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  • 1
    Publication Date: 2017-12-08
    Description: The behaviour of aquifers with karst porosity is dependent on hydrological conditions. This is due to the peculiar characteristics of the groundwater flow and dynamics of hydrological processes in karst. As a result, karst aquifers are especially vulnerable to the effects of environmental change. We assessed the long-term climatological and hydrological trends and the short-term effects of increasingly frequent extreme hydrological events (droughts) for the Mediterranean karst spring Rižana in SW Slovenia. The findings predict higher mean annual air temperatures of 0.34°C decade –1 , lower annual precipitation of c. 60 mm decade –1 and higher annual actual evapotranspiration (especially during spring and summer) of 32–49 mm decade –1 . As a consequence, we can expect a decrease in the mean annual discharge of the spring of c. 480 l s –1 decade –1 with prolonged dry summer periods. Detailed monitoring of the physical, chemical and microbiological parameters showed that the flood pulses caused by precipitation events after a long dry period cause a significant deterioration in water quality. In such situations, contaminants stored in the unsaturated zone are flushed out and counts of coliform bacteria can reach 〉1400 cfu (100 ml) –1 , with total Al and Fe concentrations up to 206 and 474 μg l –1 , respectively. These results suggest that there should be urgent adherence to water quality standards to protect karst water sources in view of the anticipated climatological stresses. Management strategies should promote monitoring and the rational use of karst water supplies.
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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  • 2
    Publication Date: 2003-02-27
    Description: Summary Various aqueous wood preservative solutions containing Cu(II) in the form of copper(II) sulphate or copper(II) octanoate, ethanolamine and in one case octanoic acid were investigated by spectrophotometry, polarography and Electron Paramagnetic Resonance (EPR) spectroscopy. Results have shown the same coordination environment around Cu(II) in all solutions with ethanolamine. Computer simulation of the EPR spectra also revealed that the coordination in the first coordination sphere of copper is the same at low concentration of ethanolamine. At 20% ethanolamine concentration, a mixture of two complexes (one with two nitrogens and the other with three) could be detected. The active compound in the investigated ethanolamine containing solutions is the same when previously synthesised copper(II) octanoate was used, or when copper(II) sulphate and octanoic acid were utilized instead. Fungicidal and leaching experiments with the treated wood resulted in the same conclusion: it is not necessary to use pre-synthesised copper(II) octanoate for the preparation of waterborne copper/ethanolamine wood preservatives. Preservative preparation time and costs can be reduced by simply dissolving copper(II) sulphate and octanoic acid in aqueous ethanolamine solutions.
    Print ISSN: 0018-3830
    Electronic ISSN: 1437-434X
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by De Gruyter
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  • 3
    Publication Date: 2002-04-29
    Description: Summary The tolerance of various fungi against copper was examined. For this purpose, we impregnated Norway spruce (Picea abies) specimens with two different aqueous solutions: copper(II) octanoate with ethanolamine or copper(II) sulfate (cCu = 1.0 × 10−2 mol/l). Impregnated and unimpregnated test specimens were then exposed to brown rot fungi Antrodia vaillantii and Gloeophyllum trabeum or to white-rot fungi Schizophyllum commune and Trametes versicolor. After 2, 4, 6 and 12 weeks of exposure Electron Paramagnetic Resonance, Atomic Absorption Spectroscopy and mass loss measurements were performed. The results indicate that A. vaillantii, G. trabeum and T. versicolor transform copper(II) sulfate in wood into non-soluble, and therefore non-toxic, copper oxalate. The intensity of this reaction depends on the amount of excreted oxalic acid and was the highest for A. vaillantii and the lowest for T. versicolor. In the presence of ethanolamine, formation of insoluble copper oxalate was not possible and therefore, decay could not proceed. The major portion of copper remained in the wood and only minor amounts were in some cases translocated into nutrient media.
    Print ISSN: 0018-3830
    Electronic ISSN: 1437-434X
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by De Gruyter
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