ALBERT

Description: The Zotino Tall Tower Observatory in Central Siberia (ZOTTO, 60°48' N, 89°21' E) is an excellent location to monitor the continental carbon cycle. Since April 2009, a fully automated low maintenance measurement system based on a cavity ring-down spectroscopy (CRDS) analyzer is installed at the site to measure continuously carbon dioxide (CO2) and methane (CH4) from six heights up to 301 m a.g.l. Buffer volumes in each air line remove short term CO2 and CH4 mixing ratio fluctuations associated with turbulence, and allow continuous, near-concurrent measurements from all six tower levels. Instead of drying the air sample, the simultaneously measured water vapor is used to correct the dilution and pressure-broadening effects for the accurate determination of dry air CO2 and CH4 mixing ratios. The stability of the water vapor correction was demonstrated by repeated laboratory and field tests. The effect of molecular adsorption in the wet air lines was shown to be negligible. The low consumption of four calibration tanks that need recalibration only on decadal timescale further reduces maintenance. The measurement precision (accuracy) of 0.04 ppm (0.09 ppm) for CO2 and 0.3 ppb (1.5 ppb) for CH4 is compliant with the WMO recommendations. The data collected during the 2009 vegetation period reveals a seasonal cycle amplitude of 26.4 ppm at the 301 m level.

Description: A new coastal background site has been established for observations of greenhouse gases (GHGs) in the central Namib Desert at Gobabeb, Namibia. The location of the site was chosen to provide observations for a data-poor region in the global sampling network for GHGs. Semi-automated, continuous measurements of carbon dioxide, methane, nitrous oxide, carbon monoxide, atmospheric oxygen, and basic meteorology are made at a height of 21 m a.g.l., 50 km from the coast at the northern border of the Namib Sand Sea. Atmospheric oxygen is measured with a differential fuel cell analyzer (DFCA). Carbon dioxide and methane are measured with an early-model cavity ring-down spectrometer (CRDS); nitrous oxide and carbon monoxide are measured with an off-axis integrated cavity output spectrometer (OA-ICOS). Instrument-specific water corrections are employed for both the CRDS and OA-ICOS instruments in lieu of drying. The performance and measurement uncertainties are discussed in detail. As the station is located in a remote desert environment, there are some particular challenges, namely fine dust, high diurnal temperature variability, and minimal infrastructure. The gas handling system and calibration scheme were tailored to best fit the conditions of the site. The CRDS and DFCA provide data of acceptable quality when base requirements for operation are met, specifically adequate temperature control in the laboratory and regular supply of electricity. In the case of the OA-ICOS instrument, performance is significantly improved through the implementation of a drift correction through frequent measurements of a working tank.

Description: Methane and carbon dioxide were measured with an autonomous and continuous running system on a ferry line crossing the Baltic Sea on a 2–3 day interval from the Mecklenburg Bight to the Gulf of Finland in 2010. Surface methane saturations show great seasonal differences in shallow regions like the Mecklenburg Bight (103–507%) compared to deeper regions like the Gotland Basin (96–161%). The influence of controlling parameters like temperature, wind, mixing depth and processes like upwelling, mixing of the water column and sedimentary methane emissions on methane oversaturation and emission to the atmosphere are investigated. Upwelling was found to influence methane surface concentrations in the area of Gotland significantly during the summer period. In February 2010, an event of elevated methane concentrations in the surface water and water column of the Arkona Basin was observed, which could be linked to a wind-derived water level change as a potential triggering mechanism. The Baltic Sea is a source of methane to the atmosphere throughout the year, with highest fluxes during the winter season. Stratification was found to intensify the formation of a methane reservoir in deeper regions like Gulf of Finland or Bornholm Basin, which leads to long lasting elevated methane concentrations and enhanced methane fluxes, when mixed to the surface during mixed layer deepening in autumn and winter. Methane concentrations and fluxes from shallow regions like the Mecklenburg Bight are rather controlled by sedimentary production and consumption of methane, wind events and the change in temperature-dependent solubility of methane in the surface water. Methane fluxes vary significantly in shallow regions (e.g. Mecklenburg Bight) and regions with a temporal stratification (e.g. Bornholm Basin, Gulf of Finland). On the contrary, areas with a permanent stratification like the Gotland Basin show only small seasonal fluctuations in methane fluxes.

Description: Methane and carbon dioxide were measured with an autonomous and continuous running system on a ferry line crossing the Baltic Sea on a 2–3 day interval from the Mecklenburg Bight to the Gulf of Finland in 2010. Surface methane saturations show great seasonal differences in shallow regions like the Mecklenburg Bight (103–507%) compared to deeper regions like the Gotland Basin (96–161%). The influence of controlling parameters like temperature, wind, mixing depth and processes like upwelling, mixing of the water column and sedimentary methane emissions on methane oversaturation and emission to the atmosphere are investigated. Upwelling was found to influence methane surface concentrations in the area of Gotland significantly during the summer period. In February 2010, an event of elevated methane concentrations in the surface water and water column of the Arkona Basin was observed, which could be linked to a wind-derived water level change as a potential triggering mechanism. The Baltic Sea is a source of methane to the atmosphere throughout the year, with highest fluxes occurring during the winter season. Stratification was found to promote the formation of a methane reservoir in deeper regions like Gulf of Finland or Bornholm Basin, which leads to long lasting elevated methane concentrations and enhanced methane fluxes, when mixed to the surface during mixed layer deepening in autumn and winter. Methane concentrations and fluxes from shallow regions like the Mecklenburg Bight are predominantly controlled by sedimentary production and consumption of methane, wind events and the change in temperature-dependent solubility of methane in the surface water. Methane fluxes vary significantly in shallow regions (e.g. Mecklenburg Bight) and regions with a temporal stratification (e.g. Bornholm Basin, Gulf of Finland). On the contrary, areas with a permanent stratification like the Gotland Basin show only small seasonal fluctuations in methane fluxes.

Description: We present 2.5 years (from June 2006 to December 2008) of in-situ measurements of CO2, O2, CH4, CO, N2O and SF6 mixing ratios sampled from 23, 90 and 163 m above ground on the Ochsenkopf tower in the Fichtelgebirge range, Germany (50°01'49" N, 11°48'30" E, 1022 m a.s.l.). In addition to the in-situ measurements, flask samples are taken at Ochsenkopf at approximately weekly intervals and are subsequently analysed for the mixing ratios of the same species, as well as H2, and the stable isotopes, δ13C, δ18O in CO2. The in-situ measurements of CO2 and O2 from 23 m show substantial diurnal variations that are modulated by biospheric fluxes, combustion of fossil fuels, and by diurnal changes in the planetary boundary layer height. Measurements from 163 m exhibit only very weak diurnal variability, as this height (1185 m a.s.l.) is generally above the nocturnal boundary layer. CH4, CO, N2O and SF6 show little diurnal variation even at 23 m owing to the absence of any significant diurnal change in the fluxes and the absence of any strong local sources or sinks. From the in-situ record, the seasonal cycles of the gas species have been characterized and the multi-annual trends determined. Because the record is short, the calculation of the trend is sensitive to inter-annual variations in the amplitudes of the seasonal cycles. However, for CH4 a significant change in the growth-rate was detected for 2006.5–2008.5 as compared with the global mean from 1999 to 2006 and is consistent with other recent observations of a renewed increasing global growth rate in CH4 since the beginning of 2007.

Description: Quasi-continuous, in-situ measurements of atmospheric CO2, O2/N2, CH4, CO, N2O, and SF6 have been performed since August 2005 at the tall tower station near Bialystok, in Eastern Poland, from five heights up to 300 m. Besides the in-situ measurements, flask samples are filled approximately weekly and measured at Max-Planck Institute for Biogeochemistry for the same species and, in addition, for H2, Ar/N2 and the stable isotopes 13C and 18O in CO2. The in-situ measurement system was built based on commercially available analysers: a LiCor 7000 for CO2, a Sable Systems "Oxzilla" FC-2 for O2, and an Agilent 6890 gas chromatograph for CH4, CO, N2O and SF6. The system was optimized to run continuously with very little maintenance and to fulfill the precision requirements of the CHIOTTO project. The O2/N2 measurements in particular required special attention in terms of technical setup and quality assurance. The evaluation of the performance after more than three years of operation gave overall satisfactory results, proving that this setup is suitable for long term remote operation with little maintenance. The precision achieved for all species is within or close to the project requirements. The comparison between the in-situ and flask sample results, used to verify the accuracy of the in-situ measurements, showed no significant difference for CO2, O2/N2, CH4 and N2O, and a very small difference for SF6. The same comparison however revealed a statistically significant difference for CO, of about 6.5 ppb, for which the cause could not be fully explained. From more than three years of data, the main features at Bialystok have been characterized in terms of variability, trends, and seasonal and diurnal variations. CO2 and O2/N2 show large short term variability, and large diurnal signals during the warm seasons, which attenuate with the increase of sampling height. The trends calculated from this dataset, over the period August 2005 to December 2008, are 2.02±0.46 ppm/year for CO2 and −23.2±2.5 per meg/year for O2/N2. CH4, CO and N2O show also higher variability at the lower sampling levels, which in the case of CO is strongly seasonal. Diurnal variations in CH4, CO and N2O mole fractions can be observed during the warm season, due to the periodicity of vertical mixing combined with the diurnal cycle of anthropogenic emissions. We calculated increase rates of 10.1±4.4 ppb/year for CH4, (−8.3)±5.3 ppb/year for CO and 0.67±0.08 ppb/year for N2O. SF6 shows only few events, and generally no vertical gradients, which suggests that there are no significant local sources. A weak SF6 seasonal cycle has been detected, which most probably is due to the seasonality of atmospheric circulation. SF6 increased during the time of our measurement at an average rate of 0.29±0.01 ppt/year.

Description: To monitor the continental carbon cycle, a fully automated low maintenance measurement system is installed at the Zotino Tall Tower Observatory in Central Siberia (ZOTTO, 60°48' N, 89°21' E) since April 2009. A cavity ring-down spectroscopy (CRDS) analyzer continuously measures carbon dioxide (CO2) and methane (CH4) from six heights up to 301 m a.g.l. Buffer volumes in each air line remove short term CO2 and CH4 mixing ratio fluctuations associated with turbulence, and allow continuous, near-concurrent measurements from all tower levels. Instead of drying the air sample, the simultaneously measured water vapor is used to correct the dilution and pressure-broadening effects for the accurate determination of dry air CO2 and CH4 mixing ratios. The stability of the water vapor correction was demonstrated by repeated laboratory and field tests. The effect of molecular adsorption in the wet air lines was shown to be negligible. The low consumption of four calibration tanks that need recalibration only on decadal timescale further reduces maintenance. The measurement precision (accuracy) of 0.04 ppm (0.09 ppm) for CO2 and 0.3 ppb (1.5 ppb) for CH4 is compliant with the WMO recommendations. The data collected so far (until April 2010) reveals a seasonal cycle amplitude for CO2 of 30.4 ppm at the 301 m level.

Description: A new coastal background site has been established for observations of greenhouse gases (GHGs) in the central Namib Desert at Gobabeb, Namibia. The location of the site was chosen to provide observations for a data-poor region in the global sampling network for GHGs. Semi-automated continuous measurements of carbon dioxide, methane, nitrous oxide, carbon monoxide, atmospheric oxygen, and basic meteorology are made at a height of 21 m a.g.l., 50 km from the coast at the northern border of the Namib Sand Sea. Atmospheric oxygen is measured with a differential fuel cell analyzer (DFCA). Carbon dioxide and methane are measured with an early-model cavity ring-down spectrometer (CRDS); nitrous oxide and carbon monoxide are measured with an off-axis integrated cavity output spectrometer (OA-ICOS). Instrument-specific water corrections are employed for both the CRDS and OA-ICOS instruments in lieu of drying. The performance and measurement uncertainties are discussed in detail. As the station is located in a remote desert environment, there are some particular challenges, namely fine dust, high diurnal temperature variability, and minimal infrastructure. The gas handling system and calibration scheme were tailored to best fit the conditions of the site. The CRDS and DFCA provide data of acceptable quality when base requirements for operation are met, specifically adequate temperature control in the laboratory and regular supply of electricity. In the case of the OA-ICOS instrument, performance is significantly improved through the implementation of a drift correction through frequent measurements of a reference cylinder.

Description: We present an integrated system for measuring atmospheric concentrations of CO2, O2, CH4, CO, and N2O in central Siberia. Our project aims to demonstrate the feasibility of establishing long-term, continuous, high precision atmospheric measurements to elucidate greenhouse gas processes from a very remote mid-continental boreal environment. Air is sampled from five heights on a custom-built 300-m tower. Common features to all species' measurements include air intakes, an air drying system, flushing procedures, and data processing methods. Calibration standards are shared among all five measured species as a result of extending and optimising a proven methodology for long-term O2 calibration. Our system achieves the precision and accuracy requirements specified by the European Union's "CarboEurope" and "ICOS" (Integrated Carbon Observing System) programmes in the case of CO2, O2, and CH4, while CO and N2O require some further improvements. We found that it is not possible to achieve these high precision measurements without skilled technical assistance on-site, primarily because of 2–3 month delays in access to data and diagnostic information. We present results on the stability of reference standards in high pressure cylinders. We also found that some previous methods do not mitigate fractionation of O2 in a sample airstream to a satisfactory level.

Description: Quasi-continuous, in-situ measurements of atmospheric CO2, O2/N2, CH4, CO, N2O, and SF6 have been performed since August 2005 at the tall tower station near Bialystok, in Eastern Poland, from five heights up to 300 m. Besides the in-situ measurements, flask samples are filled approximately weekly and measured at Max-Planck Institute for Biogeochemistry for the same species and, in addition, for H2, Ar/N2 and the stable isotopes 13C and 18O in CO2. The in-situ measurement system was build based on commercially available analysers: a LiCor 7000 for CO2, a Sable Systems "Oxzilla" FC-2 for O2, and an Agilent 6890 gas chromatograph for CH4, CO, N2O and SF6. The system was optimized to run continuously with very little maintenance and to fulfill the precision requirements of the CHIOTTO project. The O2 measurements in particular required special attention in terms of technical setup and quality assurance. The evaluation of the performance after more than three years of operation gave overall satisfactory results, proving that this setup is suitable for long term remote operation with little maintenance. The precision achieved for all species is within or close to the project requirements. The comparison between the in-situ and flask sample results, used to verify the accuracy of the in-situ measurements, showed no significant difference for CO2, O2/N2, CH4 and N2O, and a very small difference for SF6. The same comparison however revealed a statistically significant difference for CO, of about 6.5 ppb, for which the cause could not be fully explained at the moment. From more than three years of data, the main features at Bialystok have been characterized in terms of variability, trends, and seasonal and diurnal variations. CO2 and O2/N2 show large short term variability, and large diurnal signals during the warm seasons, which attenuate with the increase of sampling height. The trends calculated from this dataset, over the period August 2005 to December 2008, are 2.02±0.46 ppm/year for CO2 and −23.2±2.5 per meg/year for O2/N2. CH4, CO and N2O show also higher variability at the lower sampling levels, which in the case of CO is strongly seasonal. Diurnal variations in CH4, CO and N2O mole fractions can be observed during the warm season, due to the periodicity of vertical mixing combined with the diurnal cycle of anthropogenic emissions. We calculated increase rates of 10.1±4.4 ppb/year for CH4, (−8.3)±5.3 ppb/year for CO and 0.67±0.08 ppb/year for N2O. SF6 shows only few events, and generally no vertical gradients, which suggests that there are no significant local sources. A weak SF6 seasonal cycle has been detected, which most probably is due to the seasonality of atmospheric circulation. SF6 increased during the time of our measurement at an average rate of 0.29±0.01 ppt/year.