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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of applied electrochemistry 11 (1981), S. 489-492 
    ISSN: 1572-8838
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Elektrotechnik, Elektronik, Nachrichtentechnik
    Notizen: Abstract Electrodes for the electrochemical reduction of oxygen have been studied galvanostatically. The electrodes were of the activated carbon-polymeric iron phthalocyanine (FePc) type, made hydrophobic with a Teflon treatment. A link between the FePc and the carbon was achieved by covalently binding imidazol to the carbon surface and then letting the FePc co-ordinate to the free nitrogen of the imidazol molecule. In this way an initial improvement of the stability of the electrode potential and the polarization data was achieved. It has furthermore been established that the potential responds more rapidly to changes, i.e. it is more reversible, than an analogous electrode based on carbon that has not been treated with imidazol.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    ISSN: 1572-8838
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Elektrotechnik, Elektronik, Nachrichtentechnik
    Notizen: Abstract Electrodes for the electrochemical reduction of oxygen have been studied both galvanostatically and by XPS and IR spectroscopy. The electrodes contain a polymeric phthalocyanine catalyst fixed to an activated carbon carrier by a covalent link of imidazol. Various preparation methods have been tried to make conditions for the coupling of imidazol to the carbon surface as mild as possible. It is concluded from the XPS measurements that about one imidazol molecule is present for every second C6 unit on the carbon surface. The treatment described results in highly reversible electrode systems. The lifetime of the electrode is limited to several hundred hours, the sudden decrease thereafter is probably related to a solvolysis of the carbon-nitrogen bond linking the imidazol to the surface.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 74 (1989), S. 451-456 
    ISSN: 1434-6036
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The valence band structure of a HfN0.93 (100) crystal has been investigated utilizing angle-resolved photoemission and HeI, NeI and ArI radiation. The experimental data are compared with calculated spectra and calculated direct transitions for stoichiometric HfN. The comparison shows that most of the structures in the recorded spectra can be identified as originating from bulk band transitions. The dispersions of the experimental peaks are predicted reasonably well theoretically, using final states approximated by free-electron bands. However, the experimental peaks are in general found somewhat deeper below the Fermi level than the calculated positions.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 96 (1994), S. 87-92 
    ISSN: 1434-6036
    Schlagwort(e): 73.20.-r ; 79.60.Bm
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Angle resolved core level studies of the Si 2p and W 4f levels have been carried out on the (110) surface of a WSi2 single crystal using synchrotron radiation. Surface shifted components have been revealed both in the Si 2p and W 4f spectra. Investigations were carried out at two different annealing temperatures. The results indicate Si enrichment at the surface, and a larger enrichment after the higher temperature anneals. The reactivity upon initial oxygen exposure was investigated. Strong Si oxidation was observed but chemically shifted W 4f components could also be detected.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    ISSN: 1573-0794
    Schlagwort(e): Comets ; C/1995 O1 (Hale-Bopp) ; radio observations ; molecules
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Physik
    Notizen: Abstract C/1995 O1 (Hale-Bopp) has been observed on a regular basis since August 1995 at millimetre and submillimetre wavelengths using IRAM, JCMT, CSO and SEST radio telescopes. The production rates of eight molecular species (CO, HCN, CH3OH, H2CO,H2S, CS, CH3CN,HNC) have been monitored as a function of heliocentric distance(rh from 7 AU pre-perihelion to 4 AU post-perihelion. As comet Hale-Bopp approached and receded from the Sun, these species displayed different behaviours. Far from the Sun, the most volatile species were found in general relatively more abundant in the coma. In comparison to other species, HNC, H2CO and CS showed a much steeper increase of the production rate with decreasing rh. Less than 1.5 AU from the Sun, the relative abundances were fairly stable and approached those found in other comets near 1 AU. The kinetic temperature of the coma, estimated from the relative intensities of the CH3OH and CO lines, increased with decreasing rh, from about10 K at 7 AU to 110 K around perihelion. The expansion velocity of the gaseous species, derived from the line shapes, also increased with a law close torh 3.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Journal of superconductivity 11 (1998), S. 73-74 
    ISSN: 1572-9605
    Schlagwort(e): Thallium cuprates ; Tl-2201 ; thin films
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Abstract The growth of Tl-2201 films on LaAlO3 single crystal substrates has been investigated. The synthesis involved precursor films made by laser ablation that were treated with Tl2O(g) in near-equilibrium conditions. By optimising the method of preparation, we obtained films that were highly smooth, c-axis oriented and epitaxial. The rocking curve of the (0010) reflection had a FWHM of 0.27°. A Tc of 92K was achieved without post-annealing.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    ISSN: 1572-9605
    Schlagwort(e): High-temperature superconductivity ; superconducting gap ; phonons ; reflectivity spectra ; alloys
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Abstract We report a reflectivity study of thez-polarized TO-phonons of Pr x Y1−x Ba2Cu4O8 and YBa2−y Sr y Cu4O8 alloys in the temperature range 10–300 K. Anomalies of the frequency and linewidth of the plane-oxygen vibration atω∼300 cm−1 due to the opening of the superconducting gap are found to occur upon crossing the superconducting transition temperatureT c . Phonon self-energy effects are strongly dependent onT c , providing evidence for a relative shift of the gap with respect to the energy of phonon.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    Applied physics 66 (1998), S. 1223-1226 
    ISSN: 1432-0630
    Schlagwort(e): PACS: 74.70; 68.55; 61.16.Ch
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau , Physik
    Notizen: 2 Ba2CuO6 films on single-crystal LaAlO3 was investigated using atomic force microscopy and X-ray diffraction. Most of the film surface consisted of flat areas separated by single or several unit-cell steps. This morphology suggests that the films grow predominantly by a step-flow mechanism. A Tl-2201 film grown using a precursor film deposited at 700 °C exhibited stacks of planes arranged in a screw-like manner on a flat background. Islands of 1–3 μm size and a height of 2–20 unit cells were dominant structures on the surface. Possible causes for the formation of the screw-like structures are discussed.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Applied physics 55 (1992), S. 449-460 
    ISSN: 1432-0630
    Schlagwort(e): 71.30.+h ; 73.40.Ns ; 79.60.Gs
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau , Physik
    Notizen: Abstract Alkali-metal layers on semiconductor surfaces are model systems for metal-semiconductor contacts, Schottky barriers, and metallization processes. The strong decrease of the work function as a function of alkali-metal coverage is also technically made use of. Recently, however, interest in these systems is growing owing to ongoing controversial discussions about questions like: Is the adsorbate system at monolayer coverage metallic or semiconducting, and does the metallization take place in the alkali overlayer or in the top layer of the semiconductor? Is the bonding ionic or covalent? What ist the absolute coverage at saturation? What are the adsorption sites? Do all alkali metals behave similar on the same semiconductor surface? We try to answer some of the questions for Li, Na, K and Cs on Si(111)(2×1), K and Cs on Si(111)(7×7) and on GaAs(110), and Na and K on Si(100)(2×1) employing the techniques of direct and inverse photoemission.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    ISSN: 1432-2056
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Eleven isolated plantations of Norway spruce Picea abies (L.) Karst, in Troms county, northern Norway, were examined for bark insects in summers 1990 and 1991. Field-infested bolts from controlled fellings were reared in laboratory to complement field-investigations. Results are compared to records made from the same plantations 1974–78. Eight scolytid species, two curculionids and two cerambycids were found inhabiting spruce in 1990–91. Dryocoetes autographus was found in ten, and Tetropium castaneum in 9 plantations. Hylastes cunicularius has apparently expanded its distribution since 1978. One plantation had no bark insects confined to spruce, except old galleries of Pityogenes chalcographus. No new immigrants to the region were found, but one curculionid species may have become extinct. Reproduction of Dryocoetes autographus and Tetropium castaneum was studied in the laboratory. D. autographus bred consecutive generations from the same bolt, whereas T. castaneum displayed varying generation time, partly within the same bolt. This enhances their viability in plantations where felling activity is low. Several scolytid species widely distributed elsewhere in naturally spruce-forested areas in Scandinavia north of the Arctic circle are still absent in Troms, including all the smallest species. It is suggested that the success of colonizers in unpredictable climates depends on both dispersal capabilities (larger species have a higher dispersal power than the smallest species), life cycle flexibility and versatility in habitat requirements. It is concluded that only species with certain properties have established in the plantations, i.e. the immigration and colonization is not stochastic.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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