ALBERT

Description: Bacterial cellulose (BC) is a new kind of cellulose with great potential in enhancing preparation of isotactic Polypropylene (iPP) composites, which have been found with excellent performance. However, the interface compatibility between BC and iPP is poor. In this study, iPP/BC composites were prepared by solution mixing. Esterification modified BC (CO) and Maleic anhydride grafted polypropylene (MAPP) added as a compatibilizer was both used to improve the interfacial compatibility of the iPP/BC composites. The rheology and isothermal crystallization behavior of the composites was tested and discussed. The result shows that the complex viscosity and storage modulus of the composite significantly increase in the rule iPP, iPP/BC2, iPP/CO2, and M-iPP/BC3, which indicates that the compatibility of the composite increases as this rule. According to the isothermal crystallization kinetics result, the crystal growth mode of iPP was not affected by the addition of BC and the interfacial compatibility. The spherulite growth rate of the iPP/BC composite increases with increasing crystallization temperature. Especially, the value decreases as the same rule with the complex viscosity and storage modulus of the composite at the same isothermal crystallization temperature. These results suggest that the interface compatibility of iPP/BC composites is greatly improved and the interface compatibility of the M-iPP/BC3 is better than the iPP/CO2.

Description: Isotactic polypropylene (iPP) is a commonly used thermoplastic polymer with many excellent properties. But high brittleness, especially at low temperatures, limits the use of iPP. The presence of transcrystallization of iPP makes it possible for fiber-reinforced iPP composites with higher strength. Bacterial cellulose (BC) is a kind of cellulose with great potential to be used as a new filler to reinforce iPP due to its high crystallinity, biodegradability and efficient mechanical properties. In this study, the iPP/BC hamburger composite was prepared by a simple hot press and maleic anhydride grafted polypropylene (MAPP) was used to improve the interface compatibility of iPP and BC. The polarizing microscope (POM) photograph shows that BC successfully induces the transcrystallization of iPP. The differential Scanning Calorimeter (DSC) date proves that the addition of BC could improve the thermal properties and crystallization rate of the composite. Especially, this change is more obvious of the iPP/MAPP/BC. The mechanical properties of the iPP/BC composites were greatly increased. This DSC date is higher than BC; we used BC particles to enhance the iPP in our previous research. The scanning Electron Microscope (SEM) analysis intuitively shows that the interface of the iPP/MAPP/BC is more smooth and flat than the iPP/BC. The fourier Transform infrared spectroscopy (FT-IR) analysis of the iPP/BC hamburger composites was shown that a new C=O group vibration appeared at 1743 cm−1, which indicated that the hydrogen bond structure of BC molecules was weakened and some hydroxyl groups were substituted after modification which can increase the lipophilicity of BC. These results indicated that the BC fiber can easily induce the transcrystallization of iPP, which has excellent mechanical properties. Moreover, the addition of MAPP contributes greatly to the interface compatibility of iPP and BC.

Description: Isotactic polybutylene-1 (iPB) has lots of advantages and is best used as hot water pipe. However, to transform into stable crystal form I, the iPB needs as long as 7 days. In this process, the irreversible damage brings great difficulties to the use of the iPB. The method which convert it directly into crystal I has shortcomings such as being requiring complex operation and being expensive. In this study, an innovative idea was put forward, not paying attention to the crystal transformation of iPB but only focusing on reducing the time it can be applied. In this study, bamboo powder was modified by the silane coupling agent KH570 (KBP) to prepare iPB/KBP composite. The infiltration test and Fourier transform infrared (FTIR) analysis showed that the hydrophilicity of KBP is greatly reduced, which can greatly improve the compatibility of the iPB and KBP. The tensile strength, tensile modulus, flexural strength, and flexural modulus of the composites storage for 3 days is equal to the pure iPB with storage 7 days with the KBP additions of 3%, 3%, 7%, and 5%, respectively. The heat deformation temperature (HDT) of the composite with 3% KBP after 1-day storage reached the value of pure iPB storage for 7 days. This provides more space and possibilities for the industrialization of the iPB. The crystallization behavior of iPB/KBP composites proves that the addition of KBP accelerates the crystallization rate of iPB, but the crystallinity of the iPB/KBP composites is not changed. The SEM photograph of iPB/KBP composites showed that when the KBP addition was low the compatibility between KBP and iPB was good. When the KBP addition was increased the agglomeration of KBP in the iPB was very obvious, which leads to the poor mechanical properties of the composite.

Description: It is the fact that there are lots of hazard incidents in underground uranium mines caused by radon but in-suit uranium samples were difficult to collect. Based on closed chamber method, three similar samples in different sealed ways were made in a laboratory with different material rations, namely uranium tailings, quartz sand, cement, iron powder and silicon powder to measure the radon concentrations with and without low-frequency vibrations, which was used by the experimental device for low-frequency vibration diffusion of radon. The results showed that the radon exhalation coming from the similar samples was influenced by the low frequency vibration; the results are presented as two-stage variations compared with the blank group. The radon exhalation increased with the rising vibration frequency when the frequency was 50 to 70 Hz, but fell slowly after reaching the peak radon exhalation rate. Analyses of the relations between the rock damage degree, changes in porosity and the occurrence of an inflection point in the radon exhalation rate in the samples found that they also increased when the frequency was between 0 to 80 in sample 3. The maximum porosity of the third samples was about 4.8% with a low-frequency vibration 60 Hz, while the maximum damage degree was about 0.07 at 50 Hz.

Description: Radon is internationally recognized as one of the seven seismic precursors. A self-assembly ultrasonic generator and experimental apparatus for radon measurement were utilized to explore the radon exhalation regularities of water-bearing porous media under different ultrasonic intensities. The experimental results showed that there was a coupling relationship among radon exhalation rate, moisture content, and ultrasonic frequency. With the increase of the frequency of the ultrasonic wave, its effect on the promotion of radon exhalation rate was found to be a more obviously positive linear correlation. The radon exhalation rate, which could climb to a maximum value of 0.179 Bq·m−2·s−1 in a naturally air-dried sample, increased at first and then decreased along with increased moisture content. Moreover, this study found that the ultrasonic wave had the most remarkable promoting effects on the radon exhalation rate of porous media with high moisture content, and there is a positive linear correlation between the growth rate of the radon exhalation rate and moisture content. The experimental results could provide a beneficial reference for the continual monitoring of radon in a seismically active belt and an explanation of radon anomalies; however, the proposed experimental model was simplified, so further insights are strictly required for a reliable correlation with the real monitoring of radon in a seismically active belt.