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  • 1
    Publication Date: 2017-04-04
    Description: New Sr and Nd isotope data for whole rocks, glasses and minerals are combined to reconstruct the nature and origin of mixing end-members of the 200 km3 trachytic to phonolitic Campanian Ignimbrite (Campi Flegrei, Italy) magmatic system. The least-evolved magmatic end-member shows equilibrium between host glass and the majority of the phenocrysts and is less radiogenic in Sr and Nd than the most-evolved magma. On the contrary, only the Fe-rich pyroxene from the most-evolved erupted magma is in equilibrium with the matrix glass, while all other minerals are in isotopic disequilibrium. These magmas mixed prior to and during the Campanian Ignimbrite eruption and minerals were freely exchanged between the magma batches. Combining the results of the geochemical investigations on magma end-members with geophysical and geological data, we develop the following scenario. In stage 1, a parental, less differentiated magma rose into the middle crust, and evolved through combined crustal assimilation and crystal fractionation. In stage 2, the differentiated magma rose to shallower depth, fed the pre-Campanian Ignimbrite activity and evolved by further open-system processes into the most-evolved and most-radiogenic Campanian Ignimbrite end-member magma. In stage 3, new trachytic magma, isotopically distinct from the pre-Campanian Ignimbrite magmas, rose from ca. 6 km to shallower depth, recharged the most-evolved pre-Campanian Ignimbrite magma chamber, and formed the large and stratified Campanian Ignimbrite magmatic system. During the course of the Campanian Ignimbrite eruption, the two layers were tapped separately and/or simultaneously, and gave rise to the range of chemical and isotopic values displayed by the Campanian Ignimbrite pumices, glasses and minerals.
    Description: Published
    Description: 285-300
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Campanian Ignimbrite ; Radiogenic isotopes ; Mixing process ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 54 (1992), S. 404-410 
    ISSN: 1432-0630
    Keywords: 07.65 ; 35.00 ; 42.55 R
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A pump- and probe-beam technique is used for measuring time-resolved excited-state absorption (ESA) and stimulated-emission (SE) spectra of Er3+ doped YAlO3. The Er3+ 4 I 15/2 → 4 F 7/2 transition of the sample is excited at 488 nm by an excimer laser pumped dye laser. The ESA and SE of broadband xenon flashlamp light is monitored between 300 and 860 nm by an optical multichannel analyzer (OMA). The analysis of the experimental results provides information on the effective cross sections σESA and σSE originating from several levels and on the populations of these levels. To our knowledge this represents the first detailed investigation of time-resolved ESA and SE over a broad spectral range in rare-earth doped materials.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 297 (1979), S. 35-43 
    ISSN: 1618-2650
    Keywords: Altersbest. von geolog. Proben ; K/Ca-Methode, Calcium-Isotopenverhältnismessung, Thermionen-MS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Es wird ein analytisches Verfahren zur K/Ca-Altersbestimmung geologischer Proben beschrieben. Die zur Berechnung des Alters notwendigen Gleichungen werden abgeleitet und zwei alternative, analytische Verfahren der K/Ca-Methode hinsichtlich ihrer Genauigkeit diskutiert. Wichtigste Voraussetzung für die Anwendbarkeit des Verfahrens sind genaue Calcium-Isotopenverhältnismessungen, wobei das 40Ca/42Ca-Verhältnis für die Bestimmung des relativen radiogenen 40Ca-Anteils herangezogen wird. Das 42Ca/44Ca-Verhältnis wird als interner Standard zur Korrektur verwendet. Die Kalium- und Calciumbestimmungen in den Mineralien werden durch Flam-men-Atomemissionsspektrometrie mit einem internen Lithiumstandard bzw. durch massenspektrometrische Isotopenverdünnungsanalyse durchgeführt. Die Problematik der Kontamination bei der Aufarbeitung der Proben wird diskutiert. Die Ergebnisse der K/Ca-Datierung eines Langbeinits und eines Mikroklins stimmen gut mit denjenigen anderer Datierungsmethoden an den gleichen Proben überein. Die Reproduzierbarkeit des analytischen Verfahrens der K/Ca-Datierung wird an einigen Feldspäten gezeigt, wobei relative Standardabweichungen zwischen 1,8 und 7,6 % erreicht werden.
    Notes: Summary An analytical procedure for the K/Ca age determination of geological samples is described, the relevant equations are developed and two alternative analytical methods are discussed according to their precision. An important precondition for the feasibility of the K/Ca method is the measurement of precise Ca isotope ratios. The ratio 40Ca/42Ca is used to determine the relative radiogenic 40Ca portion, whereas the 42Ca/44Ca ratio is taken as an internal standard. K and Ca in minerals are determined by flame atomic emission spectrometry with an internal lithium standard and by isotope dilution mass spectrometry, respectively. The contamination problem during the reprocessing of the samples is discussed. The results achieved by dating a langbeinite and a microcline sample by the K/Ca method agree well with those achieved by other age determination methods. The standard deviation of the K/Ca method in analyzing several feldspars ranges from 1.8–7.6%.
    Type of Medium: Electronic Resource
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