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  • International Union of Crystallography (IUCr)  (1)
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    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 52 (1996), S. 453-455 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: The structure of the title compound [N,N'-methylenedipyridinium 1-iodononahydro-closo-decaborate(2-), C11H12N2+2.B10H9I2−] has been determinated by single-crystal X-ray diffraction at room temperature. This is the first halogeno derivative of closo-[B10H10]2− with the substituent in the apical position. The square pyramid with the capping ipso-B atom is slightly compressed. The B—I distance of 2.209 (6) Å in [1-IB10H9]2− is significantly shorter than the distance of 2.230 (2) Å in the [2-IB10H9]2− isomer.
    Type of Medium: Electronic Resource
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