ISSN:
1573-9171
Keywords:
salts of nitro compounds
;
nitroso compounds
;
nitrones
;
trimethylsilyl nitronates
;
isoxazolidines
;
1,3-dipolar cycloaddition
;
regioselectivity
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Anions of aliphatic nitro compounds R1R2C=NO2 − react with nitroso compounds RNO to give nitrones R1R2C=N(O)R. Salts of nitro compounds with metals and Et3N, as well as trimethylsilyl nitronates in the presence of F−, can serve as the sources of the anions. The structure of the nitrones was established by NMR spectroscopy. 1,3-Dipolar cycloaddition of a series of the nitrones obtained to olefins was investigated.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01431312
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