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  • Physics  (2)
  • Engineering General  (1)
  • Wiley-Blackwell  (3)
  • Springer
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 2835-2842 
    ISSN: 0887-6266
    Keywords: polymer blends ; random copolymer ; compatibilizer ; encapsulation ; coalescence ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: We investigate the compatibilizing performance of a random copolymer in the melt state, using transmission electron microscopy. Blends of polystyrene (PS) and poly(methyl methacrylate) (PMMA) are chosen as a model system, and a random copolymer of styrene and methyl methacrylate (SMMA) with 70 wt % styrene is used as a compatibilizer. From TEM photographs it is clear that SMMA moves to the interface between PS and PMMA domains during melt mixing, and forms encapsulating layers. However, the characteristic size of the dispersed phase increases gradually with annealing time for all blend systems studied. This demonstrates that the encapsulating layer of SMMA does not provide stability against static coalescence, which calls into question the effectiveness of random copolymers as practical compatibilizers. We interpret the encapsulation by random copolymers in terms of a simple model for ternary polymer blends. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 2835-2842, 1997
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 1603-1617 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The stress-strain behavior of randomly crosslinked polydimethylsiloxane (PDMS) networks was studied. The small-strain data obtained agreed well with available data on radiation-crosslinked PDMS networks. It was found that both the suppression of junction fluctuation and trapped entanglements have to be considered in order to account for the discrepancy between experimental data and the phantom-network theory. With the addition of a constant trapped entanglement term, Flory's recent network model describes correctly the behavior of our networks under tonsion and compression. The values of the parameters used in fitting the data are within the range suggested by Flory for typical rubber networks. Edwards' “potential pipe” theory did not correlate our data over the entire range of strain variation.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 6 (1986), S. 819-839 
    ISSN: 0271-2091
    Keywords: Lubricated Flow ; Extensional Flow ; Compression Moulding ; Two-Liquid Interface Flow ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A thin film of low-viscosity lubricating liquid between a solid wall and a viscous material reduces shear stress on the latter and tends to make it flow as though it were slipping along the wall. The result when the lubricated material is being squeezed out of the gap between approaching parallel plates is flow more nearly irrotational, or extensional, the more effective the lubricating film on the plates. Two Newtonian analyses of this flow situation are reported. One is an approximate, asymptotic analytical solution for Newtonian lubricating flow in the films and combined mixed flow, shear and extension, in the viscous layer. The second is a full two-dimensional axisymmetric solution of the momentum and continuity equations along with the kinematic condition which governs the motion of the interface. Both analyses indicate that there are two limiting flow regimes, depending on the ratio of the thickness of each of the two phases to radius and on the viscosity ratio of the two liquids. In one limit the flow is parallel squeezing and the lubricant layer slowly thins and persists a long time. In the other the lubricant is expelled preferentially. Implications of the results are discussed for rheological characterization of viscoelastic liquids and for prediction of lubricated or autolubricated flows in processing situations.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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