ISSN:
1612-1112
Keywords:
Column liquid chromatography
;
Rhenium bipyridine complexes
;
Phosphorus ligand
;
Inorganicity/organicity ratio
;
Retention behavior
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The high-performance liquid chromatography of fourteen rhenium complexes with phosphorus and 2,2′-bipyridine-derivative ligands has been examined. Good separation between these complexes was achieved by use of an ODS column with a 60∶40 (v/v) mixture of MeOH and KH2PO4-NaOH buffer as mobile phase. Linear correlations were observed between the capacity factors of the mono-phosphorus complexes and Fujita's organicity/inorganicity ratios for the phosphorus ligands, revealing that Fujita's organicity/inorganicity parameters are useful for evaluating of the retention behavior of these complexes.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02292999
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