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  • 1
    Publication Date: 2017-04-04
    Description: We present the first chlorine isotope compositional data for gases and lavas from Mount Etna (Italy), and to our knowledge, of active Mediterranean volcanism. We investigated lavas erupted and gases discharged during 2008-2011 from a high-temperature fumarole (HT; 〉300°C) and plume gases from both North East and Central Craters. Most of the samples vary in a narrow range of chlorine isotope composition (37Cl values ≈ 0 ± 0.7‰) with gases partially overlapping with rocks. Only HT gases sampled in 2009 have been clearly affected by secondary processes (37Cl values 〉 15.9‰), resulting in partial removal of chlorine and isotopic fractionation producing a 37Cl enrichment in the residual gaseous HCl. These secondary processes also affect, although to a lesser extent, plume gases from North East Crater (NEC). Although post-magmatic processes are able to modify the chlorine isotope composition, 37Cl values are not affected by magma degassing for residual fractions ≥ 0.3 in the melt, or any effect is within our data variability. Finally, 37Cl values and Cl/K ratios of magmatic chlorine constrain the Etnean source to be compatible with depleted mantle (DMM) contaminated by altered oceanic crust (AOC), in agreement with indications from more common isotopic tracers of mantle processes.
    Description: Published
    Description: 134-142
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Mount Etna ; chlorine isotope ; plume ; fumarole ; degassing ; mantle source ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: In this paper we present the first data of temperature continuously recorded in two fumarole fields (designated VOR and HOR) located in the summit area of Mount Etna volcano (Italy). The time series embraces two distinct periods: (1) October 2007 to November 2009, during which an effusive eruption occurred from May 2008 to July 2009, and (2) November 2011 to June 2012, characterized by the occurrence of strong paroxysms (fire fountains and lava flow). The analysis of the temperature signal in both the time and frequency domains, and its comparison with meteorological observations allowed us to separate the exogenous influences from the effects of variations in the activity state of the volcano. The acquired data were weakly affected by seasonal cycles of the air temperature and strongly affected by the rainfall. Optimization of site conditions (i.e., sensor depth and soil permeability) markedly reduced meteorological disturbances. The distance from the main degassing and/or eruptive fractures was crucial to maximizing the probability of the technical survival of the monitoring apparatus, which was seriously affected by the emission of acidic gases, tephra fallout, and lava flows. Apart from the exogenous influences, the most appreciable variation was observed at VOR, where a huge increase in fumarole temperature was detected immediately after the onset of the 2008–2009 eruption. Such an anomalous increase was attributed to the rapid ascent of magma feeding the eruptive fracture. Another abrupt increase in temperature was recorded at HOR in March and April 2012. During this period the frequency of paroxysm occurrence increased markedly, and this led us to hypothesize that the thermal anomaly was due to the intrusion of a new batch of magma in the conduits of the southeast crater. Medium- to long-term monitoring (weeks to months) of fumarole temperatures revealed variations that were attributed to pressurization/depressurization phases of the shallow volcanic system, which varied between the various monitored sectors of the volcano. Our observations suggest that continuous monitoring of fumarole temperature can give useful information about the activity of Mount Etna. Moreover, due to the complexity of its shallow plumbing system, we conclude that the monitoring systems should be extended to cover the entire fumarole network of the summit area.
    Description: Published
    Description: 12-20
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Continuous monitoring ; Mount Etna ; Fumarole temperature ; Meteorological parameters ; Volcanic Degassing ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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