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  • Chemical Engineering  (5)
  • cyanide  (1)
  • Wiley-Blackwell  (6)
  • National Academy of Sciences
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  • Wiley-Blackwell  (6)
  • National Academy of Sciences
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1372-1374 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 41 (1993), S. 465-473 
    ISSN: 0006-3592
    Keywords: cyanidase ; biocatalyst ; cyanide ; waste-water ; effluents ; cyanogenic glycoside ; amygdalin ; flat membrane reactor ; apricot seed extract ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Cyanidase, an immobilized enzyme preparation for hydrolyzing cyanide to ammonia and formate, was applied for the treatment of cyanide-containing waste waters from the food industry. Apricot seed extract was chosen as a model effluent. The enzymatic hydrolysis of pure amygdalin, the main cyanogenic glycoside in the extract, and the degradation of the cyanide formed was investigated and compared with the behavior of the real extract in a batch slurry reactor. A diffusional-type, flat-membrane reactor with immobilized cyanidase was developed, where the enzyme is effectively protected from adverse effects of high molecular components contained in the extract. For monitoring continuous-membrane reactor operation, a new unsegmented ammonia measurement system was developed and applied. In continuous operation the cyanidase retained its original activity for more than 400 hours on steam. © 1993 John Wiley & Sons, Inc.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 701-702 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 602-604 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 23 (1983), S. 556-559 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The striation thickness distribution developed in an impingment T-mixer is predicted using the statistical theory of turbulent diffusion. The predicted distribution is independent of the mixing nozzle Reynolds number, in agreement with some experiments, and is primarily a function of the mixing head geometry, the ratio of the reagent flow rates and the residence time distribution of the flow in the mixing head. Mixing is described as the result of fluid deformation in the intertial subrange of turbulent flow. The relationship of deformation to time and energy dissipation rate ∊ is examined. In the impingement T-mixer ∊ is related to the kinetic energies of the streams entering and leaving the head. (There are no surface tension effects and pressure is relatively uniform in the mixing head, so that the kinetic energy is dissipated by viscous forces.) The distribution of residence times of fluid elements in the T-mixer is responsible for varying degrees of deformation and hence a distribution of striation thickness. This residence time distribution does not seem to have been studied and the flow pattern was thus modeled as perfect macromixing, having an exponential distribution. The procedure developed in this paper to calculate the distribution of striation thickness allows reasonable estimates of its parameters from fluid mechanical information and showed good agreement with experimental values, without having to fit any quantities. This new approach to striation thickness distribution is worth further evaluation.
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 25 (1985), S. 1-5 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Turbulent flow in the impingement mixing head of a reactions injection molding machine produces a laminated mixture, whose striations are mostly so thick that any subsequent copolymerization would be hindered by diffusion. However, further reduction in striation thickness occurs during laminar flow through the runner. This is calculated here and is a function of the radial position in the runner and of its length/diameter ratio. So, for example, when L/D = 10, it is predicted that at least 79 percent of, the reagent striations would be thin enough to permit reaction under kinetically controlled conditions.
    Additional Material: 3 Ill.
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