ALBERT

Description: This study developed an upgrading process focusing on acid transformations of water phase pyrolysis bio-oils to esters of oxygen-containing fuels via ZSM−5 catalyst. Temperature was set as a factor with five levels ranging from 60 to 135 °C with reaction time from 1 to 8 h. The results showed that 89% of high acid conversion and over 90% of ester selectivity was obtained from the feedstock via 2 wt % ZSM−5 catalysts in a fixed feedstock to methanol ratio analyzed by HPLC and GC–MS. The upgrading process followed Langmuir–Hinshelwood and reaction constants were calculated to build a practical upgrading model for bio-oil compounds. Thermodynamics of the process showed endothermic properties during the breaking bonds’ reaction on carbonyl of acid while the reaction between the carbon in methanol and electrophile acid intermediate demonstrated exothermic performance. The optimum reaction conditions for the process was at a temperature of 100.1 °C with catalyst loading of 3.98 wt %.

Description: The feature extraction technique for an electronic nose (e-nose) applied in tobacco smell detection in an open country/outdoor environment with periodic background strong interference is studied in this paper. Principal component analysis (PCA), Independent component analysis (ICA), re-filtering and a priori knowledge are combined to separate and suppress background interference on the e-nose. By the coefficient of multiple correlation (CMC), it can be verified that a better separation of environmental temperature, humidity, and atmospheric pressure variation related background interference factors can be obtained with ICA. By re-filtering according to the on-site interference characteristics a composite smell curve was obtained which is more related to true smell information based on the tobacco curer’s experience.

Description: Water, Vol. 10, Pages 1064: The Application of a Modified Version of the SWAT Model at the Daily Temporal Scale and the Hydrological Response unit Spatial Scale: A Case Study Covering an Irrigation District in the Hei River Basin Water doi: 10.3390/w10081064 Authors: Zheng Wei Baozhong Zhang Yu Liu Di Xu As a well-built, distributed hydrological model, the Soil and Water Assessment Tool (SWAT) has rarely been evaluated at small spatial and short temporal scales. This study evaluated crop growth (specifically, the leaf area index and shoot dry matter) and daily evapotranspiration at the hydrological response unit (HRU) scale, and SWAT2009 was modified to accurately simulate crop growth processes and major hydrological processes. The parameters of the modified SWAT2009 model were calibrated using data on maize for seed from 5 HRUs and validated using data from 7 HRUs. The results show that daily evapotranspiration, shoot dry matter and leaf area index estimates from the modified SWAT2009 model were satisfactory at the HRU level, and the RMSE values associated with daily evapotranspiration, shoot dry matter, and leaf area index were reduced by 17.0%, 1.6%, and 71.2%, compared with SWAT2009. Thus, the influences of various optimal management practices on the hydrology of agricultural watersheds can be effectively assessed using the modified model.

Description: Water, Vol. 10, Pages 438: Research on the Treatment and Comprehensive Utilization of Phenylhydrazine Hydrochloride Effluent Water doi: 10.3390/w10040438 Authors: Xide Liu Di Zhou Heng Zhang In the production process of 1 ton of phenylhydrazine hydrochloride (PHH); ~10 tons of liquid waste are formed, which includes multiple contaminants but also recyclable resources. In order to realize the recyclingof residual PHH in liquid waste; a liquid ammonia neutralization method is utilized, and extraction-reextraction technology is adopted. As a result, the recovery rate of PHH reachedup to 90.0%. Meanwhile, 3.8 tons of ammonium salts can be obtained after the iquid ammonia neutralization reaction which can be reused as raw materials for compound fertilizer. During the treatment process, there is no discharge of the three wastes, which meets the requirements of harmless treatment. Finally, these results provide important reference values for PHH production enterprises to solve the problems of waste pollution and to achieve recycling of resources.

Description: Energies, Vol. 10, Pages 1706: Field Measurement and Evaluation of the Passive and Active Solar Heating Systems for Residential Building Based on the Qinghai-Tibetan Plateau Case Energies doi: 10.3390/en10111706 Authors: Zhijian Liu Di Wu Miao Jiang Hancheng Yu Wensheng Ma Passive and active solar heating systems have drawn much attention and are widely used in residence buildings in the Qinghai-Tibetan plateau due to its high radiation intensity. In fact, there is still lack of quantitative evaluation of the passive and active heating effect, especially for residential building in the Qinghai-Tibetan plateau areas. In this study, three kinds of heating strategies, including reference condition, passive solar heating condition and active solar heating condition, were tested in one demonstration residential building. The hourly air temperatures of each room under different conditions were obtained and analyzed. The results show the indoor air temperature in the living room and bedrooms (core zones) was much higher than that of other rooms under both passive and active solar heating conditions. In addition, the heating effect with different strategies for core zones of the building was evaluated by the ratio of indoor and outdoor degree hour, which indicates that solar heating could effectively reduce the traditional energy consumption and improve the indoor thermal environment. The passive solar heating could undertake 49.8% degree hours for heating under an evaluation criterion of 14 °C and the active solar heating could undertake 75% degree hours for heating under evaluation criterion of 18 °C, which indicated that solar heating could effectively reduce the traditional energy consumption and improve the indoor thermal environment in this area. These findings could provide reference for the design and application of solar heating in similar climate areas.

Description: Materials, Vol. 11, Pages 1233: Effects of Temperature and Strain Rate on the Fracture Behaviors of an Al-Zn-Mg-Cu Alloy Materials doi: 10.3390/ma11071233 Authors: Yue Guo Mingxing Zhou Xingdong Sun Long Qian Lijia Li Yingjie Xie Zeyang Liu Di Wu Liguo Yang Tong Wu Dan Zhao Jinguo Wang Hongwei Zhao Effects of temperature and strain rate on the fracture behaviors of an Al-Zn-Mg-Cu alloy are investigated by isothermal uniaxial tensile experiments at a wide range of temperatures and strain rates, from room temperature (RT) to 400 °C and from 10−4 s−1 to 10−1 s–1, respectively. Generally, the elevation of temperature leads to the increasing of elongation to fracture and the reduction of peak stress, while higher strain rate results in the decreasing of elongation to fracture and the increasing of peak stress. Interestingly, we found that the coefficient of strain rate sensitivity (m-value) considerably rises at 200 °C and work of fracture (Wf) fluctuates drastically with the increase of strain rate at RT and 100 °C, both of which signify a non-uniform and unstable deformation state below 200 °C. A competition of work hardening (WH) and dynamic recrystallization (DRX) exists at 200 °C, making it serve as a transitional temperature. Below 200 °C, WH is the main deformation mechanism of flow stress, and DRX dominates the flow stress above 200 °C. It has been found that from RT to 200 °C, the main feature of microstructure is the generation of dimples and microvoids. Above 200 °C, the coalescence of dimples and microvoids mainly leads to the failure of specimen, while the phenomenon of typically equiaxed dimples and nucleation appear at 400 °C. The observations of microstructure are perfectly consistent with the related macroscopic results. The present work is able to provide a comprehensive understanding of flow stress of an Al-Zn-Mg-Cu alloy at a wide range of temperatures and strain rates, which will offer valuable information to the optimization of the hot forming process and structural design of the studied alloy.

Description: This paper presents a hierarchical classification approach for Synthetic Aperture Radar (SAR) images. The Conditional Random Field (CRF) and Bayesian Network (BN) are employed to incorporate prior knowledge into this approach for facilitating SAR image classification. (1) A multilayer region pyramid is constructed based on multiscale oversegmentation, and then, CRF is used to model the spatial relationships among those extracted regions within each layer of the region pyramid; the boundary prior knowledge is exploited and integrated into the CRF model as a strengthened constraint to improve classification performance near the boundaries. (2) Multilayer BN is applied to establish the causal connections between adjacent layers of the constructed region pyramid, where the classification probabilities of those sub-regions in the lower layer, conditioned on their parents’ regions in the upper layer, are used as adjacent links. More contextual information is taken into account in this framework, which is a benefit to the performance improvement. Several experiments are conducted on real ESAR and TerraSAR data, and the results show that the proposed method achieves better classification accuracy.

Description: Odor intensity (OI) indicates the perceived intensity of an odor by the human nose, and it is usually rated by specialized assessors. In order to avoid restrictions on assessor participation in OI evaluations, the Vector Model which calculates the OI of a mixture as the vector sum of its unmixed components’ odor intensities was modified. Based on a detected linear relation between the OI and the logarithm of odor activity value (OAV—a ratio between chemical concentration and odor threshold) of individual odorants, OI of the unmixed component was replaced with its corresponding logarithm of OAV. The interaction coefficient (cosα) which represented the degree of interaction between two constituents was also measured in a simplified way. Through a series of odor intensity matching tests for binary, ternary and quaternary odor mixtures, the modified Vector Model provided an effective way of relating the OI of an odor mixture with the lnOAV values of its constituents. Thus, OI of an odor mixture could be directly predicted by employing the modified Vector Model after usual quantitative analysis. Besides, it was considered that the modified Vector Model was applicable for odor mixtures which consisted of odorants with the same chemical functional groups and similar molecular structures.