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  • 1
    Publication Date: 2018-09-11
    Description: Porous materials have superior electrochemical performance owing to its their structure, which could increase the specific and contact area with the electrode. The spinel Li4Mn5O12 has a three-dimensional tunnel structure for a better diffusion path, which has the advantage of lithium ion insertion and extraction in the framework. However, multi-space spherical materials with single morphologies are rarely studied. In this work, waxberry-like and raspberry-like nanospheres for Li4Mn5O12 have been fabricated by the wet chemistry and solid-state methods for the first time. The diameter of a single waxberry- and raspberry-like nanosphere is about 1 μm and 600 nm, respectively. The specific capacitance of Li4Mn5O12 was 535 mF cm−2 and 147.25 F g−1 at the scan rate of 2 mV s−1, and the energy density was 110.7 Wh kg−1, remaining at 70% after 5000th charge-discharge cycles. Compared with raspberry-like nanosphere Li4Mn5O12, the waxberry-like nanoporous spinel Li4Mn5O12 shows the better electrochemical performance and stability; furthermore, these electrochemical performances have been improved greatly compared to the previous studies. All these results indicate that the waxberry-like nanoporous spinel Li4Mn5O12 could provide a potential application in high performance supercapacitors.
    Electronic ISSN: 2079-9268
    Topics: Electrical Engineering, Measurement and Control Technology
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  • 2
    Publication Date: 2021-04-08
    Description: Wetlands play a critical role in global hydrological and biogeochemical cycles. Regulating the regional climate is one of the most important ecosystem services of natural wetlands. However, the impact of wetlands on local temperature on the global scale and the attribution is still unclear. This study utilizes the satellite-based products (land surface temperature (LST), albedo, and evapotranspiration (ET)) to evaluate the difference in LST between wetlands and their adjacent landcover types and the possible drivers. Here we show that on average for the whole year, wetlands have a cooling effect in tropical regions, but have a warming effect in boreal regions. The impacts of wetlands on LST show great seasonality in the boreal regions; i.e., the wetlands have a warming effect in winter but a cooling effect in summer. The difference in albedo and ET between wetlands and the other landcover types only interprets 30% of temporal variation of the difference in LST. Due to the large water storage in wetlands, the ground heat flux (G) may interpret the rest of the impact, absorbing energy in summer and releasing energy in winter in wetlands, which has often been neglected in previous studies. Our results indicate that it is critical to comprehensively consider the effects of wetland restoration in different regions to realize potential climatic benefits in the future.
    Electronic ISSN: 2072-4292
    Topics: Architecture, Civil Engineering, Surveying , Geography
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