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  • Elsevier  (28)
  • Springer  (18)
  • Nature Publishing Group  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 94 (1986), S. 461-471 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract A compositionally diverse suite of volcanic rocks, including tholeiites, phonolites, basanites and nephelinites, occurs as accidental blocks in the palagonitic tuff of Kaula Island. The Kaula phonolites are the only documented phonolites from the Hawaiian Ridge. Among the accidental blocks, only the phonolites and a plagioclase basanite were amenable to K-Ar age dating. They yielded ages of 4.0–4.2 Ma and 1.8±0.2 Ma, respectively. Crystal fractionation modeling of major and trace element data indicates that the phonolites could be derived from a plagioclase basanite by subtraction of 27% clinopyroxene, 21% plagioclase, 16% anorthoclase, 14% olivine, 4% titanomagnetite and 1% apatite, leaving a 16% derivative liquid. The nephelinites contain the same phenocryst, xenocryst and xenolith assemblages as the tuff. Thus, they are probably comagmatic. The strong chemical similarity of the Kaula nephelinites and basanites to those from the post-erosional stage Honolulu Group on Oahu, the presence of garnet-bearing pyroxenites in the Kaula nephelinites (which previously, had only been reported in the Honolulu volcanic rocks) and the similar age of the Kaula basanite to post-erosional lavas from nearby volcanoes are compelling evidence that the Kaula basanites and nephelinites were formed during a “post-erosional” stage of volcanism.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 95 (1987), S. 100-113 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Kohala Volcano, the oldest of five shield volcanoes comprising the island of Hawaii, consists of a basalt shield dominated by tholeiitic basalt, Pololu Volcanics, overlain by alkalic lavas, Hawi Volcanics. In the upper Pololu Volcanics the lavas become more enriched in incompatible elements, and there is a transition from tholeiitic to alkalic basalt. In contrast, the Hawi volcanics consist of hawaiites, mugearites, and trachytes. 87Sr/86Sr ratios of 14 Pololu basalts and 5 Hawi lavas range from 0.70366 to 0.70392 and 0.70350 to 0.70355, respectively. This small but distinct difference in Sr isotopic composition of different lava types, especially the lower 87Sr/86Sr in the younger lavas with higher Rb/Sr, has been found at other Hawaiian volcanoes. Our data do not confirm previous data indicating Sr isotopic homogeneity among lavas from Kohala Volcano. Also some abundance trends, such as MgO-P2O5, are not consistent with a simple genetic relationship between Pololu and Hawi lavas. We conclude that all Kohala lavas were not produced by equilibrium partial melting of a compositionally homogeneous source.
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 302 (1983), S. 785-789 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Haleakala Volcano consists of a tholeiitic basalt shield overlain by alkalic lavas. As a function of decreasing age, La/Ce, Ba/La, Nb/La, Rb/Sr and 143Nd/144Nd increase but Sm/Nd and 87Sr/86Sr decrease. Inverse correlations between these ...
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  • 4
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract At 39.5° S in the southern volcanic zone of the Andes three Pleistocene-recent stratovolcanoes, Villarrica, Quetrupillan and Lanin, form a trend perpendicular to the strike of the Andes, 275 to 325 km from the Peru-Chile trench. Basalts from Villarrica and Lanin are geochemically distinct; the latter have higher incompatible element abundances and La/Sm but lower Ba/La and alkali metal/La ratios. These differences are consistent with our previously proposed models involving: a) a west to east decrease in an alkali metal-rich, high Ba/La slab-derived component which causes an across strike decrease in degree of melting; or b) a west to east increase in the contamination of subduction-related magma by enriched subcontinental lithospheric mantle. Silicic and mafic lavas from the stratovolcanoes have overlapping Sr, Nd and O isotopic ratios. Silicic lavas also have geochemical differences that parallel those of their associated basalts, e.g., rhyolite from Villarrica has lower La/Sm and incompatible element contents than high-SiO2 andesite from Lanin. At each volcano the most silicic lavas can be modelled by closed system fractional crystallization while andesites are best explained by magma mixing. Apparently crustal contamination was not an important process in deriving the evolved lavas. Basaltic flows from small scoria cones, 20–35 km from Villarrica volcano have high incompatible element contents and low Ba/La, like Lanin basalts, but trend to higher K/Rb (356–855) and lower 87Sr/ 86Sr (0.70361–0.70400) than basalts from either stratovolcano. However all basalts have similar Nd, Pb and O isotope ratios. The best explanation for the unique features of the cones is that the sources of SVZ magmas, e.g., slab-derived fluids or melts of the subcontinental lithospheric mantle, have varying alkali metal and radiogenic Sr contents. These heterogeneities are not manifested in stratovolcano basalts because of extensive subcrustal pooling and mixing. This model is preferable to one involving crustal contamination because it can account for variable Sr isotope ratios and uniform Nd and Pb isotope ratios among the basalts, and the divergence of the cones from across-strike geochemical trends defined by the stratovolcanoes.
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  • 5
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Basaltic lavas from the AMAR Valley and the Narrowgate region of the FAMOUS Valley on the Mid-Atlantic Ridge (36° to 37° N) range in texture from aphyric to highly plagioclase phyric (〉25% large plagioclase phenocrysts). Based on 87Sr/86Sr and 143Nd/144Nd ratios, most of these lavas can be subdivided into two distinct, isotopically homogeneous, groups: Group I has lower 87Sr/86Sr (0.70288±1) and higher 143Nd/144Nd (0.51312±1) ratios; Group II has higher 87Sr/86Sr (0.70296±1) and lower 143Nd/144Nd (0.51309±2) ratios. Most Group II lavas are aphyric, whereas Group I lavas are primarily plagioclase phyric. Lavas from both groups show a wide range in incompatible element abundance ratios (e.g., Zr/Nb =6–29; (La/Sm)n=0.6–1.7). Aphyric lavas have relatively constant Sc (40±1.5 ppm) abundances and CaO/Al2O3 ratios (0.80±0.02). Group I lavas are confined primarily to the AMAR rift valley floor whereas Group II lavas are found along the east and west marginal highs. We interpret the isotopic differences between the two groups as reflecting a temporal change in the upwelling mantle beneath this region of the Mid-Atlantic Ridge which is south of the Azore Islands. For each group, a petrogenetic model consistent with the geochemical data is multi-stage decompression melting of an initially enriched, homogeneous, mantle source region. If the early derived, incompatible-element enriched, melt increments are not always pooled with subsequent increments, the erupted magma batches may have the major element characteristics of melts derived by 10 to 20% melting, but with incompatible element abundance ratios reflecting the change from an enriched to depleted source during the incremental melting process. In this process an initially homogeneous source can generate primary magmas with the required range in incompatible element abundance ratios shown by each group. The nearly constant CaO/Al2O3 ratios and Sc contents of the aphyric lavas with decreasing Mg ? reflects subsequent polybaric fractionation of clinopyroxene, plagioclase and olivine over the pressure interval 8–6 kbar (24–18 km), followed by rapid transport to the surface and eruption. There is no geochemical evidence for a crustal magma chamber beneath this section of the Mid-Atlantic Ridge.
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  • 6
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract From 33°–42° S in central-south Chile, there are numerous volcanoes which form part of the Andean magmatic arc caused by subduction of the Nazca plate beneath western South America. The 〈0.3 m.y. old Laguna del Maule volcanic complex at 36° S is in a transition region between volcanoes at 33°–34° S formed dominantly of hornblende-bearing andesite and volcanoes south of 37° S dominantly composed of basalt and basaltic andesite. The Laguna del Maule complex ranges in composition from basalt (∼0.3 m.y.) to rhyolite (post-glacial). Although there is abundant evidence for magma mixing, basalt and rhyolite have similar Sr and Nd isotopic ratios, thereby requiring that the mixing members had the same isotopic ratios (87Sr/ 86Sr ∼0.70419 and 143Nd/144Nd ∼0.51274). In contrast, dacitic dikes and a volcanic neck which also have evidence for magma mixing are isotopically distinct. Major and trace element abundances are consistent with a genetic relationship between the basalt and rhyolite, either by low-pressure, plagioclase-dominated, fractional crystallization or by partial melting of a plagioclase-rich assemblage. There is no evidence that the rhyolites contain more of a crustal component than the associated basic volcanics.
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  • 7
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The crustal history of volcanic rocks can be inferred from the mineralogy and compositions of their phenocrysts which record episodes of magma mixing as well as the pressures and temperatures when magmas cooled. Submarine lavas erupted on the Hilo Ridge, a rift zone directly east of Mauna Kea volcano, contain olivine, plagioclase, augite ±orthopyroxene phenocrysts. The compositions of these phenocryst phases provide constraints on the magmatic processes beneath Hawaiian rift zones. In these samples, olivine phenocrysts are normally zoned with homogeneous cores ranging from ∼ Fo81 to Fo91. In contrast, plagioclase, augite and orthopyroxene phenocrysts display more than one episode of reverse zoning. Within each sample, plagioclase, augite and orthopyroxene phenocrysts have similar zoning profiles. However, there are significant differences between samples. In three samples these phases exhibit large compositional contrasts, e.g., Mg# [100 × Mg/(Mg+Fe+2)] of augite varies from 71 in cores to 82 in rims. Some submarine lavas from the Puna Ridge (Kilauea volcano) contain phenocrysts with similar reverse zonation. The compositional variations of these phenocrysts can be explained by mixing of a multiphase (plagioclase, augite and orthopyroxene) saturated, evolved magma with more mafic magma saturated only with olivine. The differences in the compositional ranges of plagioclase, augite and orthopyroxene crystals between samples indicate that these samples were derived from isolated magma chambers which had undergone distinct fractionation and mixing histories. The samples containing plagioclase and pyroxene with small compositional variations reflect magmas that were buffered near the olivine + melt ⇒Low-Ca pyroxene + augite + plagioclase reaction point by frequent intrusions of mafic olivine-bearing magmas. Samples containing plagioclase and pyroxene phenocrysts with large compositional ranges reflect magmas that evolved beyond this reaction point when there was no replenishment with olivine-saturated magma. Two of these samples contain augite cores with Mg# of ∼71, corresponding to Mg# of 36–40 in equilibrium melts, and augite in another sample has Mg# of 63–65 which is in equilibrium with a very evolved melt with a Mg# of ∼30. Such highly evolved magmas also exist beneath the Puna Ridge of Kilauea volcano. They are rarely erupted during the shield building stage, but may commonly form in ephemeral magma pockets in the rift zones. The compositions of clinopyroxene phenocryst rims and associated glass rinds indicate that most of the samples were last equilibrated at 2–3 kbar and 1130–1160 °C. However, in one sample, augite and glass rind compositions reflect crystallization at higher pressures (4–5 kbar). This sample provides evidence for magma mixing at relatively high pressures and perhaps transport of magma from the summit conduits to the rift zone along the oceanic crust-mantle boundary.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 70 (1979), S. 127-141 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Tholeiitic basalts dredged from the Mid-Atlantic Ridge (MAR) axis at 43 ° N are enriched in incompatible trace elements compared to the ‘ normal’ incompatible element depleted tholeiites found from 49 ° N to 59 ° N and south of 33 ° N on the MAR. The most primitive 43 ° N glasses have MgO/FeO*= 1.2 and coexist with olivine (Fo90–91) and chrome-rich spinel. The tholeiitic basalts from the MAR 43 ° N are distinct from the strongly incompatible trace element depleted tholeiities found elsewhere in the Atlantic, and have trace element features typical of island tholeiities and MAR axis tholeiites from 45 ° N. Petrographic, major, and compatible trace element trends of the axial valley tholeiites at 43 ° N are consistent with shallow-level fractionation; in particular, evolution from primitive liquids with forsteritic olivine plus chrome spinel as liquidus phases to fractionated liquids with plagioclase plus clinopyroxene as major crystallizing phases. However, each dredge haul has distinctive incompatible trace element abundances. These trace element characteristics require a hetrogeneous mantle or complex processes such as open system fractional crystallization and magma mixing. Alkali basalts (∼5% normative nepheline) were dredged from a prominent fracture zone at 43 ° N. Typical of alkali basalts they are strongly enriched (compared to tholeiites) in incompatible elements. Their highly fractionated rare-earth element (REE) abundances require residual garnet during partial melting. The 43 ° N tholeiites and alkali basalts could be derived from a garnet peridotite source with REE contents equal to 2 × chondrites by ∼5% and 1% melting, respectively. Alternatively, they could be derived from a moderately light REE enriched source by ∼25% and 9.5% melting, respectively.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 70 (1979), S. 439-450 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Seventeen granitoid samples from batholiths in central Chile (33 °–34 ° S) have been analyzed for trace element content. The samples range in age from Paleozoic to Tertiary, and in rock type from quartz diorite to granite. In general, compared to andesites from central-south Chile these rocks are more siliceous with lower abundances of compatible trace elements and higher abundances of incompatible trace elements. However, Upper Tertiary granodiorites have important geochemical similarities, such as highly fractionated rare-earth element (REE) distributions relative to chondrites, to some modern andesites in this region; e.g., Marmolejo. Similar highly fractionated REE distributions are also common in the cores of zoned intrusive sequences in the Sierra Nevada of the western U.S. Based on limited sampling of central Chile Cretaceous and Tertiary plutonics, there may be a west to east increase in light REE/heavy REE ratio and in Sr content. Compared to the Upper Tertiary granodiorites, the Paleozoic granodiorites have similar REE abundances but lower Sr, Sc, Cr, Co, and Ni contents.
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  • 10
    Publication Date: 2007-09-01
    Print ISSN: 0016-7037
    Electronic ISSN: 1872-9533
    Topics: Chemistry and Pharmacology , Geosciences
    Published by Elsevier
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