ALBERT

Description: The frequency and intensity of extreme hydrological events in Alpine regions is projected to increase with climate change. The goal of this study is to better understand the functioning of aquifers composed of complex alluvial and rockfall deposits in Alpine valleys and to quantify the role of these natural storage spaces in flood attenuation and baseflow maintenance. Geomorphological and hydrogeological mapping, tracer tests, and continuous flow measurements were conducted in the Reintal (German Alps), where runoff from a karst spring infiltrates a series of postglacial alluvial/rockfall aquifers. During high-flow conditions, groundwater velocities of 30 m h−1 were determined along 500 m; hydrograph analyses revealed short lag times (5 h) between discharge peaks upstream and downstream from the aquifer series; the maximum discharge ratio downstream (22) and the peak recession coefficient (0.196 d−1) are low compared with other Alpine catchments. During low-flow conditions, the underground flow path length increased to 2 km and groundwater velocities decreased to 13 m h−1. Downstream hydrographs revealed a delayed discharge response after 101 h and peaks damped by a factor of 1.5. These results indicate that alluvial/rockfall aquifers might play an important role in the flow regime and attenuation of floods in Alpine regions.

Description: Nitrate (NO3−) contamination of groundwater associated with agronomic activity is of major concern in many countries. Where agriculture, thin free draining soils and karst aquifers coincide, groundwater is highly vulnerable to nitrate contamination. As residence times and denitrification potential in such systems are typically low, nitrate can discharge to surface waters unabated. However, such systems also react quickest to agricultural management changes that aim to improve water quality. In response to storm events, nitrate concentrations can alter significantly, i.e. rapidly decreasing or increasing concentrations. The current study examines the response of a specific karst spring situated on a grassland farm in South Ireland to rainfall events utilising high-resolution nitrate and discharge data together with on-farm borehole groundwater fluctuation data. Specifically, the objectives of the study are to formulate a scientific hypothesis of possible scenarios relating to nitrate responses during storm events, and to verify this hypothesis using additional case studies from the literature. This elucidates the controlling key factors that lead to mobilisation and/or dilution of nitrate concentrations during storm events. These were land use, hydrological condition and karstification, which in combination can lead to differential responses of mobilised and/or diluted nitrate concentrations. Furthermore, the results indicate that nitrate response in karst is strongly dependent on nutrient source, whether mobilisation and/or dilution occur and on the pathway taken. This will have consequences for the delivery of nitrate to a surface water receptor. The current study improves our understanding of nitrate responses in karst systems and therefore can guide environmental modellers, policy makers and drinking water managers with respect to the regulations of the European Union (EU) Water Framework Directive (WFD). In future, more research should focus on the high-resolution monitoring of karst aquifers to capture the high variability of hydrochemical processes, which occur at time intervals of hours to days.

Description: Artificial tracers are powerful tools for investigating karst systems. Tracers are commonly injected into sinking streams or dolines, while springs serve as monitoring sites. The obtained flow and transport parameters represent mixed information from the vadose, epiphreatic and phreatic zones (that is, the aquifer remains a black box). Accessible active caves constitute valuable but underexploited natural laboratories to gain detailed insights into the hydrologic functioning of the aquifer. Two multi-tracer tests in the catchment of a major karst spring (Blautopf, Germany) with injections and monitoring in two associated water caves aimed at obtaining spatially and temporally resolved information on groundwater flow in different compartments of the system. Two tracers were injected into the caves to characterize the hydraulic connections between them and with the spring. Two injections at the land surface, far from the spring, aimed at resolving the aquifer's internal drainage structure. Tracer breakthrough curves were monitored by field fluorimeters in caves and at the spring. Results demonstrate the dendritic drainage structure of the aquifer. It was possible to obtain relevant flow and transport parameters for different sections of this system. The highest mean flow velocities (275 m h−1) were observed in the near-spring epiphreatic section (open-channel flow), while velocities in the phreatic zone (pressurized flow) were one order of magnitude lower. Determined conduit water volumes confirm results of water balances and hydrograph analyses. In conclusion, experiments and monitoring in caves can deliver spatially resolved information on karst aquifer heterogeneity and dynamics that cannot be obtained by traditional investigative methods.

Description: Two different in situ spectrophotometers are compared that were used in the field to determine nitrate-nitrogen (NO3-N) concentrations at two distinct spring discharge sites. One sensor was a double wavelength spectrophotometer (DWS) and the other a multiple wavelength spectrophotometer (MWS). The objective of the study was to review the hardware options, determine ease of calibration, accuracy, influence of additional substances and to assess positive and negative aspects of the two sensors as well as troubleshooting and trade-offs. Both sensors are sufficient to monitor highly time-resolved NO3-N concentrations in emergent groundwater. However, the chosen path length of the sensors had a significant influence on the sensitivity and the range of detectable NO3-N. The accuracy of the calculated NO3-N concentrations of the sensors can be affected if the content of additional substances such as turbidity, organic matter, nitrite or hydrogen carbonate significantly varies after the sensors have been calibrated to a particular water matrix. The MWS offers more possibilities for calibration and error detection but requires more expertise compared with the DWS.

Description: Artificial tracers are powerful tools to investigate karst systems. Tracers are commonly injected into sinking streams or dolines, while springs serve as monitoring sites. The obtained flow and transport parameters represent mixed information from the vadose, epiphreatic and phreatic zones, i.e., the aquifer remains a black box. Accessible active caves constitute valuable but underexploited natural laboratories to gain detailed insights into the hydrologic functioning of the aquifer. Two multi-tracer tests in the catchment of a major karst spring (Blautopf, Germany) with injections and monitoring in two associated water caves aimed at obtaining spatially and temporally resolved information on groundwater flow in different compartments of the system. Two tracers were injected in the caves to characterize the hydraulic connections between them and with the spring. Two injections at the land surface, far from the spring, aimed at resolving the aquifer's internal drainage structure. Tracer breakthrough curves were monitored by field fluorimeters in caves and at the spring. Results demonstrate the dendritic drainage structure of the aquifer. It was possible to obtain relevant flow and transport parameters for different sections of this system. The highest mean flow velocities (275 m h−1) were observed in the near-spring epiphreatic section (open-channel flow), while velocities in the phreatic zone (pressurized flow) were one order of magnitude lower. Determined conduit water volumes confirm results of water balances and hydrograph analyses. In conclusion, experiments and monitoring in caves can deliver spatially resolved information on karst aquifer heterogeneity and dynamics that cannot be obtained by traditional investigative methods.

Description: Nitrate (NO3-) contamination of groundwater associated with agronomic activity is of major concern in many countries. Where agriculture, thin free draining soils and karst aquifers coincide, groundwater is highly vulnerable to nitrate contamination. As residence times and denitrification potential in such systems are typically low, nitrate can discharge to surface waters unabated. However, such systems also react quickest to agricultural management changes that aim to improve water quality. In response to storm events, nitrate concentrations can alter significantly, i.e., rapidly decreasing or increasing concentrations. The current study examines the response of a specific karst spring situated on a grassland farm in south Ireland to rainfall events utilising high-resolution nitrate and discharge data together with on-farm borehole groundwater fluctuation data. Specifically, the objectives of the study are to formulate a scientific hypothesis of possible scenarios relating to nitrate responses during storm events, and to verify this hypothesis using additional case studies from the literature. This elucidates the controlling key factors that lead to mobilisation and/or dilution of nitrate concentrations during storm events. These were land use, hydrological condition and karstification, which in combination can lead to differential responses of mobilised and/or diluted nitrate concentrations. Furthermore, the results indicate that nitrate response in karst is strongly dependent on nutrient source, whether mobilisation and/or dilution occur and the pathway taken. This will have consequences for the delivery of nitrate to a surface water receptor. The current study improves our understanding of nitrate responses in karst systems and therefore can guide environmental modellers, policy makers and drinking water managers with respect to the regulations of the European Union (EU) Water Framework Directive (WFD). In future, more research should focus on high resolution monitoring of karst aquifers to capture the high variability of hydrochemical processes, which occur at time intervals of hours to days.

Description: Two different in-situ spectrophotometers are compared that were used in the field to determine nitrate-nitrogen (NO3-N) concentrations at two distinct spring discharge sites. One sensor was a double wavelength spectrophotometer (DWS) and the other a multiple wavelength spectrophotometer (MWS). The objective of the study was to review the hardware options, determine ease of calibration, accuracy, influence of additional substances and to assess positive and negative aspects of the two sensors as well as troubleshooting and trade-offs. Both sensors are sufficient to monitor highly time-resolved NO3-N concentrations in emergent groundwater. However, the chosen path length of the sensors had a significant influence on the sensitivity and the range of detectable NO3-N. The accuracy of the calculated NO3-N concentrations of the sensors can be affected, if the content of additional substances such as turbidity, organic matter, nitrite or hydrogen carbonate significantly varies after the sensors have been calibrated to a particular water matrix. The MWS offers more possibilities for calibration and error detection, but requires more expertise compared with the DWS.

Description: The frequency and intensity of extreme hydrological events in alpine regions is projected to increase with climate change. The goal of this study was to better understand the functioning of aquifers composed of complex alluvial and rockfall deposits in alpine valleys and to quantify the role of these natural storage spaces in flood attenuation and baseflow maintenance. Geomorphological and hydrogeological mapping, tracer tests, and continuous flow measurements were conducted in the Reintal valley (German Alps), where runoff from a karst spring infiltrates into a series of postglacial alluvial/rockfall aquifers. During high-flow conditions, groundwater velocities of 30 m h−1 were determined along 500 m; hydrograph analyses revealed short lag times (5 h) between discharge peaks upstream and downstream from the aquifer series; the maximum discharge ratio downstream (22) and the peak recession coefficient (0.196 d−1) are low compared with other alpine catchments. During low-flow conditions, the underground flow path length increased to 2 km and groundwater velocities decreased to 13 m h−1. Downstream hydrographs revealed a delayed discharge response after 101 h and peaks dampened by a factor of 1.5. These results indicate that alluvial/rockfall aquifers might play an important role in the flow regime and attenuation of floods in alpine regions.

Description: Karst aquifers are difficult to manage due to their unique hydrogeological characteristics. Future climate projections suggest a strong change in temperature and precipitation regimes in European karst regions over the next decades. Alpine karst systems can be especially vulnerable under changing hydro-meteorological conditions since snowmelt in mountainous environments is an important controlling process for aquifer recharge and is highly sensitive to varying climatic conditions. Our paper presents the first study to investigate potential impacts of climate change on mountainous karst systems by using a combined lumped and distributed modeling approach with consideration of subsurface karst drainage structures. The study site is characterized by high-permeability (karstified) limestone formations and low-permeability (non-karst) sedimentary Flysch. The model simulation under current conditions demonstrates that a large proportion of precipitation infiltrates into the karst aquifer as autogenic recharge. Moreover, the result shows that surface snow storage is dominant from November to April, while subsurface water storage in the karst aquifer dominates from May to October. The climate scenario runs demonstrate that varied climate conditions significantly affect the spatiotemporal distribution of water fluxes and storages: (1) the total catchment discharge decreases under all evaluated future climate conditions. (2) The spatiotemporal discharge pattern is strongly controlled by temperature variations, which can shift the seasonal snowmelt pattern, with snow storage in the cold season (December to April) decreasing significantly under all change scenarios. (3) Increased karst aquifer recharge in winter and spring, and decreased recharge in summer and autumn, partly offset each other. (4) Impacts on the karst springs are distinct; the lowest permanent spring presents a “robust” discharge behavior, while the highest overflow outlet is highly sensitive to changing climate. This analysis effectively demonstrates that the impacts on subsurface flow dynamics are regulated by the characteristic dual flow and spatially heterogeneous distributed drainage structure of the karst aquifer. Overall, our study highlights the fast groundwater dynamics in mountainous karst catchments, which make them highly vulnerable to future changing climate conditions. Additionally, this work presents a novel holistic modeling approach, which can be transferred to similar karst systems for studying the impact of climate change on local karst water resources with consideration of their individual hydrogeological complexity and hydraulic heterogeneity.

Description: Climate change projections indicate significant changes to precipitation and temperature regimes in European karst regions. Alpine karst systems can be especially vulnerable under changing hydro-meteorological conditions since snowmelt in mountainous environments is an important controlling process for aquifer recharge, and is highly sensitive to varying climatic conditions. The current study presents an investigation of present and future water fluxes and storages at an Alpine karst catchment using a distributed numerical model. A delta approach combined with random sampling was used to assess the potential impacts of climate changes. The study site is characterized by high permeability (karstified) limestone formations and low permeability (non-karst) sedimentary flysch. The model simulation under current conditions demonstrates that a large proportion of precipitation infiltrates into the karst aquifer as autogenic recharge. Surface runoff in the adjacent non-karst areas partly infiltrates into the karst aquifer as allogenic point recharge. Moreover, the result shows that surface snow storage is dominant from November to April, while subsurface water storage in the karst aquifer dominates from May to October. The climate scenario runs demonstrate that varied climate conditions significantly affect the spatiotemporal distribution of water fluxes and storages: (1) the total catchment discharge decreases under all evaluated future climate conditions. (2) The spatiotemporal discharge pattern is strongly controlled by temperature variations, which can shift the seasonal snowmelt pattern, with snow storage in the cold season (December to April) decreasing significantly under all change scenarios. (3) Increased karst aquifer recharge in winter and spring, and decreased recharge in summer and autumn, partly offset each other. (4) Impacts on the karst springs are distinct; the permanent spring presents a robust discharge behavior, while the estavelle is highly sensitive to changing climate. This analysis effectively demonstrates that the impacts on subsurface flow dynamics are regulated by the characteristic dual flow and spatially heterogeneous distributed drainage structure of the karst aquifer. Overall, our study suggests that bespoke hydrological models tailored to the specific subsurface characteristics of an Alpine karst catchment are needed to understand climate change impact.