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  • Geological Society of London  (1)
  • Schweizerbart  (1)
  • 1
    Publikationsdatum: 2015-12-02
    Beschreibung: Monohydrocalcite (MHC, CaCO 3 ·H 2 O) is a thermodynamically metastable phase relative to calcite and aragonite in aqueous solution. Although MHC occurs broadly in organisms, little information about its biogenic origin is available. In this paper, a series of amorphous calcium carbonates (ACCs) with different Mg 2+ contents were first synthesized in the presence of polyaspartic acid (PASP), and the phase transformations of the PASP-regulated Mg-ACCs (PASP-Mg-ACCs) were then studied under different medium conditions. The structure, morphology and composition of the precursor PASP-Mg-ACCs and transformation products were investigated by using a wide range of techniques, including XRD, FT-IR, FESEM, TG-DTA, 13 C NMR and ICP-AES. Our results show that PASP-Mg-ACC with 24.71 mol% Mg 2+ can be transformed into MHC, without formation of hydromagnesite or other hydrated magnesium carbonates, whereas the PASP-Mg-ACCs with 〈24 mol% Mg 2+ resulted in magnesian calcite and aragonite. Time-course transition experiments unveiled that the transformation from PASP-Mg-ACCs to crystalline phases proceeds through the dissolution of the initial precursor PASP-Mg-ACCs and the subsequent crystallization of the secondary mineral phases. The formation of different secondary minerals depends not only on the Mg 2+ but also on the PASP content in precursor PASP-Mg-ACCs. Because of the exclusive formation of MHC from PASP-Mg-ACC under current biomimetic conditions, biomacromolecule-regulated Mg-ACC may act as the transient precursor and be responsible for the biogenesis of MHC. The current results contribute to the elucidation of the biogenic origin and role of MHC in nature.
    Print ISSN: 0935-1221
    Digitale ISSN: 1617-4011
    Thema: Geologie und Paläontologie
    Publiziert von Schweizerbart
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2017-11-17
    Beschreibung: The Dexing copper mine is the largest open pit copper mines in Asia, with mining and beneficiation history stretching back more than half a century; consequently it has large amounts of ore tailings. The mineralogy, chemical composition and distribution of elements in the impounded tailings are of great significance to the future utilization and reclamation of the tailings ponds. In total, 1400 tailing samples from 35 drill cores were collected from the 1 tailings pond at the Dexing copper mine. All samples were analyzed to determine their chemical composition. The particle size, XRD, pH and sequential extraction fractions of selected samples were determined. The silt-size fraction dominates the grain-size distribution. Quartz and sericite are the most abundant gangue minerals in the tailings, with medians of 54.3 and 23.7%, respectively. 3D modeling of the tailings pond suggests that the distribution of particle size, minerals and elements is mainly controlled by the gravitational separation during tailings discharge. Silica, Cu, Mo and Ti are enriched in the dam area of the tailings pond, whereas Al 2 O 3 and K 2 O are enriched in the impoundment area. The potential Cu, Ti and sericite reserves in the tailings pond were estimated at 38 149 tons, 142 175 tons and 8.15 million tons, respectively. The tailings are not significantly oxidized and so their environmental risk is low under the present circumstances. Their weak alkalinity and presence of carbonate minerals provide the tailings buffering capacity to weak acids. Sequential extraction data suggest that the mobility of elements in the tailings pond is low; however, about 6040 tons of Cu, 428 tons of Zn, 252 tons of Mo, 145 tons of As and 66 tons of Pb, may be released if the physicochemical conditions change and the tailings become acidic.
    Print ISSN: 1467-7873
    Digitale ISSN: 1467-7873
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Standort Signatur Erwartet Verfügbarkeit
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