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  • 1
    Publication Date: 2017-09-05
    Description: Interpretations of paleomagnetic observations assume that naturally occurring magnetic particles can retain their primary magnetic recording over billions of years. The ability to retain a magnetic recording is inferred from laboratory measurements, where heating causes demagnetization on the order of seconds. The theoretical basis for this inference comes from previous models that assume only the existence of small, uniformly magnetized particles, whereas the carriers of paleomagnetic signals in rocks are usually larger, nonuniformly magnetized particles, for which there is no empirically complete, thermally activated model. This study has developed a thermally activated numerical micromagnetic model that can quantitatively determine the energy barriers between stable states in nonuniform magnetic particles on geological timescales. We examine in detail the thermal stability characteristics of equidimensional cuboctahedral magnetite and find that, contrary to previously published theories, such nonuniformly magnetized particles provide greater magnetic stability than their uniformly magnetized counterparts. Hence, nonuniformly magnetized grains, which are commonly the main remanence carrier in meteorites and rocks, can record and retain high-fidelity magnetic recordings over billions of years.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 2
    Publication Date: 2019-01-22
    Description: Paleomagnetic observations provide valuable evidence of the strength of magnetic fields present during evolution of the Solar System. Such information provides important constraints on physical processes responsible for rapid accretion of the protoplanetesimal disk. For this purpose, magnetic recordings must be stable and resist magnetic overprints from thermal events and viscous acquisition over many billions of years. A lack of comprehensive understanding of magnetic domain structures carrying remanence has, until now, prevented accurate estimates of the uncertainty of recording fidelity in almost all paleomagnetic samples. Recent computational advances allow detailed analysis of magnetic domain structures in iron particles as a function of grain morphology, size, and temperature. Our results show that uniformly magnetized equidimensional iron particles do not provide stable recordings, but instead larger grains containing single-vortex domain structures have very large remanences and high thermal stability—both increasing rapidly with grain size. We derive curves relating magnetic thermal and temporal stability demonstrating that cubes (〉35 nm) and spheres (〉55 nm) are likely capable of preserving magnetic recordings from the formation of the Solar System. Additionally, we model paleomagnetic demagnetization curves for a variety of grain size distributions and find that unless a sample is dominated by grains at the superparamagnetic size boundary, the majority of remanence will block at high temperatures (∼100 °C of Curie point). We conclude that iron and kamacite (low Ni content FeNi) particles are almost ideal natural recorders, assuming that there is no chemical or magnetic alteration during sampling, storage, or laboratory measurement.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 3
    Publication Date: 2017-11-29
    Description: Nonideal, nonsingle-domain magnetic grains are ubiquitous in rocks; however, they can have a detrimental impact on the fidelity of paleomagnetic records—in particular the determination of ancient magnetic field strength (paleointensity), a key means of understanding the evolution of the earliest geodynamo and the formation of the solar system. As a consequence, great effort has been expended to link rock magnetic behavior to paleointensity results, but with little quantitative success. Using the most comprehensive rock magnetic and paleointensity data compilations, we quantify a stability trend in hysteresis data that characterizes the bulk domain stability (BDS) of the magnetic carriers in a paleomagnetic specimen. This trend is evident in both geological and archeological materials that are typically used to obtain paleointensity data and is therefore pervasive throughout most paleomagnetic studies. Comparing this trend to paleointensity data from both laboratory and historical experiments reveals a quantitative relationship between BDS and paleointensity behavior. Specimens that have lower BDS values display higher curvature on the paleointensity analysis plot, which leads to more inaccurate results. In-field quantification of BDS therefore reflects low-field bulk remanence stability. Rapid hysteresis measurements can be used to provide a powerful quantitative method for preselecting paleointensity specimens and postanalyzing previous studies, further improving our ability to select high-fidelity recordings of ancient magnetic fields. BDS analyses will enhance our ability to understand the evolution of the geodynamo and can help in understanding many fundamental Earth and planetary science questions that remain shrouded in controversy.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 4
    Publication Date: 2016-07-31
    Description: The thermal demagnetization of pseudo-single-domain (PSD) magnetite (Fe 3 O 4 ) particles, which govern the magnetic signal in many igneous rocks, is examined using off-axis electron holography. Visualization of a vortex structure held by an individual Fe 3 O 4 particle (~250 nm in diameter) during in situ heating is achieved through the construction and examination of magnetic-induction maps. Step-wise demagnetization of the remanence-induced Fe 3 O 4 particle upon heating to above the Curie temperature, performed in a similar fashion to bulk thermal demagnetization measurements, revealed its vortex state remains stable under heating close to its unblocking temperature, and is recovered upon cooling with the same or reversed vorticity. Hence, the PSD Fe 3 O 4 particle exhibits thermomagnetic behavior comparable to a single-domain carrier, and thus vortex-states are considered reliable magnetic recorders for paleomagnetic investigations.
    Print ISSN: 0094-8276
    Electronic ISSN: 1944-8007
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 5
    Publication Date: 2019
    Description: We determine the role of particle shape in the type of magnetic extraction processes used in mining. We use a micromagnetic finite element method (FEM) to analyze the effect of external magnetic fields on the magnetic structures of sub-micron magnetite particles. In non-saturating fields, the magnetite particles contain multiple possible non-uniform magnetization states. The non-uniformity was found to gradually disappear with increasing applied field strength; at 100 mT the domain structure became near uniform; at 300 mT the magnetic structure saturates and the magnetization direction aligned with the field. In magnetic separation techniques, we suggest that 100 mT is the optimal field for magnetite to maximize the magnetic field with the lowest energy transfer; larger particles, i.e., 〉1 µm, will likely saturate in smaller fields than this. We also examined the effect of external magnetic fields on a much larger irregular particle (L × W × H = 179.5 × 113 × 103 μm) that was too large to be examined using micromagnetics. To do this we used COMSOL. The results show the relative difference between the magnitude of magnetic flux density of the particle and that of a corresponding sphere of the same volume is 〈5% when the distance to the particle geometry center is more than five times the sphere radius. The ideas developed in this paper have the potential to improve magnetic mineral extraction yield.
    Electronic ISSN: 2076-3263
    Topics: Geosciences
    Published by MDPI
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  • 6
    Publication Date: 2015-08-07
    Description: The effect of maghemization on the magnetic properties of magnetite (Fe 3 O 4 ) grains in the pseudo-single-domain (PSD) size range is investigated as a function of annealing temperature. X-ray diffraction and transmission electron microscopy confirms the precursor grains as Fe 3 O 4 ranging from ∼ 150 nm to ∼ 250 nm in diameter, whilst Mössbauer spectrometry suggests the grains are initially near-stoichiometric. The Fe 3 O 4 grains are heated to increasing reaction temperatures of 120 – 220 ºC to investigate their oxidation to maghemite (γ-Fe 2 O 3 ). High-angle annular dark field imaging and localized electron energy-loss spectroscopy reveals slightly oxidized Fe 3 O 4 grains, heated to 140 ºC, exhibit higher oxygen content at the surface. Off-axis electron holography allows for construction of magnetic induction maps of individual Fe 3 O 4 and γ-Fe 2 O 3 grains, revealing their PSD (vortex) nature, which is supported by magnetic hysteresis measurements, including first-order reversal curve analysis. The coercivity of the grains is shown to increase with reaction temperature up to 180 ºC, but subsequently decreases after heating above 200 ºC; this magnetic behavior is attributed to the growth of a γ-Fe 2 O 3 shell with magnetic properties distinct from the Fe 3 O 4 core. It is suggested there is exchange coupling between these separate components that results in a vortex state with reduced vorticity. Once fully oxidized to γ-Fe 2 O 3 , the domain states revert back to vortices with slightly reduced coercivity. It is argued that due to a core/shell coupling mechanism during maghemization, the directional magnetic information will still be correct, however, the intensity information will not be retained. This article is protected by copyright. All rights reserved.
    Electronic ISSN: 1525-2027
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 7
    Publication Date: 2015-12-16
    Description: As samples of ever decreasing sizes are being studied paleomagnetically, care has to be taken that the underlying assumptions of statistical thermodynamics (Maxwell-Boltzmann statistics) are being met. Here, we determine how many grains and how large a magnetic moment a sample needs to have to be able to accurately record an ambient field. It is found that for samples with a thermoremanent magnetic moment larger than 10 −11 Am 2 the assumption of a sufficiently large number of grains is usually given. Standard 1 inch diameter paleomagnetic samples usually contain enough magnetic grains such that statistical errors are negligible, but ‘single silicate crystal’ works on, for example, zircon, plagioclase and olivine crystals are approaching the limits of what is physically possible, leading to statistic errors in both the angular deviation and paleointensity that are comparable to other sources of error. The reliability of nano-paleomagnetic imaging techniques capable of resolving individual grains (used, for example, to study the cloudy zone in meteorites), however, is questionable due to the limited area of the material covered.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 8
    Publication Date: 2015-02-20
    Description: Paleointensity estimates provide much needed information on field generation within Earth's core and upon the convective processes at work within the mantle. We present new paleointensity estimates from the early Cretaceous Etendeka large igneous province in Namibia (~135Ma) which add to the sparse southern hemisphere dataset. The Early Cretaceous marks an important change in the Earth's magnetic field from a state of rapid polarity reversals, to one of long-term stability associated with the onset of the Cretaceous Normal Superchron at c. 121Ma. Paleointensity determinations, using the IZZI protocol, were carried out on a total of 172 specimens from 14 sites encompassing the exposed stratigraphy of the Etendeka province. Numerous checks of data reliability were considered before results were accepted, including partial thermoremanent magnetisation (pTRM) checks and pTRM tail checks, hysteresis properties, thermomagnetic analyses, observations under reflected light, and changes to room-temperature susceptibility during the experiments. Following these checks a total of 64 individual samples from 5 sites were considered to provide reliable paleointensity determinations. These results were combined to provide site mean data with an overall average virtual dipole moment (VDM) for the study of 2.5 ± 1.0 x 10 22 Am 2 . This value equates to approximately 30% of present Earth's field and, when considered alongside existing studies, suggests that Earth's field strength was low in the time leading up to the Cretaceous normal superchron. This article is protected by copyright. All rights reserved.
    Electronic ISSN: 1525-2027
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 9
    Publication Date: 2015-10-30
    Description: A new method to determine the atomic attempt time τ 0 of magnetic relaxation of fine particles, which is central to rock and soil magnetism and paleomagnetic recording theory, is presented, including the determination of its temperature dependence, and simultaneously the grain-size distribution of a sample. It is based on measuring a series of zero-field magnetic viscous decay curves for saturation isothermal remanent magnetization at various different temperatures, that are later joined together on a single grain-size scale from which the grain-size distribution and attempt time are determined. The attempt time was determined for three samples containing non-interacting, single-domain titanomagnetites of different grain-sizes for temperatures between 27 K and 374 K. No clear temperature-dependent trend was found, however, values varied significantly from one sample to the other: from 10 −11 s to 10 −8 s; in particular, the sample containing multiple magnetic phases had an effective attempt time significantly lower than the more homogeneous samples, thereby questioning the applicability of the simple Néel-Arhennius equation for magnetic relaxation for composite materials.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 10
    Publication Date: 2019
    Description: Abstract The Day diagram is used extensively in rock magnetism for domain state diagnosis. It has been shown recently to be fundamentally ambiguous for 10 sets of reasons. This ambiguity highlights the urgency for adopting suitable alternative approaches to identify the domain state of magnetic mineral components in rock magnetic studies. We evaluate 10 potential alternative approaches here and conclude that four have value for identifying data trends, but, like the Day diagram, they are affected by use of bulk parameters that compromise domain state diagnosis in complex samples. Three approaches based on remanence curve and hysteresis loop unmixing, when supervised by independent data to avoid nonuniqueness of solutions, provide valuable component‐specific information that can be linked by inference to domain state. Three further approaches based on first‐order reversal curve diagrams provide direct domain state diagnosis with varying effectiveness. Environmentally important high‐coercivity hematite and goethite are represented with variable effectiveness in the evaluated candidate approaches. These minerals occur predominantly in noninteracting single‐domain particle assemblages in paleomagnetic contexts, so domain state diagnosis is more critical for ferrimagnetic minerals. Treating the high‐coercivity component separately following normal rock magnetic procedures allows focus on the more vexing problem of diagnosing domain state in ferrimagnetic mineral assemblages. We suggest a move away from nondiagnostic methods based on bulk parameters and adoption of approaches that provide unambiguous component‐specific domain state identification, among which various first‐order reversal curve‐based approaches provide diagnostic information.
    Print ISSN: 2169-9313
    Electronic ISSN: 2169-9356
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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