ALBERT

Description: We interpret here the variability of levels of carbonaceous aerosols based on a 12 yr database from 78 monitoring stations across Spain specially compiled for this article. Data did not evidence any spatial trends of carbonaceous aerosols across the country. Conversely, results show marked differences in average concentrations from the cleanest, most remote sites (around 1 μg m−3 of non-mineral carbon (nmC), mostly made of organic carbon (OC) with very little elemental carbon (EC), around 0.1 μg m−3; OC / EC = 12–15), to the highly polluted major cities (8–10 μg m−3 of nmC; 3–4 μg m−3 of EC; 4–5 μg m−3 of OC; OC / EC = 1–2). Thus, urban (and very specific industrial) pollution was found to markedly increase levels of carbonaceous aerosols in Spain, with much lower impact of biomass burning and of biogenic emissions. Correlations between yearly averaged OC / EC and EC concentrations adjust very well to a potential equation (OC = 3.37 EC0.326, R2 = 0.8). A similar equation is obtained when including average concentrations obtained at other European sites (OC = 3.60EC0.491, R2 = 0.7). A clear seasonal variability in OC and EC concentrations was detected. Both OC and EC concentrations were higher during winter at the traffic and urban sites, but OC increased during the warmer months at the rural sites. Hourly equivalent black carbon (EBC) concentrations at urban sites accurately depict road traffic contributions, varying with distance from road, traffic volume and density, mixing-layer height and wind speed. Weekday urban rush-hour EBC peaks are mimicked by concentrations of primary gaseous emissions from road traffic, whereas a single midday peak is characteristic of remote and rural sites. Decreasing annual trends for carbonaceous aerosols were observed between 1999 and 2011 at a large number of stations, probably reflecting the impact of the EURO4 and EURO5 standards in reducing the diesel PM emissions. This has resulted in some cases in an increasing trend for NO2 / (OC + EC) ratios as these standards have been much less effective for the abatement of NOx exhaust emissions in passenger diesel cars. This study concludes that EC, EBC, and especially nmC and OC + EC are very good candidates for new air quality standards since they cover both emission impact and health-related issues.

Description: Living organisms respond both to current and previous environments, which can have important consequences on population dynamics. However, there is little experimental evidence based on long-term field studies of the effects of previous environments on the performance of individuals. We tested the hypothesis that trees that establish under different environmental conditions perform differently under similar post-establishment conditions. We used the slow-growing, evergreen Mediterranean oak Quercus ilex subsp. rotundifolia as target species. We analyzed the effects of previous environments, competition effects and tradeoffs among life-history traits (survival, growth, and reproduction). We enhanced seedling establishment for three years by reducing abiotic environmental harshness by means of summer irrigation and artificial shading in 12 experimental plots, while four plots remained as controls. Then these treatments were interrupted for ten years. Seedlings under ameliorated environmental conditions survived and grew faster during early establishment. During the post-management period, previous treatments 1) did not have any effect on survival, 2) experienced a slower above-ground growth, 3) decreased root biomass as indicated from reflectivity of Ground Penetration Radar, 4) increased acorn production mostly through a greater canopy volume and 5) increased acorn production effort. The trees exhibited a combination of effects related to acclimation for coping with abiotic stress and effects of intra-specific competition. In accordance with our hypothesis, tree performance overall depended on previous environmental conditions, and the response was different for different life-history traits. We recommend early management because it increased plot cover, shortened the time to attain sexual maturity and increased the amount of acorn production. Plots such as those assessed in this study may act as sources of propagules in deforested agricultural landscapes thus aiding natural establishment of new plants.

Description: We interpret here the variability of levels of carbonaceous aerosols based on a 12-yr database from 78 monitoring stations across Spain especially compiled for this article. Data did not evidence any spatial trends of carbonaceous aerosols across the country. Conversely, results show marked differences in average concentrations from the cleanest, most remote sites (around 1 μg m−3 of non-mineral carbon (nmC), mostly made of organic carbon (OC), with very little elemental carbon (EC) 0.1 μg m−3; OC/EC = 12–15), to the highly polluted major cities (8–10 μg m−3 of nmC; 3–4 μg m−3 of EC; 4–5 μg m−3 of OC; OC/EC = 1–2). Thus, urban (and very specific industrial) pollution was found to markedly increase levels of carbonaceous aerosols in Spain, with much lower impact of biomass burning. Correlations between yearly averaged OC/EC and EC concentrations adjust very well to a potential equation (OC/EC = 3.37 EC−0.67 R2 = 0.94). A similar equation is obtained when including average concentrations obtained at other European sites (y = 3.61x−0.5, R2 = 0.78). A clear seasonal variability in OC and EC concentrations was detected. Both OC and EC concentrations were higher during winter at the traffic and urban sites, but OC increased during the warmer months at the rural sites. Hourly equivalent black carbon (EBC) concentrations at urban sites accurately depict road traffic contributions, varying with distance to road, traffic volume and density, mixing layer height and wind speed. Weekday urban rush-hour EBC peaks are mimicked by concentrations of primary gaseous emissions from road traffic, whereas a single midday peak is characteristic of remote and rural sites. Decreasing annual trends for carbonaceous aerosols were observed between 1999 and 2011 at a large number of stations, probably reflecting the impact of the EURO4 and EURO5 standards in reducing the diesel PM emissions. This has resulted in some cases in an increasing trend of NO2/OC+EC ratios, because these standards have been much less effective for the abatement of NOx exhaust emissions in passenger diesel cars. This study concludes that EC, EBC, and especially nmC and OC+EC are very good candidates for new air quality standards since they cover both emission impact and health related issues.

Description: The occurrence of African dust outbreaks over the western Mediterranean basin were identified on an 11 year period (2001–2011). PM10 daily data from nine regional background air quality monitoring sites across the study area were compiled and the net dust load transported during each event was estimated. Then, the main atmospheric circulation patterns causing the transport of African air masses, were characterized by mean of an objective classification methodology of atmospheric variables fields. Next, the potential source areas of mineral dust, associated to each circulation pattern were identified by trajectory statistical methods. Finally, an impact index was calculated to estimate the incidence of the African dust outbreaks produced during each circulation pattern, on the levels of dust load in PM10 concentrations recorded in the different regions. Our results indicate that the values of the impact index and the areas affected by African dust, strongly depended on the atmospheric circulation pattern. Four circulation types were obtained by the classification procedure. Two of them (CT-1 and CT-4) occurred predominantly during the warm season, bringing dust from areas of Algeria, Tunisia, Western Sahara, western Libya and Mauritania. African dust outbreaks produced during the CT-4 were the most frequent across the period of study, generating the highest impact index over southern, central and eastern regions of the Iberian Peninsula as well as over the Balearic Islands. Conversely, the events caused by the CT-1 encompassed the highest impact index over the western areas of the Iberian Peninsula. The two remaining circulation types (CT-2 and CT-3) were more frequently observed during the spring season. The prevailing flows generated by these two atmospheric circulation patterns, carried mineral dust from areas of Algeria, Tunisia and Western Sahara, giving rise to higher values of the impact index from eastern to western areas of the western Mediterranean basin.

Description: The occurrence of African dust outbreaks over different areas of the western Mediterranean Basin were identified on an 11-year period (2001–2011). The main atmospheric circulation patterns causing the transport of African air masses were characterized by means of an objective classification methodology of atmospheric variable fields. Next, the potential source areas of mineral dust, associated to each circulation pattern were identified by trajectory statistical methods. Finally, an impact index was calculated to estimate the incidence of the African dust outbreaks produced during each circulation pattern, in the areas of study. Four circulation types were obtained (I–IV) and three main potential source areas of African dust were identified (Western Sahara and Morocco; Algeria; northeastern Algeria and Tunisia). The circulation pattern I (24% of the total number of episodic days) produced the transport of dust mainly in summer from Western Sahara, southern Morocco and Tunisia. The circulation pattern IV (33%) brings dust mainly from areas of northern and southern Algeria in summer and autumn, respectively. The circulation pattern II (31%) favored the transport of dust predominantly from northern Algeria, both in spring and summer. Finally, the circulation type III was the less frequently observed (12%). It occurred mainly in spring and with less intensity in winter, carrying dust from Western Sahara and southern Morocco. Our findings point out that the most intense episodes over the western Mediterranean Basin were produced in the summer period by the circulation type I (over the western side of the Iberian Peninsula) and the circulation type IV (over the central and eastern sides of the Iberian Peninsula and the Balearic Islands).