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  • Articles  (6)
  • Gas chromatography  (4)
  • modeling
  • Springer  (6)
  • Molecular Diversity Preservation International
  • Taylor & Francis
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Plasma chemistry and plasma processing 13 (1993), S. 237-271 
    ISSN: 1572-8986
    Keywords: High-power transferred arc ; air plasma ; turbulence ; radiative transfer ; modeling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract A physical model of two zones (constricted arc and cathode jet) of a 1-MW transferred arc in air is presented. It is based on the solution al conservation equations by a finite-differenee method. Turbulence is treated with Prandtl's approximation, whereas radiative transfer is solved considering a nonhontogeneous medium, with the hypothesis of gray spectral bands. The in of radiative transfer on the temperature field is illustrated using two-band and four-band radiation models. We also show the influence of several parameters on plasma jet properties: current intensity between 500 and 1500 A; gas mass /low rate between 10 and 90g/s, vortex injection. The arc characteristics are analyzed in accordance with physical mechanisms such as heat conduction, radiation, turbulence, convection, and miring of cold gas.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Plasma chemistry and plasma processing 17 (1997), S. 409-432 
    ISSN: 1572-8986
    Keywords: Plasma torch ; modeling ; laminar and turbulent flow
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract A mathematical 2D representation is developed describing the temperature and the velocity profiles in a DC plasma torch and in the resulting plume. It is based on the resolution of conservation equations using the Simple method after Patankar. In the first part, we illustrate the effects of the turbulence, using, on the one hand, two Prandtl's mixing length models and, on the other hand, a standard k – ε model. We also show the influence of physical parameters like the inlet mass flow rate, the current intensity, and the kind of gas (argon or air) on the characteristics of the plasma. The second part of this study presents a comparison of the model with experimental results encountered in the literature. The profiles obtained at the exit of the torch are compared to the mathematical formulation used as boundary condition by the models taking into account only the plasma jet.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 20 (1985), S. 371-375 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Flame photometric detector ; Sulphur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The effect of experimental conditions such as gas flow rates, detector and column temperatures on sulphur response are discussed. It is concluded that the response of the flame photometric detector is affected by the O/H ratio and the total gas flow. Column temperature has an important influence upon S2 emission. It is shown that the sulphur response of the FPD is dependent on the compound containing the sulphur.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 42 (1996), S. 465-468 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Packed column separations ; Pyridine and alkylpyridines
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The gas chromatography of the β-picolines in a lowboiling tar base fraction, is described. The methods developed employ packed columns with binary phases containing N,N,N′,N′-tetrakis(2-hydroxypropyl) ethylenediamine plus metal transition stearate, or with a ternary phase containing this mixture and o-hydroxyethylresorcinol
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Aliphatic hydrocarbons ; Chlorinated aromatics ; Pork liver extracts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A multicomponent extraction/concentration procedure has been developed for the enrichment of PCBs, PCTs and aliphatic hydrocarbons (pristane, C18, C19, C20, C22, C24, C28, C32 and C36) in pork liver. These components of the enriched extract were then simultaneously determined by gas chromatography. Mean recoveries ranged from 81.5% for pristane to 93% for PCBs;CV% (0.9–6.7) indicated the method to be both precise and reproducible.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 49 (1999), S. 385-390 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Structure correlations ; Polycyclic aromatic hydrocarbons ; Polychlorinated biphenyls ; Polychlorinated pesticides
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A composite chromatographic retention index system has been developed for identifying polycyclic aromatic hydrocarbons, polychlorinated biphenyls and polychlorinated pesticides. When retention indices and thermodynamic data of polycyclic aromatic hydrocarbons on 5% phenylmethylsiloxane stationary phase were compared with those obtained on polydimethylsiloxane a correlation was found between retention and electronic properties. Determination and quantitation of individual contaminants in water and sediment samples from Lake Mecoacán were achieved by capillary gas chromatography with flame ionization and electrocapture detection.
    Type of Medium: Electronic Resource
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