ALBERT

Description: 〈span〉〈div〉Abstract〈/div〉This study examines rainfall variations of the Mid-Carnian Pluvial Episode (CPE) based on the continental fluvial sedimentology, palaeosol and clay mineralogy records of the Stable Meseta (eastern Spain). In the formation examined, the Manuel Fm or K2 Fm, the CPE is represented by three regressive–transgressive sequences, or subunits K2.1, K2.2 and K2.3, from base to top. Each subunit broadly consists of a genetic stratigraphic sequence bearing well-developed highstand, lowstand and transgressive systems tracts. Hydromorphic features in the palaeosols suggest changes in the activity of both groundwater and surface water. The clay mineral assemblage is dominated by illite, with a minor presence of kaolinite and traces of smectite in some samples. After ruling out tectonism in the study area, climate and eustatism emerge as the main allogenic controls in the sedimentary record. Differentiated sedimentary facies and architectural elements in the K2.2 subunit were probably controlled by both a more humid climate and source area, whereas K2.1 and K2.3 were more related to base-level changes and eustatic control. The presence of more waterlogged pedotypes and of kaolinite and traces of smectite in the clay mineral assemblage of K2.2 also indicates increased humidity. Notwithstanding, our data do not point to intense rainfall periods for the CPE in eastern Spain.〈/span〉

Description: High-quality images provided by 3D seismic surveys have transformed the interpretations of salt geometries in passive margins. Complementary field studies are needed to expand the ideas derived from seismic image interpretation. The Cotiella Basin exposes middle Coniacian–early Santonian basins developed by post-rift gravity-driven extension and passive diapirism in the proto-Atlantic Ocean. Salt-related sedimentary and structural features were preserved during the subsequent Pyrenean Orogeny, but the diapirs were squeezed to such a degree that they were completely destroyed. As a result, their influence on the development of the Cotiella Basin remains unclear. This paper presents a 3D geometric reconstruction of the extensional faults, the stratigraphic surfaces and the associated salt structures with the main objective of discussing the role of extension versus salt withdrawal. Our results indicate that the main Cotiella Basin was dominated by extensional faulting combined with along-strike salt migration, whereas the smaller Armeña, Mediodía and Seira basins were mainly dominated by salt withdrawal, involving the growth of passive diapirs, salt pillows and transfer faults. This is relevant because the described structures constitute an almost unique example to study in outcrop the structural style and kinematics of structures usually found offshore.

Description: Iron occurs naturally as Fe2+, Fe3+, and, to a lesser extent, as Fe0. Many fundamental (bio)geochemical processes are based on redox cycling between these oxidation states. Mossbauer spectroscopy provides quantitative information about the distribution of Fe among its oxidation states, identification of Fe-bearing phases, and relative distribution of Fe among those phases. Portable, miniaturised Mossbauer spectrometers were developed for NASA's Mars Exploration Rovers (in operation since 2004) and provide a means for non-destructive, in-situ field investigations. On Mars, these instruments provided evidence for aqueous activity with implications for habitability, were applied in geological mapping of the landing sites, and helped to identify meteorites, for example. On Earth, they were used in field studies of green rust, the identification of air pollution sources, or the study of archaeological artefacts. Their application to in-situ resource utilisation (ISRU) on the Moon has been demonstrated in a recent NASA field test of hardware for oxygen production. A new detector system in an advanced version of these instruments is based on Si Drift Detectors and permits the simultaneous acquisition of X-ray fluorescence spectra to determine elemental compositions.

Description: Th/U values in zircon are commonly used to discriminate between metamorphic (Th/U 〈 0.1) and magmatic (Th/U 〉 0.1) origin for zircon overgrowths. We test this hypothesis in the San Ciprián massif, a late orogenic granitic intrusion in the hinterland of the Variscan orogeny. Zircon grains from this granite have cores with inherited Ediacaran ages and Th/U 〉 0.1, whereas zircon mantles yield an age of about 287 Ma, interpreted as the time of crystallization of the granite, and have Th/U 〈 0.1. Hence, the San Ciprián massif presents an uncommon but unambiguous example of magmatic zircon mantles with Th/U values typical of metamorphic zircon. The most likely causes for the unusually low-Th/U zircon values in the San Ciprián massif are a combination of a U-rich magma composition (owing to a fractionation process) and the absence of other U-enriched accessory minerals. Our work in determining Th/U ratios substantiates the warning previously made by some researchers and precludes the use of Th/U values in zircon as an unequivocal indicator of metamorphic origin in the absence of other chemical, zircon morphology or field-based independent criteria. Supplementary materials: Code and data to generate Figures 1 and 5 are available at http://www.geolsoc.org.uk/SUP18885 .

Description: Sedimentary facies is a key control on petrophysical properties within subsurface reservoirs and facies modelling is a critical aspect of reservoir modelling. Several modelling methods exist and selecting the best approach for a specific case is challenging and time-consuming. Outcrop analogues provide detailed information on architecture, geometry and facies connectivity that is not directly available in the subsurface. By modelling outcrop data it is possible to test and compare different modelling strategies systematically in a case where the geology is well constrained. The Eocene aged, Sant Llorenc del Munt fan-delta complex (NE Spain) is a well exposed, transgressive-regressive fan-delta. Outcrop data were used to test a variety of modelling strategies in which the density of conditioning wells, stratigraphic subdivision, modelling algorithm and trends were all varied. The results of these modelling exercises were compared against themselves and against a close-to-deterministically built Base Case reconstruction using a series of static measures including the distribution of fan-delta front reservoir facies, directional connectivity and reservoir-to-well connectivity. The results highlight the following: (a) the impact of the conditioning well density on improving the stratigraphic architecture reproduction in the different modelling approaches; (b) that surface-based modelling subdivisions including the maximum flooding surface to separate independent grids for modelling the transgressive and regressive sequence sets can be detrimental when compared to using only the top and base of the composite sequence unless additional constraints are included; (c) that an algorithm combining a linear trend and a Gaussian field is the most suitable algorithm for reproducing this type of architecture, but requires defining a 3D trend; and (d) the need for using trends to reproduce the architecture when well data are sparse. These results provide guidelines for modelling analogue fan-delta reservoirs in the subsurface.

Description: A multidisciplinary study (U–Pb sensitive high-resolution ion microprobe geochronology, Hf and O isotopes in zircon, Sr and Nd isotopes in whole-rocks, as well as major and trace element geochemistry) has been carried out on granitoid samples from the area west of Valcheta, North Patagonian Massif, Argentina. These confirm the Cambrian age of the Tardugno Granodiorite (528 ± 4 Ma) and the Late Permian age of granites in the central part of the Yaminué complex (250 Ma). Together with petrological and structural information for the area, we consider a previously suggested idea that the Cambrian and Ordovician granites of northeastern Patagonia represent continuation of the Pampean and Famatinian orogenic belts of the Sierras Pampeanas, respectively. Our interpretation does not support the hypothesis that Patagonia was accreted in Late Palaeozoic times as a far-travelled terrane, originating in the Central Transantarctic Mountains, and the arguments for and against this idea are reviewed. A parautochthonous origin is preferred with no major ocean closure between the North Patagonian Massif and the Sierra de la Ventana fold belt. Supplementary material: U–Pb SHRIMP analytical data, geochemical analyses and sample global positioning system locations are available at www.geolsoc.org.uk/SUP18722 .

Description: In this paper, we present the first palaeomagnetic data (51 sites) for Mesozoic (Lower–Middle Jurassic) sediments of the Moroccan Central High Atlas and address the study of a widespread remagnetization. The remagnetization is characterized by a very stable component with systematic normal polarity, carried by magnetite. The relationship between the magnetic properties and location within the basin suggests that the acquisition of the remagnetization is controlled by basin geometry. Fold-tests indicate that the overprint acquisition is syn-folding in some structures but clearly predates the Tertiary compressional stage. Using the small circle intersection method we have calculated the remagnetization direction ( D = 336.4°, I = 29.2°). Comparison with the global apparent polar wander path indicates that the remagnetization was acquired during the Late Cretaceous (probably Cenomanian). Considering both the basinal confinement of remagnetization and the connection with other remagnetization events in the western Tethys, we propose a scenario explaining widespread remagnetizations in the region, concerning both basin-scale conditions mainly related to sediment thickness and a regional-scale thermal event acting as catalyst of remagnetizations in those sedimentary basins that satisfy the basin-scale conditions.

Description: 〈p〉Many archaeological sites with jadeitite artefacts are known in the Caribbean region, but defining the source of the raw material is a major problem because of great mineralogical heterogeneity both in potential sources and in artefacts. The archaeological settlement site of Playa Grande on the northern coast of the Dominican Republic is particularly significant because it yielded evidence of on-site axe manufacture, and lies only 20–30 km NE of a recently discovered potential source area of serpentinite mélanges in the nearby Río San Juan Complex (RSJC). A suite of nine artefacts was chosen from a collection of over 100 excavated woodworking tools rich in jadeite, as well as two blueschist artefacts. Permission to perform destructive analysis allowed data on petrography, mineral chemistry and bulk-rock chemistry to be obtained. Seven of the nine artefacts are jadeitite 〈i〉sensu stricto〈/i〉 (〉90 vol% jadeite), which are identical to material known from the RSJC. Two artefacts are jadeite–lawsonite rocks. These and the two blueschists show only minor differences from corresponding rocks of the RSJC source. With this direct linking of source and site material, it is now possible to better define source discriminators for the Caribbean and to assess sampling bias.〈/p〉

Description: 〈span〉〈div〉Abstract〈/div〉The resolution of data acquired over modern seafloors does not allow imaging of the inner features of a fluid seep structure, particularly in the shallow subsurface. In the SE Basin of France (Drôme), fossil cold seep structures comprising fossil-rich carbonate lenses were identified about 30 years ago within the Oxfordian (Late Jurassic) Terres Noires Formation. These structures were first interpreted as pseudo-bioherms related to hydrothermal activity, but comparison with active seep sites on modern margins, together with isotopic analyses, led to a reinterpretation involving cold fluids instead. To date, all seep sites have generally been studied individually without considering any link to neighbouring or more distant sites. Based on 23 high-resolution stratigraphic logs within the structure coupled to mosaicked aerial photographs from a drone survey, 19 fluid seep events were correlated in the area, including two new sites exposed as a result of weathering. We have shown that each identified sub-site is composed of subvertically stacked fossil-rich carbonate lenses interbedded with marls, which developed in smooth, 4–6 m deep depressions beneath the local seabed. The nodules present within the depressions are of primary importance as they mark the area of active seeping. This general organization is very similar to the modern Regab giant pockmark in the Lower Congo Basin where only a few sub-sites are active at the same time. A spatio-temporal 3D reconstruction of the position of these sub-sites shows that the carbonate lenses are organized into clusters comprising up to seven sub-sites grouped together in the same stratigraphic interval and the same geographical zone. A sandbox experiment where gas is injected at constant flow rate at the base of a box filled with a matrix of water-saturated grains displays a pattern consisting of disturbed sediments inside a parabolic-shaped area. This parabolic shape was also identified on a seismic profile across the Regab giant pockmark, suggesting that the processes are similar for the Beauvoisin and Regab seep areas. The laboratory experiments also show that the seeping conduit is stable during a given period of time and suddenly shifts laterally. This is mainly as a result of the collapse of the conduit, the lateral migration and the reopening at a new position. The general log obtained in the Beauvoisin seep area suggests a similar pattern with periods of seeping alternating with periods of quiescence, each of which is 〈span〉c〈/span〉. 200 kyr. Even if a pockmark seems to have been inactive for a long period of time, this could be due to the lateral shift of the feeder conduit, meaning that the sub-seafloor is still charged with gas. This is of primary importance for risk assessment, hydrocarbon exploration and general understanding of geobiology at seafloor seeps.〈/span〉

Description: 〈p〉Size distribution and evolution of framboidal and euhedral microscopic crystals of pyrite (micropyrites, MPy) have been used for the last thirty years to deduce palaeo-redox conditions. The analysis of the MPy distributions can give valuable information about these palaeo-redox conditions. However, other information can also be retrieved from this type of analysis. In this work, we propose that the formation of new populations of MPy is a proxy of the transition from the anchizone to the epizone. High-resolution X-ray tomography (micro-CT) was used to determine the size distributions of MPy hosted in pelitic rocks subjected to different grades of low temperature metamorphism. These data were filtered and statistically analysed, which allowed us to find a statistical representative size distribution of the MPy present in the samples. The metamorphic grade was determined using the Kübler Index in combination with petrological and scanning electron microscopy (SEM) examination. The results show a relationship between metamorphic grade and MPy size distributions, and that new populations of MPy formed due to the effects of metamorphism. This new methodology for MPy size distribution has different potential applications in some fields of Earth sciences, such as palaeoenvironment reconstruction, ore mining or metamorphic petrology.〈/p〉