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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of peptide research and therapeutics 5 (1998), S. 269-276 
    ISSN: 1573-3904
    Keywords: metalloenzymes ; peptide-porphyrins ; solid-phase peptide-synthesis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract New metal-tetraphenylporphyrins and Fmoc-lysine-metalloporphyrin derivatives have been used to prepare peptide-porphyrin and peptide-metalloporphyrin compounds via solid-phase peptide synthesis. A water-soluble peptide, covalently bound to a manganese(III)-porphyrin, has been used as a catalyst to promote the oxidation of ABTS by hydrogen peroxide or t-butylhydroperoxide.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of peptide research and therapeutics 5 (1998), S. 269-276 
    ISSN: 1573-3904
    Keywords: metalloenzymes ; peptide-porphyrins ; solid-phase peptide-synthesis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary New metal-tetraphenylporphyrins and Fmoc-lysine-metalloporphyrin derivatives have been used to prepare peptide-porphyrin and peptide-metalloporphyrin compounds via solid-phase peptide synthesis. A water-soluble peptide, covalently bound to a manganese(III)-porphyrin, has been used as a catalyst to promote the oxidation of ABTS by hydrogen peroxide ort-butylhydroperoxide.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2020-11-12
    Description: Public concern about anthropogenic seismic- ity in Italy first arose in the aftermath of the deadly M ≈ 6 earthquakes that hit the Emilia-Romagna region (northern Italy) in May 2012. As these events occurred in a (tectonically active) region of oil and gas production and storage, the question was raised, whether stress perturbations due to underground industrial activities could have induced or triggered the shocks. Following expert recommendations, in 2014, the Italian Oil & Gas Safety Authority (DGS-UNMIG, Ministry of Economic Development) published guidelines (ILG - Indirizzi e linee guida per il monitoraggio della sismicità, delle deformazioni del suolo e delle pressioni di poro nell’ambito delle attività antropiche), describing regula- tions regarding hydrocarbon extraction, waste-water in- jection and gas storage that could also be adapted to other technologies, such as dams, geothermal systems, CO2 storage, and mining. The ILG describe the frame- work for the different actors involved in monitoring activities, their relationship and responsibilities, the procedure to be followed in case of variations of mon- itored parameters, the need for in-depth scientific anal- yses, the definition of different alert levels, their mean- ing and the parameters to be used to activate such alerts. Four alert levels are defined, the transition among which follows a decision to be taken jointly by relevant au- thorities and industrial operator on the basis of evalua- tion of several monitored parameters (micro-seismicity, ground deformation, pore pressure) carried on by a scientific-technical agency. Only in the case of liquid reinjection, the alert levels are automatically activated on the basis of exceedance of thresholds for earthquake magnitude and ground shaking – in what is generally known as a Traffic Light System (TLS). Istituto Nazionale di Geofisica e Vulcanologia has been charged by the Italian oil and gas safety authority (DGS- UNMIG) to apply the ILG in three test cases (two oil extraction and one gas storage plants). The ILG indeed represent a very important and positive innovation, as they constitute official guidelines to coherently regulate monitoring activity on a national scale. While pilot studies are still mostly under way, we may point out merits of the whole framework, and a few possible critical issues, requiring special care in the implementa- tion. Attention areas of adjacent reservoirs, possibly licenced to different operators, may overlap, hence mak- ing the point for joint monitoring, also in view of the possible interaction between stress changes related to the different reservoirs. The prescribed initial blank- level monitoring stage, aimed at assessing background seismicity, may lose significance in case of nearby ac- tive production. Magnitude – a critical parameter used to define a possible step-up in activation levels – has inherent uncertainty and can be evaluated using differ- ent scales. A final comment considers the fact that relevance of TLS, most frequently used in hydraulic fracturing operations, may not be high in case of trig- gered tectonic events.
    Description: Published
    Description: 1015–1028
    Description: 1IT. Reti di monitoraggio e sorveglianza
    Description: JCR Journal
    Keywords: Anthropogenic seismicity ; Alert system ; Monitoring guidelines ; 04.06. Seismology ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2021-06-22
    Description: The densely populated Po Plain, a very deep sedi- mentary basin in northern Italy, is prone to heavy shaking during earthquakes. Seismic hazard assessment must account for local variation in wave amplification. Standard ground motion prediction equations may fail to picture the complexity of strong lateral gradients in seismic response, due to sharp structural heterogeneity. For this reason, there is an increasing demand for full waveform predictions for engineering applications. Here, we present an implementation of a hybrid broadband simulation based on the method of Mai et al. (Bull Seismol Soc Am 100(6):3338–3339, 2010), to obtain complete broadband seismograms of 0.1–10 Hz. With this method, low frequency (〈1 Hz) and high frequency (1–10 Hz) seismograms are simulated separately using a deter- ministic and a stochastic method, respectively. We apply the method to four events recorded within the Po basin, with magnitude ranging from Mw = 4.4 to Mw = 5.6. The low frequency (LF) simulation is performed using SPECFEM3D on a few test sub- surface velocity models. The three-dimensional velocity model MAMBo (Molinari et al. in Bull Seismol Soc Am 105(2A):753–764, 2015)—consisting of a detailed structural description of the basin, based on extensive active-source data, embedded within a regional 3D crustal model—provided the best results for broadband simulations that most closely corresponded with the observations. It performed better than an ambient noise tomography model with more accurate S-wave velocities but less well defined layer topographies, emphasizing the importance of first order velocity discontinuities. The high frequency (HF) seis- mograms are simulated using the multiple scattering approach of Zeng et al. (J Geophys Res Solid Earth 96(B1):607–619, 1991). The scattering coefficients are obtained by performing a non linear inversion for each station to find best fitting synthetic envelopes. HF energy is then combined at 1 Hz to match the amplitude and phase spectra of the LF signal. We are able to simulate full waveforms throughout the Po Plain, of which shaking duration matches observed data for stations located in the basin. Shaking amplitudes are generally overestimated in the low frequency simulation by the MAMBo velocity model. Updating the MAMBo velocity model with more accurate S-wave velocity information of the ambient noise tomography model should improve the fit in future simulations.
    Description: Published
    Description: 2181–2198
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Ground motion ; hybrid method ; sedimentary basin ; Seismic shaking scenario ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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