Publication Date:
2012-01-01
Description:
This paper investigated the layered manganese dioxide with hydrate (MnO2⋅xH2O) deposits onto nitrogen-containing carbon nanotube (CNxNTs) as a hierarchical electrode for an energy-storage device. The dense and entangled CNxNTs were directly grown by microwave plasma-enhanced chemical vapor deposition (MPECVD) on a carbon cloth (CC), and subsequently used as a current collector. By controlling the pH value of KMnO4precursor solution, and incorporating nitrogen into CNTs as a reducing agent, the MnO2thin layer was uniformly fabricated on the CNxNTs at room temperature by using a spontaneous reduction method. The role of incorporation nitrogen is not only capable of creating active sites on the CNT surface, but can also donate electrons to reduceMnO4-to MnO2spontaneously. From the measurements of cyclic voltammograms and galvanostatic charge/discharge, MnO2/CNxNTs/CC composite electrodes illustrated excellent specific capacitance of 589.1 Fg-1. The key factor for high performance could be attributed to the thin-layered MnO2nanostructure, which resulted in the full utilization of MnO2deposits. Hence, the hierarchically porous MnO2/CNxNTs/CC electrodes exhibited excellent capacitive behavior for electrochemical capacitor application.
Print ISSN:
2090-3529
Electronic ISSN:
2090-3537
Topics:
Chemistry and Pharmacology
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Electrical Engineering, Measurement and Control Technology
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