keywords: multipoint Padé-type approximation ; orthogonal rational functions ; quadrature formula ; 41A21 ; 30E05 ; 41A55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract We study the convergence of rational interpolants with prescribed poles on the unit circle to the Herglotz-Riesz transform of a complex measure supported on [−π, π]. As a consequence, quadrature formulas arise which integrate exactly certain rational functions. Estimates of the rate of convergence of these quadrature formulas are also included.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Numerical algorithms 21 (1999), S. 185-203 
    ISSN: 1572-9265
    Keywords: systems of differential equations ; analytic solutions ; matrix Padé approximation ; rationality ; minimum degrees ; uniqueness ; partial differential equations ; 41A21 ; 34A45 ; 35A35
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract In this paper we present a technique to study the existence of rational solutions for systems of differential equations — for an ordinary differential equation, in particular. The method is relatively straightforward; it is based on a rationality characterisation that involves matrix Padé approximants. It is important to note that, when the solution is rational, we use formal power series “without taking into account” their circle of convergence; at the end of this paper we justify this. We expound the theory for systems of linear first-order ordinary differential equations in the general case. However, the main ideas are applied in numerical resolution of partial differential equations.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Numerical algorithms 15 (1997), S. 167-192 
    ISSN: 1572-9265
    Keywords: Matrix Padé Approximation ; rationality ; minimum degrees ; uniqueness ; 65 ; 41 ; 15
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract In many applications it is of major interest to decide whether a given formal power series with matrix-valued coefficients of arbitrary dimensions results from a matrix-valued rational function. As the main result of this paper we provide an answer to this question in terms of Matrix Padé Approximants of the given power series. Furthermore, given a matrix rational function, the “smallest” degrees of the matrix polynomials which represent it are not necessarily unique. Therefore we study a certain minimality-type, that is, minimum degrees. We aim to obtain all the minimum degrees for the polynomials which represent the function as equivalents. In addition, given that the rational representation of the function for the same pair of degrees need not be unique, we have obtained conditions to study the uniqueness of said representation. All the results obtained are presented graphically in tables setting out the above information. They lead to a number of properties concerning special structures, staired blocks, in the Padé Table.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 42 (1996), S. 465-468 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Packed column separations ; Pyridine and alkylpyridines
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The gas chromatography of the β-picolines in a lowboiling tar base fraction, is described. The methods developed employ packed columns with binary phases containing N,N,N′,N′-tetrakis(2-hydroxypropyl) ethylenediamine plus metal transition stearate, or with a ternary phase containing this mixture and o-hydroxyethylresorcinol
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  • 6
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Aliphatic hydrocarbons ; Chlorinated aromatics ; Pork liver extracts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A multicomponent extraction/concentration procedure has been developed for the enrichment of PCBs, PCTs and aliphatic hydrocarbons (pristane, C18, C19, C20, C22, C24, C28, C32 and C36) in pork liver. These components of the enriched extract were then simultaneously determined by gas chromatography. Mean recoveries ranged from 81.5% for pristane to 93% for PCBs;CV% (0.9–6.7) indicated the method to be both precise and reproducible.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 49 (1999), S. 385-390 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Structure correlations ; Polycyclic aromatic hydrocarbons ; Polychlorinated biphenyls ; Polychlorinated pesticides
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A composite chromatographic retention index system has been developed for identifying polycyclic aromatic hydrocarbons, polychlorinated biphenyls and polychlorinated pesticides. When retention indices and thermodynamic data of polycyclic aromatic hydrocarbons on 5% phenylmethylsiloxane stationary phase were compared with those obtained on polydimethylsiloxane a correlation was found between retention and electronic properties. Determination and quantitation of individual contaminants in water and sediment samples from Lake Mecoacán were achieved by capillary gas chromatography with flame ionization and electrocapture detection.
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