ALBERT

Description: New scanning electron microscope observations of unadulterated calcareous nannofossil assemblages on lamina surfaces of Cretaceous Tanzania Drilling Project sediments reveal high diversity in the 〈3 μm size-range and high abundances of small and frangible morphologies. These assemblages prompt comparison to modern assemblages, which show similar high diversity and abundance of very small and fragile taxa, although these assemblages are generally not preserved in the fossil record due to taphonomic filtering. Not only are there broad similarities between the general composition of modern assemblages and those of the Tanzanian lagerstätte, but also our discovery of several new Cretaceous taxa provides evidence for greatly extended fossil lineages of extant orders, with implications for both deep-time biodiversity divergence and survival through the end-Cretaceous mass extinction. Our findings include: new species that are the first-recorded Mesozoic representatives of the extant Syracosphaeraceae and Papposphaeraceae; potentially previously unrecorded diversity in the Mesozoic Calciosoleniaceae, another extant order, represented by extant species that have been described already; and new species and unusually high abundances of the Mesozoic Stephanolithiaceae. We also highlight the extended range of an incertae sedis Cenozoic genus, Ellipsolithus, into at least the Turonian.

Description: Quantifying the potential exposure of property to damages associated with storm surges, extreme weather and hurricanes is fundamental to developing frameworks that can be used to conceive and implement mitigation plans as well as support urban development that accounts for such events. In this study, we aim at quantifying the total value and area of properties exposed to the flooding associated with Hurricane Florence that occurred in September 2018. To this aim, we implement an approach for the identification of affected areas by generating a map of the maximum flood extent obtained from a combination of the flood extent produced by the Federal Emergency Management Agency's (FEMA's) water marks with those obtained from spaceborne radar remote-sensing data. The use of radar in the creation of the flood extent allows for those properties commonly missed by FEMA's interpolation methods, especially from pluvial or non-fluvial sources, and can be used in more accurately estimating the exposure and market value of properties to event-specific flooding. Lastly, we study and quantify how the urban development over the past decades in the regions flooded by Hurricane Florence might have impacted the exposure of properties to present-day storms and floods. This approach is conceptually similar to what experts are addressing as the “expanding bull's eye effect”, in which “targets” of geophysical hazards, such as people and their built environments, enlarge as populations grow and spread. Our results indicate that the total value of property exposed to flooding during Hurricane Florence was USD 52 billion (in 2018 USD), with this value increasing from USD ∼10 billion at the beginning of the past century to the final amount based on the expansion of the number of properties exposed. We also found that, despite the decrease in the number of properties built during the decade before Florence, much of the new construction was in proximity to permanent water bodies, hence increasing exposure to flooding. Ultimately, the results of this paper provide a new tool for shedding light on the relationships between urban development in coastal areas and the flooding of those areas, which is estimated to increase in view of projected increasing sea level rise, storm surges and the strength of storms.

Description: Ammonium salts such as ammonium nitrate and ammonium sulfate constitute an important fraction of the total fine particulate matter (PM2.5) mass. While the conversion of inorganic gases into particulate-phase sulfate, nitrate, and ammonium is now well understood, there is considerable uncertainty over interactions between gas-phase ammonia and secondary organic aerosols (SOAs). Observations have confirmed that ammonia can react with carbonyl compounds in SOA, forming nitrogen-containing organic compounds (NOCs). This chemistry consumes gas-phase NH3 and may therefore affect the amount of ammonium nitrate and ammonium sulfate in particulate matter (PM) as well as particle acidity. In order to investigate the importance of such reactions, a first-order loss rate for ammonia onto SOA was implemented into the Community Multiscale Air Quality (CMAQ) model based on the ammonia uptake coefficients reported in the literature. Simulations over the continental US were performed for the winter and summer of 2011 with a range of uptake coefficients (10−3–10−5). Simulation results indicate that a significant reduction in gas-phase ammonia may be possible due to its uptake onto SOA; domain-averaged ammonia concentrations decrease by 31.3 % in the winter and 67.0 % in the summer with the highest uptake coefficient (10−3). As a result, the concentration of particulate matter is also significantly affected, with a distinct spatial pattern over different seasons. PM concentrations decreased during the winter, largely due to the reduction in ammonium nitrate concentrations. On the other hand, PM concentrations increased during the summer due to increased biogenic SOA (BIOSOA) production resulting from enhanced acid-catalyzed uptake of isoprene-derived epoxides. Since ammonia emissions are expected to increase in the future, it is important to include NH3 + SOA chemistry in air quality models.

Description: Indole is a heterocyclic compound emitted by various plant species under stressed conditions or during flowering events. The formation, optical properties, and chemical composition of secondary organic aerosol (SOA) formed by low-NOx photooxidation of indole were investigated. The SOA yield (1. 3 ± 0. 3) was estimated from measuring the particle mass concentration with a scanning mobility particle sizer (SMPS) and correcting it for wall loss effects. The high value of the SOA mass yield suggests that most oxidized indole products eventually end up in the particle phase. The SOA particles were collected on filters and analysed offline with UV–vis spectrophotometry to measure the mass absorption coefficient (MAC) of the bulk sample. The samples were visibly brown and had MAC values of  ∼ 2 m2 g−1 at λ = 300 nm and  ∼ 0. 5 m2 g−1 at λ = 400 nm, comparable to strongly absorbing brown carbon emitted from biomass burning. The chemical composition of SOA was examined with several mass spectrometry methods. Direct analysis in real-time mass spectrometry (DART-MS) and nanospray desorption electrospray high-resolution mass spectrometry (nano-DESI-HRMS) were both used to provide information about the overall distribution of SOA compounds. High-performance liquid chromatography, coupled to photodiode array spectrophotometry and high-resolution mass spectrometry (HPLC-PDA-HRMS), was used to identify chromophoric compounds that are responsible for the brown colour of SOA. Indole derivatives, such as tryptanthrin, indirubin, indigo dye, and indoxyl red, were found to contribute significantly to the visible absorption spectrum of indole SOA. The potential effect of indole SOA on air quality was explored with an airshed model, which found elevated concentrations of indole SOA during the afternoon hours contributing considerably to the total organic aerosol under selected scenarios. Because of its high MAC values, indole SOA can contribute to decreased visibility and poor air quality.

Description: An unusual new coccolithophore species is described from the deep photic zone. The species is dimorphic with small body coccoliths bearing short spines and larger spine-coccoliths with exceptionally long, hollow, quadrate spines. The species is rare but has been observed in the Pacific, Indian and Atlantic Oceans reinforcing other evidence that the deep photic zone nannoflora is more diverse and heterogeneous than previously assumed.The species also shows remarkable morphological similarity to some species of the non-calcifying haptophyte Chysochromulina of a type which has frequently been cited as evidence for possible multiple origins of calcification in haptophytes. However, the coccolith structure strongly indicates that the species is a member of the Papposphaeraceae. Available phylogenetic data from molecular genetics and biomineralization modes make it extremely unlikely that the Papposphaeraceae are closely related to the spine-bearing Chrysochromulina species and so the striking morphological similarity is almost certainly a case of homoeomorphy, and possibly functional convergence.

Description: Changes in morphology within the biostratigraphically important Oligocene nannofossil lineage, Sphenolithus predistentus, S. distentus and S. ciperoensis were investigated in carbonate sediments from the palaeo-equatorial Pacific Ocean Site 1218 in order to determine the nature of this evolutionary lineage. Using differences in their morphology and stratigraphical ranges, the aim of this study was to determine whether these taxa represent an anagenetic evolutionary lineage or a set of discrete species with overlapping stratigraphical ranges. A total of 1215 specimens from 12 samples were analysed morphometrically and the basal ratio, i.e. the ratio between the basal width and proximal cycle height, was identified as a key parameter for the study of this lineage. We conclude that S. distentus and S. predistentus are intergradational species forming an anagenetic lineage but that S. ciperoensis is a discrete species which evolved relatively abruptly in the Late Oligocene.

Description: A very distinctive new deep-photic coccolithophore is described from the NE Indian Ocean. The new species is trimorphic with: 200–300 body coccoliths bearing low spines attached by narrow stems to a basal narrow-rimmed placolith structure; up to 18 circum-flagellar coccoliths with tall sail-like spines; and up to 22 coccoliths with moderately elevated spines occurring both around the circum-flagellar coccoliths and antapically. These features make the coccolithophore unique and require placement in a new species and genus. The basal structure, however, shows similarities to a recently recognized group of narrow-rimmed placoliths. Hence, the new coccolithophore provides some support for this grouping as a significant addition to our understanding of coccolithophore biodiversity, and potentially an explanation for a set of anomalous molecular genetic results. In addition the new taxon provides further evidence that the deep-photic coccolithophore community is more diverse than has been assumed.

Description: A systematic study on the evolution and stratigraphic distribution of the species of Catinaster from several DSDP/ODP sites with magnetostratigraphic records is presented. The evolution of Catinaster from Discoaster is established by documentation of a transitional nannofossil species, Discoaster transitus. Two new subspecies, Catinaster coalitus extensus and Catinaster calyculus rectus are defined which appear to be intermediates in the evolution of Catinaster coalitus coalitus to Catinaster calyculus calyculus. The first occurrence of C. coalitus is shown to be in the lower part of C5n.2n at 10.7–10.9 Ma in the low to mid–latitude Atlantic and Pacific Oceans. The last occurrence of C. coalitus coalitus varies from the upper part of C5n.2n to the lower portion of C4A. Magnetobiostratigraphic evidence suggests that the FO of C. calyculus rectus is diachronous. Catinaster mexicanus occurs in the late Miocene and has been found only in the eastern equatorial Pacific, the Indian Ocean and the Gulf of Mexico.

Description: INTRODUCTIONBy far the most widely available computer programs for recording, manipulating, and displaying numerical data are spreadsheets, such as Microsoft Excel™ and Lotus 1-2-3™. These are powerful and flexible tools and for most workers this is an obvious way of recording micropalaeontological data. However, they have been primarily produced for business users and have limited abilities when it comes to plotting scientific graphs. This note describes some indirect but rapid methods, for using the standard graphing tools in such packages, to produce additional types of graphs of value to micropalaeontologists.STACKED HISTOGRAM CHARTSFigure 1 is a stacked histogram chart, produced in Microsoft Excel™. This type of diagram is useful, for instance, in displaying variations in size of a species between samples through a section. Stacked histogram charts are not directly supported by any spreadsheets that I have seen. As a result, they can usually only be produced by rather inefficient techniques. For example, making a separate chart for each sample and then combining them in a graphics program. The indirect approach used here is to separate each true data series with a mirror image padding data series, which is not displayed. The entire diagram is then plotted as a single chart. The steps for doing this are:(1) Enter the data (specimens per size class) in a spreadsheet (samples v. size classes).(2) Between each pair of data columns insert a column with equations which will calculate mirror image padding data. These will have the form C3 = . . .