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  • Chemical Engineering  (3)
  • Blends  (2)
  • Wiley-Blackwell  (5)
  • Nature Publishing Group
  • 1
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 1236-1241 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effectiveness of thermal analysis as a technique for screening polymeric candidates for high temperature composite application is described. DSC, DMA, and TGA were employed to measure glass transition temperature, characterize blend phase morphology, and assess thermo-oxidative stability. The materials studied were polybenzimidazole (PBI), polyimide copolymer (6FCoPI), and blends of PBI with Ultem 1000™ and 6FCoPI. The potential of misinterpretation of thermal analysis as the primary screening tool was also demonstrated. It was shown that if thermal analysis was used with insufficient understanding of the chemistry and physics of the materials under investigation, highly misleading conclusions may be derived.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 24 (1984), S. 218-225 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This review focuses on a new type of para-catenated aromatic polymer being used in the preparation of high-performance films and fibers of exceptional strength, thermal stability, and environmental resistance, including inertness to essentially all common solvents. Polymers of this type include cis and transpoly(p-phenylene benzobisoxazole) (PBO), and the cis and trans forms of the corresponding poly(p-phenylene benzobis-thiazole)(PBT). The purpose of this paper is to summarize the authors' theoretical work on the structures, conformational energies, intermolecular interactions, and electronic properties of PBO and PBT chains, including the protonated forms known to exist in strong acids. The emphasis is on how such studies provide a molecular understanding of the unusual properties and processing characteristics of this new class of materials.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 2 (1991), S. 25-30 
    ISSN: 1042-7147
    Keywords: Blends ; Liquid crystalline polymers ; Thermal analysis ; Orientation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Blends containing two, wholly aromatic, naphthalene-based liquid crystalline polymers (LCPs) are studied. Experimental results show that the viscosities of the resulting blends are lower than the parent LCPs over the entire shear-rate range investigated. The orientation development following capillary flow demonstrates, that over a defined blend composition range, some blends have higher orientability than the constituent polymers. This is further manifested in the tensile and flexural properties of injection-molded specimens. A detailed analysis indicates that in the composition range where synergistic effects are observed in orientation development as well as in mechanical properties, only one glass transition temperature is detected. This suggests that “miscibility” is desirable for obtaining maximum properties in these blend systems.
    Additional Material: 4 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 1 (1990), S. 81-92 
    ISSN: 1042-7147
    Keywords: Blends ; Liquid crystal polymers ; Thermal analysis ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Blends in which both of the component materials are capable of forming liquid crystalline phases are considered in the present work. Solid-state characterization data are presented that suggest that chemical reaction is not a dominant event when two such materials are blended in the melt. Also, ideas of small-molecule liquid crystal mixing are shown to be not applicable to describe the behavior of this system. A formalism for describing blends of liquid crystal polymers, based on Windle's sequence matching arguments, is proposed.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
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