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  • 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters  (8)
  • 05. General::05.02. Data dissemination::05.02.01. Geochemical data  (7)
  • 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics  (3)
  • 04. Solid Earth::04.02. Exploration geophysics::04.02.02. Gravity methods
  • Astronomy
  • J24
  • ddc:330
  • gas chemistry
  • Elsevier  (12)
  • Geological Society of Greece  (2)
  • Geological Survey of Slovenia - Ljubljana  (1)
  • WIT Press - Southampton, Boston
Collection
Years
  • 1
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey on the fluids released by the volcanic/geothermal system of Methana was undertaken. Characterization of the gases was made on the basis of the chemical and isotopic (He and C) analysis of 14 samples. CO2 soil gas concentration and fluxes were measured on the whole peninsula at more than 100 sampling sites. 31 samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of aquifers. Anomalies referable to the geothermal system, besides at known thermal manifesta-tions, were also recognized at some anomalous degassing soil site and in some cold groundwater. These anomalies were always spatially correlated to the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated in about 0.2 kg s-1. Although this value is low compared to other volcanic systems, anomalous CO2 degassing at Methana may pose gas hazard problems. Such volcanic risk, although restricted to limited areas, cannot be neglected and further studies have to be undertaken for its better assessment
    Description: Published
    Description: 712-722
    Description: N/A or not JCR
    Description: open
    Keywords: soil gases ; CO2 fluxes ; gas hazard ; groundwater chemistry ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Ischia volcano, in Central Italy, has long been known for its copious surface hydrothermal manifestations, signs of a pervasive circulation of hot fluids in the subsurface. Because of the significant chemical heterogeneity of fumarolic gas discharges and hot spring discharges, evidences of a complex hydrothermal setting, a definite model of fluid circulation at depth is currently unavailable, in spite of the several previous efforts. Here, we report on the chemical and isotopic composition of 120 groundwater samples, collected during several sampling surveys from 2002 to 2007. The acquired data suggest that the composition of surface manifestations reflect contributions from meteoric water, sea water, and thermal fluids rising from two distinct hydrothermal reservoir, with equilibrium temperatures of respectively ~150 °C and ~270 °C, and depths of 150–300 m and N300 m (but possibly N1000 m). We also make use of an isotopic characterization of the dissolved gas phase in thermal waters to demonstrate that the Ischia hydrothermal system is currently supplied by a deep-rising gas component (DGC), characterized by CO2 ~97.7±1.2 vol.% (on a water-free basis), δ13CCO2=−3.51±0.9‰, and helium isotopic ratio of about 3.5 Ra (3He/4He ratio normalized to the air ratio, Ra), likely magmatic in origin. An assessment of the thermal budget for Ischia hydrothermal system is also presented, in the attempt to derive a first estimate of the size and rate of degassing of the magmatic reservoir feeding the gas emissions. We calculate that a heat flow of about 153–222 MW presently drives hydrothermal circulation on the island, which we suggest is supplied in convective form (e.g., by the ascent of a high-T magmatic vapour phase) by complete degassing of 2.2–3.3 107 m3 yr−1 of trachytic magma (with ~2.1 wt.% dissolved H2O content). If extrapolated to entire period of quiescence lasting since the Arso eruption in 1302 A.D., this volume corresponds to 1.6–2.3 1010 m3 of magma degassed in about 700 years of quiescent activity.
    Description: Published
    Description: 133–159
    Description: JCR Journal
    Description: reserved
    Keywords: Ischia ; hydrothermal systems ; thermal groudwaters ; thermal and volatile budget ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: This paper discusses the abundance, speciation and mobility of As in groundwater systems from active volcanic areas in Italy. Using literature data and new additional determinations, the main geochemical processes controlling the fate of As during gas–water–rock interaction in these systems are examined. Arsenic concentrations in the fluids range from 0.1 to 6940 mg/l, with wide differences observed among the different volcanoes and within each area. The dependence of As content on water temperature, pH, redox potential and major ions is investigated. Results demonstrate that As concentrations are highest where active hydrothermal circulation takes place at shallow levels, i.e. at Vulcano Island and the Phlegrean Fields. In both areas the dissolution of As-bearing sulphides is likely to be the main source of As. Mature Cl-rich groundwaters, representative of the discharge from the deep thermal reservoirs, are typically enriched in As with respect to SO4-rich ‘‘steam heated groundwaters’’. In the HCO3 groundwaters recovered at Vesuvius and Etna, aqueous As cycling is limited by the absence of high-temperature interactions and by high-Fe content of the host rocks, resulting in oxidative As adsorption. Thermodynamic modelling suggests that reducing H2S-rich groundwaters are in equilibrium with realgar, whereas in oxidising environments over-saturation with respect to Fe oxyhydroxides is indicated. Under these oxidising conditions, As solubility decreases controlled by As co-precipitation with, or adsorption on, Fe oxy-hydroxides. Consistent with thermodynamic considerations, As mobility in the studied areas is enhanced in intermediate redox environments, where both sulphides and Fe hydroxides are unstable.
    Description: Published
    Description: 1283–1296
    Description: partially_open
    Keywords: Hydrogeochemistry ; Arsenic ; volcanic groundwaters ; speciation ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: Active volcanoes emit considerable amounts of contaminants such as As, Se and V. Mount Etna is the biggest volcano of Europe and an excellent geochemical site to study water-soil processes. Due to its volcanic activity, the rainwater has a strong compositional gradient, both in time and space. At present, the behaviour of trace elements in the soils around Mt Etna is poorly understood. To determine the influence of the rainwater pH on the potential mobilization of geogenic pollutants, batch experiments have been performed with synthetic rainwater for 25 soils collected along the flanks of the volcano. Our results show that: i) The maximum concentrations in the leaching solutions are higher for acid rain than for neutral rain (e.g. 7.7 vs 1.3 mg/L for Se). ii) With neutral rain conditions the soils upwind from the volcano have higher concentrations of Se than those downwind (up to 1.3 mg/L compared to ≤0.3 mg/L for the other samples). This trend is less clear for As and V. iii) For soils collected from 2 to 10 km downwind of the craters, Se concentrations in acid rain leachates decrease one order of magnitude with increasing distance. A similar pattern is also observed upwind from the volcano. For As and V no clear relationship between concentrations and location with respect to the volcanic craters is observed. Both i) and ii) result in a low pH dependence for samples upwind from the volcano. The biggest difference between acid and neutral leaching for As and V is observed for a sample 2 km downwind from the craters. The observed patterns are influenced by potential controlling factors, such as organic matter content, total concentrations, mineralogy, influence of the volcanic plume, etc. Our results have implications for the chemical composition of the Etnean aquifer, the only water resource to the one million inhabitants around Mt Etna, as well as for the bioavailability and potential toxicity through agricultural activities, essential to the local economy.
    Description: Published
    Description: Davos, Switzerland
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: volcanic soils ; selenium ; arsenic ; vanadium ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 5
    Publication Date: 2017-04-04
    Description: Geochemical comparison between some metals (As, Cd, Cu, Pb, Se, V, Zn) emissions from an active volcano (Mt. Etna) and a highly industrialized area (Salek Valley) showed some interesting similarities: in general, most of the elements emitted into the atmosphere do not return to the Earth's surface and are therefore dispersed into the environment. Exceptions for Salek Valley are Cd, which probably derives in large part from rock leaching, and in part As and Pb, which fall mostly as ash. Also, Etna's emissions are richer in Cd and Cu, whereas industrial emissions at Salek Valley are richer in V and Zn. All other metals have similar fluxes in the two types of emissions.
    Description: Published
    Description: Ljubljana, Slovenia
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Trace metals ; Mt. Etna ; Salek Valley ; metals budget ; pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 6
    Publication Date: 2017-04-04
    Description: Oxygen isotopes of both rainwater and groundwater samples from Mt Etna were used to obtain information on recharge areas, flow paths, and the origin of wet air masses. Oxygen isotope composition was determined in rainwater samples collected for a period of 3 years (October 1997–October 2000), in 11 rain-gauges distributed along the flanks of Mt Etna from sea level to 2900 m of altitude. Values ranged from 213.8 to þ 1.9‰, the lowest values being measured at higher altitudes and/or during cooler periods. For rain-gauges located from sea level up to 1000 m altitude, volume weighted values defined an isotopic gradient of 22.7‰/km, which is in the range observed in the Mediterranean area. Higher-altitude gauges yielded a much lower gradient (20.6‰/km), probably due to the fact that vapour condensing at higher altitudes was mixed with an 18O-rich volcanic component deriving from the huge vapour output of the summit craters. The oxygen isotope composition of about 210 groundwater samples collected all around the volcano ranged from 29.3 to 25.0‰. The higher values measured on the eastern flank indicated that recharge occurs at lower altitudes on this flank. The low variability (0.30–0.65‰) of the monthly values gathered from 14 groundwater sampling points over a period of 2 years indicates that the groundwater system is isotopically well mixed. Some long-term trends may be explained by variations in annual recharge, due to the prevalent isotope composition of wet air masses.
    Description: National Group for Volcanology (G.N.V.), Italy.
    Description: Published
    Description: 282–299
    Description: partially_open
    Keywords: Isotope hydrology ; d18O ; Groundwater ; Rainwater ; Mt Etna ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2017-04-04
    Description: Radon levels were measured in 119 groundwater samples collected throughout the active volcanic area of Mt. Etna by means of a portable Lucas-type scintillation chamber. The measured activity values range from 1.8 to 52.7 Bq l 1. About 40% of the samples exceed the maximum contaminant level of 11 Bq l 1 proposed by the USEPA in 1991. The highest radon levels are measured in the eastern sector of the volcano, which is the seismically most active zone of the volcano. On the contrary the south-western sector, which is both seismically active and a site of intense magmatic degassing, display lower radon levels. This is probably due to the formation of a free gas phase (oversaturation of CO2) that strips the radon from the water. Comparison of the data gathered at Mt. Etna with those of other areas indicates that 222Rn activity in groundwater is positively correlated with both the content of parent elements in the aquifer rocks and the temperature of the geothermal systems that interacts with the sampled aquifers.
    Description: Published
    Description: 187–201
    Description: partially_open
    Keywords: Groundwater ; Radon ; Mount Etna ; Active volcanic areas ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
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    WIT Press - Southampton, Boston
    Publication Date: 2017-04-04
    Description: Fluorosis is a widespread disease related to ingestion of high levels of fluorine through water and food. Although sometimes of anthropogenic origin, high levels of fluorine are generally related to natural sources. One of the main sources is represented by volcanic activity, which releases magmatic fluorine generally as hydrogen fluorine through volcanic degassing. For example, Mt. Etna in Italy is considered the greatest point source at the global scale, releasing on average 70 Gg of HF each year. But the impact of fluorine on human health is highly dependent on its chemical state, which means that high rates of release not necessary point to high impacts. The major pathway of magmatic fluorine to humans is in the form of fluoride ion (F-), through consumption of contaminated vegetables and drinking water. Contamination can happen either through direct uptake of gaseous HF or through rainwaters and volcanic ashes. Furthermore hydrogen fluoride, being one of the most soluble gases in magmas, exsolves only partially (〈 20%) during volcanic activity. Volcanic rocks thus contain high levels of fluorine, which are transferred to groundwaters through water-rock interaction processes in the aquifers. Large magmatic provinces, like for example the East African Rift Valley, are therefore endemic for fluorosis. Finally a literature review of volcanic related fluorosis is given.
    Description: Published
    Description: 21-30
    Description: open
    Keywords: Fluorosis ; magmatic fluorine ; volcanic activity ; groundwater ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 9
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey of the fluids released by the volcanic/geothermal system of Methana was undertaken. Gases were characterized based on the chemical and isotopic [helium (He) and carbon (C)] analysis of 27 samples. Carbon dioxide soil gas concentration and fluxes were measured at 179 sampling sites throughout the peninsula. Forty samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of the aquifers. Gases of hydrothermal origin gave a preliminary geothermometric estimate of about 210 °C. The He-isotope composition indicated mantle contributions of up to 40%, and the C-isotope composition of CO2 indicated that it predominantly (〉90%) originated from limestone decomposition. The groundwater composition was suggestive of mixing between meteoric and hydrothermally modified sea-water endmembers and water–rock interaction processes limited to simple rock dissolution driven by an increased endogenous CO2 content. All of the thermal manifestations and anomalous degassing areas, although of limited extent, were spatially correlated with the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated to be less than 0.05 kg s–1. Although this value is very low compared to those of other volcanic systems, anomalous CO2 degassing at Methana – which is currently restricted to limited areas and at present is the only volcanic risk of the peninsula – is a potential gas hazard that warrants further assessment in future studies.
    Description: Published
    Description: 818-828
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Methana ; south Aegean volcanic arc ; fluids geochemistry ; soil gases ; groundwaters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2017-04-04
    Description: New geochemical data on dissolved major and minor constituents in 276 groundwater samples from Etna aquifers reveal the main processes responsible for their geochemical evolution and mineralisation. This topic is of particular interest in the light of the progressive depletion of water resources and groundwater quality in the area. Multivariate statistical analysis reveal 3 sources of solutes: (a) the leaching of the host basalt, driven by the dissolution of magmaderived CO2; (b) mixing processes with saline brines rising from the sedimentary basement below Etna; (c) contamination from agricultural and urban wastewaters. The last process, highlighted by increased concentrations of SO4,NO3, Ca, F and PO4, is more pronounced on the lower slopes of the volcanic edifice, associated with areas of high population and intensive agriculture. However, this study demonstrates that natural processes (a) and (b) are also very effective in producing highly mineralised waters, which in turn results in many constituents (B, V, Mg) exceeding maximum admissible concentrations for drinking water.
    Description: Published
    Description: 863–882
    Description: partially_open
    Keywords: Hydrogeochemistry ; water quality ; Mt. Etna ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 539 bytes
    Format: 787985 bytes
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