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  • 1
    Publication Date: 2019-07-17
    Description: ABSTRACT. We investigated the large-scale (10–1000m) and small-scale (mm–cm) variations in size, number and arrangement of air bubbles in the EPICA Dronning Maud Land (EDML) (Antarctica) ice core, down to the end of the bubble/hydrate transition (BHT) zone. On the large scale, the bubble number density shows a general correlation with the palaeo-temperature proxy, d18O, and the dust concentration, which means that in Holocene ice there are fewer bubbles than in glacial ice. Small-scale variations in bubble number and size were identified and compared. Above the BHT zone there exists a strong anticorrelation between bubble number density and mean bubble size. In glacial ice, layers of high number density and small bubble size are linked with layers with high impurity content, identified as cloudy bands. Therefore, we regard impurities as a controlling factor for the formation and distribution of bubbles in glacial ice. The anticorrelation inverts in the middle of the BHT zone. In the lower part of the BHT zone, bubble-free layers exist that are also associated with cloudy bands. The high contrast in bubble number density in glacial ice, induced by the impurities, indicates a much more pronounced layering in glacial firn than in modern firn.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 2
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    INT GLACIOL SOC
    In:  EPIC3Journal of Glaciology, INT GLACIOL SOC, 59(218), pp. 1163-1169, ISSN: 0022-1430
    Publication Date: 2019-07-17
    Description: A new densification model, which simulates the effect of impurities on the densification of polar firn, is presented. The classical densification models of Herron and Langway (1980) and Pimienta and Barnola (Barnola and others, 1991) are modified by assuming that the activation energy for deformation is reduced by the impurities. Motivated by recent observations, the impurity effect is formulated on an empirical basis using the seasonally varying Ca2+ ion concentration. Excellent agreement between simulated and measured high-resolution density profiles confirms the new approach. The same parameterization applies for Greenland and Antarctica despite the one order of magnitude difference in impurity concentration. The new models allow us, for the first time, to simulate the density layering in firn down to the firn–ice transition. Our results emphasize the importance of impurities and density layering for the air entrapment and for dating gas records of deep ice cores, in particular for glacial climate conditions where the impurity concentrations are 10–100-fold higher than in modern firn.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 3
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    INT GLACIOL SOC
    In:  EPIC3Journal of Glaciology, INT GLACIOL SOC, 58(210), pp. 761-766, ISSN: 0022-1430
    Publication Date: 2019-07-17
    Description: Measurements of N2/O2 ratios inside individual air bubbles in various depths of the EDML ice core are presented here. The small bubbles (diameter below ~200 μm) in deeper ice are significantly enriched in O2 compared to the larger bubbles. The N2/O2 ratios show a systematic dependence on bubble size which is not the case for bubbles in shallower ice. This is interpreted as an effect of pressure relaxation during storage of the cores.
    Repository Name: EPIC Alfred Wegener Institut
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