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  • 1
    Publikationsdatum: 2019
    Beschreibung: The purpose of this article was to explore the influences of synthetic methods on the lignin-based carbon materials. In this paper, the lignin-based activated carbon materials were comparatively researched in ZnCl2 solution using various methods, including the microwave-assisted method, ultrasound method, and UV irradiation method, respectively. Scanning electron microscopy (SEM), Fourier transform infrared spectrometry (FT-IR), thermogravimetric analysis (TGA), and differential thermal analysis (DTA) were used to characterize the as-prepared samples. The effects of the synthetic parameters including the types of lignin, activated solution concentration, types of activated solution, and synthetic methods on the morphologies, thermal stability, and specific surface area of samples were comparatively investigated in detail. The specific surface area of lignin-based activated carbon increased to 473.8, 765.3, and 211.2 m2∙g−1 using the microwave-assisted method, ultrasound method, and UV irradiation method, respectively, compared with that of the control (113.4 m2∙g−1). The lignin-based carbon materials displayed the enhanced absorptive capacity, compared with that of the control. These novel synthetic methods reported here maybe have a guiding significance for the synthesis of carbon materials using the lignin as precursors.
    Digitale ISSN: 1996-1944
    Thema: Maschinenbau
    Publiziert von MDPI
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2019
    Beschreibung: To study the dynamic mechanical properties and fracture law of concrete after thermal treatment and reveal its mechanism, the impact compression test was carried out on different thermal-treated (400–800 °C) concrete specimens using a split Hopkinson pressure bas (SHPB) system. By using ANSYS/LS-DYNA, the finite element numerical simulation of the test process was illustrated. The research showed that under passive confining pressure, the more the loading rate is increased, the more obvious the effect of the passive confining pressure on the concrete specimen, as well as the more significant the improvement of the peak stress compared with the uniaxial test. On the other hand, as the temperature damage effect is enhanced, the increase in the material strength at different loading rates is reduced. Numerical simulations showed that in a uniaxial test, as the impact rate increases, the crack initiation time advances, and the degree of fracture increases at the same rate as that of the loading time. In the case of confining pressure, the stress gradually decreases to the edge from the center, and has a significant circumferential diffusion characteristic. The circumferential restraint of the passive confining pressure limits the radial deformation ability of the material to a certain extent, thereby increasing the axial compressive strength. In the analysis of the crushing process of concrete specimens, it was found that the fracture form showed a strong rate dependence. When the loading rate is low, the fracture form is a cleavage-like failure. As the loading rate increases, the fracture form changes to crush failure. The research results provide the necessary theoretical basis for the safety assessment, reinforcement, and maintenance of concrete structures after fire.
    Digitale ISSN: 1996-1944
    Thema: Maschinenbau
    Publiziert von MDPI
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2019
    Beschreibung: This study demonstrates the capability of a cloud model in simulating a real-world tornado using observed radiosonde data that define a homogeneous background. A reasonable simulation of a tornado event in Beijing, China, on 21 July 2012 is obtained. The simulation reveals the evolution of a descending reflectivity core (DRC) that has commonalities with radar observations, which retracts upward right before tornadogenesis. Tornadogenesis can be divided into three steps: the downward development of mesocyclone vortex, the upward development of tornado vortex, and the eventual downward development of condensation funnel cloud. This bottom-up development provides a numerical evidence for the growing support for a bottom-up, rapid tornadogenesis process as revealed by the state-of-the-art mobile X-band phase-array radar observations. The evolution of the simulated tornado features two replacement processes of three near-surface vortices coupled with the same midlevel updraft. The first replacement occurs during the intensification of the tornado before its maturity. The second replacement occurs during the tornado’s demise, when the connection between the midlevel mesocyclone and the near-surface vortex is cut off by a strong downdraft. This work shows the potential of idealized tornado simulations and three-dimensional illustrations in investigating the spiral nature and evolution of tornadoes.
    Digitale ISSN: 2073-4433
    Thema: Geologie und Paläontologie
    Publiziert von MDPI
    Standort Signatur Erwartet Verfügbarkeit
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