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  • 1
    Electronic Resource
    Electronic Resource
    Miscibility of poly(neopentyl glycol adipate)/chlorinated polymer blends (1982)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 1091-1093 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1982.070270328
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  • 2
    Electronic Resource
    Electronic Resource
    Miscibility of poly(styrene-co-acrylonitrile) and poly(α-methyl styrene-co-acrylonitrile) with copolymers of methyl methacrylate (1984)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 99-103 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Poly(α-methyl styrene-co-acrylonitrile) was found to be miscible with poly(methyl methacrylate-co-ethyl methacrylate) and with poly(methyl methacrylate-co-n-butyl methacrylate). All these blends exhibited lower critical solution temperatures. Poly(styrene-co-acrylonitrile) was also found to be miscible with poly(methyl methacrylate-co-ethyl methacrylate) and with poly(methyl methacrylate-co-n-butyl methacrylate). However, phase separation of these blends could not be induced by heating up to 300°C.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1984.070290110
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  • 3
    Electronic Resource
    Electronic Resource
    Miscible blends containing poly(tetrahydrofurfuryl methacrylate) (1987)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 1849-1852 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1987.070330537
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  • 4
    Electronic Resource
    Electronic Resource
    Synthesis and characterization of a new monomer with pendant hindered amine group (1991)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 29 (1991), S. 1889-1893 
    Details
    ISSN: 0887-624X
    Keywords: piperidinyl carbamate ; HALS ; synthesis ; characterization ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new monomer, 1,2,2,6,6-pentamethyl-4-piperidinyl m-isopropenyl-α, α-dimethylbenzyl carbamate, was synthesized by direct addition of 1,2,2,6,6-pentamethyl-4-piperidinol to m-isopropenyl-α, α-dimethylbenzyl isocyanate in the presence of dibutyltin dilaurate catalyst at elevated temperatures. It was characterized by FT-IR, 1H-NMR. MS, and elemental analysis. It is a potential hindered amine light stabilizer as it contains the 2,2,6,6-tetraalkylpiperidine moiety and its vinylic functionality makes it polymerizable.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1991.080291307
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  • 5
    Electronic Resource
    Electronic Resource
    Polymerization behavior of 2,2,6,6-tetramethylpiperidinyl methacrylate: A monomer carrying a hindered amine group (1992)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 30 (1992), S. 983-988 
    Details
    ISSN: 0887-624X
    Keywords: copolymerization ; 2,2,6,6-tetramethylpiperidinyl methacrylate ; HALS ; copolymer structure ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Copolymers of 2,2,6,6-tetramethylpiperidinyl methacrylate (TPMA) with styrene (S) and with methyl methacrylate (MMA) were synthesized using AIBN as initiator. S-TPMA copolymers from feed ranging from 0.10-0.80 mole fractions TPMA and MMA-TPMA copolymers from feed of 0.04-0.85 mole fractions TPMA were used in the determination of monomer reactivity ratios r1, r2. Four different methods were employed in the calculations of r1 and r2 and all calculated results were in good agreement with each other. The structure of S-TPMA copolymers was inferred to be of an alternating nature while that of MMA-TPMA copolymers was random. Both copolymers are potential hindered amine light stabilizers (HALS) and are expected to be less extractable from, and more compatible with, polystyrene and poly(methyl methacrylate) base polymers.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1992.080300604
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  • 6
    Electronic Resource
    Electronic Resource
    Copolymerization of methacrylonitrile with p-methylstyrene (1994)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 1263-1269 
    Details
    ISSN: 0887-624X
    Keywords: copolymerization ; reactivity ratio ; sequence distribution ; poly(p-methylstyrene-co-methacrylonitrile) ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Methacrylonitrile was copolymerized with p-methylstyrene in methyl ethyl ketone at 80°C initiated by azobisisobutyronitrile. Monomer reactivity ratios of methacrylonitrile and p-methylstyrene were found to be 0.205 and 0.377, respectively, using the Kelen-Tüdos method. Triad fractions and monomer sequence lengths of three copolymers were determined from 13C-NMR spectra and were found to be in good agreement with those calculated from reactivity ratios. © 1994 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1994.080320707
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  • 7
    Electronic Resource
    Electronic Resource
    Polymerization behavior of 1,2,2,6,6-pentamethyl-4-piperidinyl m-isopropenyl-α,α-dimethylbenzyl carbamate (1993)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 1499-1503 
    Details
    ISSN: 0887-624X
    Keywords: copolymerization ; 1,2,2,6,6-pentamethyl-4-piperidinyl ; m-isopropenyl-α,α-dimethylbenzyl carbamate ; HALS ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Copolymers of 1,2,2,6,6-pentamethyl-4-piperidinyl m-isopropenyl-α,α-dimethylbenzyl carbamate (CB) with styrene (S) and with methyl methacrylate (MMA) were synthesized using AIBN as initiator. S-CB copolymers made from feed ranging from 0.45-0.94 mole fractions S and MMA-CB copolymers made from feed of 0.34-0.88 mole fractions MMA were used to determine the monomer reactivity ratios r1 and r2. The structure of S-CB copolymers was inferred to be mainly of a random nature and in the MMA-CB copolymerization system there is a stronger tendency to form alternating copolymers. © 1993 John Wiley & Sons, Inc.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1993.080310619
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  • 8
    Electronic Resource
    Electronic Resource
    Miscibility of poly(chloromethyl methacrylate) with bisphenol-A polycarbonate (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 40 (1990), S. 2243-2246 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Poly(methyl methacrylate) (PMMA) and bisphenol-A polycarbonate (PC) are important commerical polymers. PMMA/PC blends were once considered as immiscible blends.1-3 However, recent studies have shown that the miscibility of PMMA/PC blends depends on the method of preparation.4-8 Chiou and co-workers4 reported that PMMA/PC blends prepared by solution casting and melt mixing were immiscible while blends prepared by precipitation from solution using n-heptane as nonsolvent were miscible over the whole composition range. Kyu and Salhanda5 reported that PMMA/PC blends cast from tetrahydrofuran (THF) at room temperature were immiscible but those cast from THF at temperatures above 47°C were miscible. In this communication, we report the miscibility of poly(chloromethyl methacrylate) (PCMMA) with PC. It will be shown that the miscibility behavior of PCMMA/PC blends is similar to that of PMMA/PC blends.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1990.070401135
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  • 9
    Electronic Resource
    Electronic Resource
    Miscibility of poly(tetrahydrofurfuryl methacrylate) and poly(tetrahydropyranyl-2-methacrylate) with some chlorine-containing polymers (1991)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 43 (1991), S. 437-443 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The miscibility of poly(tetrahydrofurfuryl methacrylate) (PTHFMA) and poly(tetrahydropyranyl-2-methacrylate) (PTHPMA) with some chlorine-containing polymers was studied by differential scanning calorimetry (DSC). PTHPMA was found to be miscible with poly(vinyl chloride) (PVC), polyepichlorohydrin (PECH), and a vinylidene chloride/vinyl chloride copolymer [P (VDC/VC)] and only partially miscible with an epichlorohydrin/ethylene oxide copolymer [P (ECH/EO)]. PTHFMA was shown to be miscible with PECH and P(VDC/VC), but its miscibility with P(ECH/EO) is composition-dependent. Information about interactions between components in PTHFMA/P (VDC/VC) and PTHPMA/P(VDC/VC) blends was estimated from melting-point depression. The interaction parameters B were found to be -1.7 and -3.6 J/cm3 for PTHFMA/P(VDC/VC) and PTHPMA/P(VDC/VC) blend systems, respectively. The miscibility behavior of PTHFMA and PTHPMA is compared to that of poly(cyclohexyl methacrylate).
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1991.070430304
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  • 10
    Electronic Resource
    Electronic Resource
    Miscibility behavior of blends of poly(alkyl methacrylate)s with poly(p-methylstyrene-co-methacrylonitrile) (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 56 (1995), S. 761-767 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The miscibility behavior of various poly(p-methylstyrene-co-methacrylonitrile) (pMSMAN)/poly(alkyl methacrylate)s blends was studied using differential scanning calorimetry. pMSMAN is miscible with poly(methyl methacrylate), poly(ethyl methacrylate), poly(n-propyl methacrylate), poly(isopropyl methacrylate), and poly(n-butyl methacrylate) over certain copolymer composition ranges, but is immiscible with poly(isobutyl methacrylate) and poly(n-amyl methacrylate). The width of the miscibility window decreases with increasing size of the pendant ester group of the poly(alkyl methacrylate), and is wider than that of the corresponding poly(p-methylstyrene-co-acrylonitrile) blend system. Various segmental interaction parameters are calculated using a binary interaction model. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1995.070560701
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