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  • 16-crown-5 derivatives  (1)
  • Cutaneous thermoreceptor  (1)
  • Springer  (2)
  • Hindawi
  • MDPI Publishing
  • Molecular Diversity Preservation International (MDPI)
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Publisher
  • Springer  (2)
  • Hindawi
  • MDPI Publishing
  • Molecular Diversity Preservation International (MDPI)
Years
  • 1
    ISSN: 1432-1254
    Keywords: Sweating ; Infrared irradiation ; Spectral region ; Cutaneous thermoreceptor ; Skin temperature
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Abstract In an attempt to detect differences in the thermal effect of infrared irradiation of different wavelengths, transient sweating response to infrared irradiation in various spectral regions was examined. In Series 1, the ventral or dorsal surface of the nude subject was irradiated repetitively for a period of 4 min (2 min on, 2 min off) by each of three kinds of infrared heaters with main emissivity in ‘near-infrared’ (NIR; 0.7–2.8 μm), ‘intermediate-infrared’ (MIR; 1.5–5.8 μm), and ‘far-infrared’ (FIR; 2.8–25 μm) regions. The sweating response on a non-irradiated area tended to be the greatest with MIR, while the magnitude of the sweating response on the irradiated area showed no consistent differences among various wavelengths. The results infer that MIR stimulated cutaneous thomoreceptors most effectively, while its direct effect on local sweat gland activity was minimal. In Series 2, the effects of 9–12 min irradiations in more restricted ranges of wavelength were compared by the combination of the three kinds of heaters with filters (translucent to wavelength ranges of 1.3–2.7, 2.7–3.5, 3.6–8.0 μm, respectively). The sweating response on a remote area was predominantly greater with the range of 2.7–3.5 μm than with the other wavelength ranges, while the local effect on sweating was minimal with this range. The results of Series 2 reinforce those of Series 1, indicating that the degree of stimulation of cutaneous thermoreceptors and of direct thermal effect on sweat gland activity differ with spectral regions incident on the skin, thus affecting local and remote effects on the sweating response.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-1111
    Keywords: Solvent and lariat effect ; 16-crown-5 derivatives ; alkali metal ions ; complex stability ; conductometry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Formation constants (K ML) of 1:1 complexes of 15-(2,5-dioxahexyl)-15-methyl-16-crown-5 (L16C5) and 15,15-dimethyl-16-crown-5 (DM16C5) with alkali metal ions were determined in acetonitrile (AN) and propylene carbonate (PC) by conductometry at 25°C. Except for the case of Li+-and K+-16C5 complexes in PC, the selectivity sequences of L16C5 and DM16C5 are identical with those of the parent crown ether 16-crown-5 (16C5) regardless of the solvent (AN, PC, methanol) (Na1 〉 Li+ 〉 K+ 〉 Rb+ 〉 Cs+), which show the size-fit correlation. The selectivities of L16C5 and DM16C5 for the alkali metal ions are governed not by the sidearms but by the cavity size. The stability of the crown ether complex is dependent not on the dielectric constant but largely on the donor number of the solvent. TheK ML(M1 +)/K ML(M2 +) ratio of L16C5 or 16C5 varies very much with the solvent in the cases of M1=Na, M2=K and M1=Na, M2=Li, but that of DM16C5 is almost constant regardless of the solvent.
    Type of Medium: Electronic Resource
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