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  • Chemical Engineering  (1,427)
  • Atomic, Molecular and Optical Physics  (214)
  • Wiley-Blackwell  (1,641)
  • National Academy of Sciences
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 37-41 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experiments are reported in which the drag of single liquid droplets settling in a tall column of another lighter immiscible liquid are measured. The experimental data for the eight pairs of liquids that were tested covered a range of droplet Reynolds numbers from 10-3 to 104. Two regimes of droplet settling were encountered. In the first regime, the droplets remained spherical, and the drag agreed very well with established solid sphere drag models. In the second regime, the droplets became deformed and oscillated; the drag was found to depart suddenly from predictions of spherical models and to increase with increasing Reynolds number. Empirical models for the point of departure from spherical drag and the coefficient of drag in the unstable regime are derived.
    Additional Material: 4 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 383-388 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bifurcation problems with slowly varying control parameters are of interest in several research areas, including catalyst deactivation, combustion, and lasers and other nonlinear optical devices. Significant theoretical work has been devoted to the study of these dynamic phenomena, but very little directly relevant experimental information is currently available. Results are presented here from an experimental study of the dynamic behavior of a catalytic reaction system due to a deliberately slowly varied control parameter. Attention is focused on the dynamics due to slow passage through simple limit and Hopf points.
    Additional Material: 10 Ill.
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  • 3
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Identification and characterization of coupled diffusional and electrochemical kinetics effects was achieved under potentiostatic anodic dissolution conditions. A one-dimensional artificial pit geometry with sample wire electrodes embedded in an inert support exposed to NaCl solutions was used to study the dissolution of stainless steel and highnickel Alloy 600. Multiple steady states for both materials were determined at conditions where the diffusional transport rates balanced the electrochemical rate of dissolution at the surface of the wire electrode. A theoretical transport model was developed to quantitatively explain the observed multiple steady state phenomena.
    Additional Material: 12 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 35 (1995), S. 1261-1271 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This study clarifies and quantifies factors which increase the ductility of a low-molecular-weight propylene homopolymer having an intrinsic viscosity of 0.89 dl/g. The tensile behavior of homopolymer/ethylene-propylene rubber (EPR) blends was studied from the viewpoint of the associated molecular structure of EPR and its compatibility with the homopolymer. When EPR is “dissolved” in a homopolymer, the glass transition temperature (Tg) of the amorphous phase of a homopolymer was found to shift to a lower temperature, with homopolymer/EPR compatibility being subsequently evaluated using this shift, i.e., Δtg. Results show two conditions are required to improve the ductility of the low-molecular weight propylene homopolymer: ΔTg must be ≥ 3°C and ≥ 30 wt% EPR must be blended with the homopolymer.
    Additional Material: 18 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 10 (1976), S. 917-935 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The instabilities, especially the singlet instabilities, of the conventional Hartree-Fock (HF) solutions for a variety of alternant and nonalternant hydrocarbons, some of which have been known to show lattice instabilities (bond-length alterations), are examined. The HF solutions for nonalternant hydrocarbons in the pentalene series larger than heptalene and [4n + 2]-annulenes larger than C22H22 are found to be singlet unstable and there appear new solutions lower in energy than the conventional HF solutions and characterized by charge-density waves exhibiting bond-order alterations. It is found that such symmetry-breaking solutions are energetically further stabilized by distorting the nuclear framework so that it may match up with the distribution of bond-order matrix elements of the charge-density wave, which means that in conjugated systems the singlet instability of the HF solution is always accompanied with the lattice instability. Further, it is shown that in conjugated systems, even when the HF solution is singlet stable, if it is not sufficiently stable as, for example, in pentalene and heptalene, there is every possibility for the occurrence of lattice instability. It is also shown that the singlet instability as well as the lattice instability arises from the existence of a sufficiently low-lying singlet excited state.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 18 (1980), S. 655-659 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The optical reflectivity spectra of quasi-one-dimensional polymers (SN)x, trans-(CH)x, and polydiacetylene are investigated in an energy range from 1 to 25 eV by use of synchrotron radiation. Observed structures associated with π-electron states are interpreted in terms of the quasi-one-dimensional one-electron bands calculated by the LCAO-type model.
    Additional Material: 2 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 22 (1982), S. 1049-1058 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Some new properties of the Lagrange multiplier μ introduced through the normalization constraint on ρ in the variations of energy density functionals are determined. Through arguments concerning the homogeneity properties of these functionals with respect to μ, it is demonstrated that at the point of variation μ = μ0 = E0/N, where E0 is the ground state energy and N is the total particle number. It is also shown that the value of μ0 is independent of the normalization imposed on ρ. The interpretation of μ0 as a chemical potential is discussed in the light of these findings.
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 600-611 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Ultrasonic welding of oriented polypropylene (OPP) using tie-layer materials has been examined. The thermal cycle at the joint interface was evaluated using a high speed data acquisition system, and concurrent changes in horn displacement (penetration) and the output power were monitored. The model explaining process operation involves four phases, i.e., I-where heating occurs because of the stresses generated in asperities on the contacting surfaces; II-where the whole tie-layer reaches the melting point; III-where the polymer melt is subjected to intense heating from viscous dissipation and is squeezed out; and IV-where the joint cools after welding. In the early stages of ultrasonic welding the heat generated at asperities on the contacting surfaces leads to melting of the tie-layer/oriented polypropylene interface within 50 ms. The tie-layer heats up because of a combination of viscoelastic dissipation and heat conduction from the oriented polypropylene/tie-layer interface, and the rate of temperature rise at the midline of the tie-layer is in the range 200°/s to 400°/s. The reduction in thickness of the test specimens (penetration) is negligible up to the time when the tie-layer melts completely, and then changes rapidly when the melted polymer at the joint interface is squeezed out. The influence of machine parameters (amplitude and contact pressure) and of tie-layer Melt Flow Index is also examined. The total time required for completion of the welding process decreases when the amplitude and applied pressure are increased. The use of low Melt Flow Index tie-layers produces peak temperature as high as 600° at the bondline, and little material is ejected during the ultrasonic welding operation.
    Additional Material: 19 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 40 (1991), S. 479-487 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The UV photoelectron spectra of 2-halogenofurans, together with 3-iodo and 2,5-diiodofurans, have been studied. The assignment of the lower energy region of the spectra was based on correlation of the ring π- and halogen levels in the related compounds, resolved vibrational structure, and in case of 2- and 2,5-diiodofurans by considering the relative intensities of their He I/He II spectra.
    Additional Material: 5 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1382-1398 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The flow pattern within a partially intermeshing co-rotating twin-screw extruder is three dimensional and extremely complex. In order to simplify the problem, a slice perpendicular to the axis of the twin-screw extruder has been considered for flow analysis as a two-dimensional or a quasi-three-dimensional problem. The flow in this slice may be considered to consist of a nip region (located between the two screws) and a translation region in which the movement of the material is very similar to the one found in single-screw extruders. The flow in these two regions have been studied separately. This paper presents the numerical and experimental results of the nip region study. The flow division in the nip region has been quantified and results are presented in terms of a flow division ratio Xf. The flow field patterns have also been obtained. Newtonian as well as non-Newtonian behavior has been investigated. The influences of such factors as (i) the geometry (the radius of the barrel, radius of the screw, distance between the two screws), (ii) the material properties (the power-law index for shear rate dependent viscosity), and (iii) processing conditions (the screw speed), have also been studied.
    Additional Material: 29 Ill.
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