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  • 13C NMR  (1)
  • Geodynamics and Tectonics  (1)
  • Oxford University Press  (1)
  • Wiley-Blackwell  (1)
  • Geological Society of America (GSA)
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Publisher
  • Oxford University Press  (1)
  • Wiley-Blackwell  (1)
  • Geological Society of America (GSA)
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  • 1
    Publication Date: 2015-04-17
    Description: Numerous regional plate reorganizations and the coeval ages of the Hawaiian Emperor bend (HEB) and Louisville bend of 50–47 Ma have been interpreted as a possible global tectonic plate reorganization at ~chron 21 (47.9 Ma). Yet for a truly global event we would expect a contemporaneous change in Africa absolute plate motion (APM) reflected by physical evidence distributed on the Africa Plate. This evidence has been postulated to take the form of the Réunion-Mascarene bend which exhibits many HEB-like features, such as a large angular change close to ~chron 21. However, the Réunion hotspot trail has recently been interpreted as a sequence of continental fragments with incidental hotspot volcanism. Here we show that the alternative Réunion-Mascarene Plateau trail can also satisfy the age progressions and geometry of other hotspot trails on the Africa Plate. The implied motion, suggesting a pivoting of Africa from 67 to 50 Ma, could explain the apparent bifurcation of the Tristan hotspot chain, the age reversals seen along the Walvis Ridge, the sharp curve of the Canary trail, and the diffuse nature of the St. Helena chain. To test this hypothesis further we made a new Africa APM model that extends back to ~80 Ma using a modified version of the Hybrid Polygonal Finite Rotation Method. This method uses seamount chains and their associated hotspots as geometric constraints for the model, and seamount age dates to determine APM through time. While this model successfully explains many of the volcanic features, it implies an unrealistically fast global lithospheric net rotation, as well as improbable APM trajectories for many other plates, including the Americas, Eurasia and Australia. We contrast this speculative model with a more conventional model in which the Mascarene Plateau is excluded in favour of the Chagos-Laccadive Ridge rotated into the Africa reference frame. This second model implies more realistic net lithospheric rotation and far-field APMs, but fails to explain key details of the Atlantic Ocean volcanic chains. Both models predict a Canary plume influence beneath the Madeiras. Neither model, when projected via the global plate circuit into the Pacific, predicts any significant change in plate motion around chron 21. Consequently, Africa APM models do not appear to provide independent support for a chron 21 global reorganization.
    Keywords: Geodynamics and Tectonics
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 25 (1987), S. 16-20 
    ISSN: 0749-1581
    Keywords: 13C NMR ; 13C Relaxation Times ; Prototropic equilibria ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Quaternary 13C dipole-dipole spin-lattice relaxation times are used to analyse prototropic equilibria of 2-acetylbenzimidazole (1) and 4-azabenzimidazole in DMSO-d6 solutions. For the first compound, fast exchange between the two chelated structures prevails for 13C relaxation times, whereas proton and 13C chemical shifts characterize a slow exchange. For 4-azabenzimidazole, 13C and 1H spectra do not exhibit absorptions from structures in slow exchange. Analysis of the T1 values of carbons 8 and 9 before and after isotopic exchange of the labile amino hydrogen clearly show that the major component of the equilibrium is the 3H structure.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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