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  • Articles  (30)
  • Copernicus  (17)
  • Wiley-Blackwell  (13)
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  • Articles  (30)
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  • 1
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    Copernicus
    In:  EPIC3Earth System Science Data Discussions https://doi.org/10.5194/essd-2019-66, Copernicus, pp. 1-39
    Publication Date: 2019-05-02
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , notRev
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  • 2
    Publication Date: 2020-08-10
    Description: The Global Ocean Data Analysis Project (GLODAP) is a synthesis effort providing regular compilations of surface to bottom ocean biogeochemical data, with an emphasis on seawater inorganic carbon chemistry and related variables determined through chemical analysis of water samples. GLODAPv2.2020 is an update of the previous version, GLODAPv2.2019. The major changes are: data from 106 more cruises added, extension of time coverage until 2019, and the inclusion of available discrete fugacity of CO2 (fCO2) values in the merged product files. GLODAPv2.2020 includes measurements from more than 1.2 million water samples from the global oceans collected on 946 cruises. The data for the 12 GLODAP core variables (salinity, oxygen, nitrate, silicate, phosphate, dissolved inorganic carbon, total alkalinity, pH, CFC-11, CFC-12, CFC-113, and CCl4) have undergone extensive quality control, especially systematic evaluation of bias. The data are available in two formats: (i) as submitted by the data originator but updated to WOCE exchange format and (ii) as a merged data product with adjustments applied to minimize bias. These adjustments were derived by comparing the data from the 106 new cruises with the data from the 840 quality-controlled cruises of the GLODAPv2.2019 data product. They correct for errors related to measurement, calibration, and data handling practices, while taking into account any known or likely time trends or variations in the variables evaluated. The compiled and adjusted data product is believed to be consistent to better than 0.005 in salinity, 1 % in oxygen, 2 % in nitrate, 2 % in silicate, 2 % in phosphate, 4 μmol kg−1 in dissolved inorganic carbon, 4 μmol kg−1 in total alkalinity, 0.01–0.02, depending on region, in pH, and 5 % in the halogenated transient tracers. The other variables included in the compilation, such as isotopic tracers and discrete fCO2 were not subjected to bias comparison or adjustments. The original data, their documentation and doi codes are available at the Ocean Carbon Data System of NOAA NCEI (https://www.nodc.noaa.gov/ocads/oceans/GLODAPv2_2020/, last access: 22 June 2020). This site also provides access to the merged data product, which is provided as a single global file and as four regional ones – the Arctic, Atlantic, Indian, and Pacific oceans – under https://doi.org/10.25921/2c8h-sa89 (Olsen et al., 2020). The bias corrected product files also include significant ancillary and approximated data. These were obtained by interpolation of, or calculation from, measured data. This living data update documents the GLODAPv2.2020 methods and provides a broad overview of the secondary quality control procedures and results.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , notRev
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  • 3
    Publication Date: 2015-03-19
    Description: The Surface Ocean CO2 Atlas (SOCAT), an activity of the international marine carbon research community, provides access to synthesis and gridded fCO2 (fugacity of carbon dioxide) products for the surface oceans. Version 2 of SOCAT is an update of the previous release (version 1) with more data (increased from 6.3 million to 10.1 million surface water fCO2 values) and extended data coverage (from 1968–2007 to 1968–2011). The quality control criteria, while identical in both versions, have been applied more strictly in version 2 than in version 1. The SOCAT website (http://www.socat.info/) has links to quality control comments, metadata, individual data set files, and synthesis and gridded data products. Interactive online tools allow visitors to explore the richness of the data. Applications of SOCAT include process studies, quantification of the ocean carbon sink and its spatial, seasonal, year-to-year and longerterm variation, as well as initialisation or validation of ocean carbon models and coupled climate-carbon models.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 8 (1985), S. 69-72 
    ISSN: 0935-6304
    Keywords: Thin-layer chromatography, HPTLC ; Cellulose plates ; Tryptophan-NAD pathway ; Rat urine ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: High performance thin-layer chromatography (HPTLC) was used to determine 12 metabolites of the tryptophan-NAD pathway in rat urine. The method of separation described in the previous report was improved. The metabolites were separated on the cellulose plate by using five multiple developments with four solvent systems. The plate was scanned by the TLC scanner at 254 nm and the amounts of the metabolites were calculated by comparing peak areas of the scanning curves obtained for the urine sample and for the authentic standards. This procedure can be used as a semiquantitative determination method for the metabolites in biological fluids.
    Additional Material: 1 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Molecular Reproduction and Development 36 (1993), S. 236-237 
    ISSN: 1040-452X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology
    Additional Material: 3 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 4 (1993), S. 17-20 
    ISSN: 1042-7147
    Keywords: Poly(organophosphazene) ; Cobaltporphyrin ; Facilitated transport ; Oxygen-separating membrane ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Rubbery poly(organophosphazene)s were synthesized, and were combined with cobaltporphyrin (CoP) which binds molecular oxygen rapidly and reversibly. The apparent oxygen-binding equilibrium constant (Kapp) is in proportion to the physical solubility coefficient of oxygen in the polymer, although the reduced equilibrium and thermodynamic parameters are not dependent on the polymer matrix species. Diffusivity of oxygen via the fixed CoP(DC) is enhanced for poly(organophosphazene) membranes with a larger oxygen diffusion constant. Poly(organophosphazene) membranes with both a large Kapp and DC yield high oxygen permeability.
    Additional Material: 3 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 49 (1993), S. 1921-1929 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Four kinds of epoxy resins: cresol novolac, tris-hydroxyphenylmethane, tetramethylbiphenol, and bisphenol A, were cured with phenol novolac epoxy resins. Characteristics of these epoxy compounds were studied by the positron annihilation lifetime (PAL) technique. Glass transition temperatures, thermal expansion coefficients, and volume of intermolecularspace holes among polymer chains were obtained from the lifetime, τ3, of the long-lived component of ortho-positronium. It was revealed that, at the glass transition temperature, Tg, the volume of the hole created among polymer chains expanded 1.4 times the volume at room temperature. The smaller flexural modulus of tris-hydroxyphenylmethane than that of the other samples was explained by the volume of intermolecular-space holes obtained from τ3. Aging effects were seen in the data of the intensities, I3, of ortho-positronium, which became smaller after heating the samples above Tg. I3 and τ3 were strongly affected by the density of cross-linkings, and their chemical structures. The larger the density of cross-linkings, the smaller I3 and higher Tg were obtained. Epoxy compounds with the higher water-absorption rates had larger intermolecular-space holes. © 1993 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 24 (1979), S. 1701-1711 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Copolyamide-esters (CPAEs) were synthesized by the amide-ester interchange reaction. The change of intrinsic viscosity during CPAE synthesis was negligible. Polyamide blocks were shortened with increasing reaction time and polyester content. The polymerization degree of nylon 12 blocks on CPAE was smaller than that of nylon 6 blocks. CPAEs were hydrolyzed by Rhizopus delemar lipase. The biodegradability decreased with the shortening of the polyamide blocks and with increasing polyamide content. It was concluded that the amount and distribution of the hydrogen bonds, based on the amide group, in the CPAE chains strongly influenced their biodegradation by this lipase.
    Additional Material: 14 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 30 (1992), S. 517-525 
    ISSN: 0887-6266
    Keywords: positron annihilation in polyethylene, before and after irradiation ; polyethylene, positron annihilation in, effect of radiation on ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Positron lifetimes were measured for four kinds of polyethylene samples and were resolved into four components. The temperature dependence of the two longlived components was examined in detail. In agreement with other results, the longest lived component could be reasonably assigned to ortho-positronium located in amorphous regions. This component was shown to be sensitive to the defects in high-density polyethylene introducted in the course of its production. Both the intensity and the lifetime of the second longest lived component were structure insensitive, i.e., they did not change even on passing through the melting point. This component has been tentatively assigned to a positronium compound state. The effect of gamma-ray irradiation was also examined. Although the intensity (I4) of the longest lived component was reduced by the irradiation, correlation between I4 and the free radical concentration was poor, and the reduction in I4 caused by the irradiation is considered to be due to structure change and not to chemical reasons.
    Additional Material: 9 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 81 (1965), S. 223-233 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Der Einfluß des Druckes auf die Geschwindigkeit der strahleninduzierten Polymerisation festen Acrylamids wurde im Druckbereich von 1-5000 Atm. und bei Temperaturen von 28-70°C untersucht.Bei niedrigen Temperaturen wird die Polymerisationsgeschwindigkeit durch Druck erniedrigt, in der Nähe des Schmelzpunktes des Acrylamids jedoch erhöht.Weiter wurde gefunden, daß die Reaktionsgeschwindigkeit bei konstanter Temperatur im Anfangsstadium der Polymerisation durch Druck erniedrigt, später jedoch erhöht wird.Die Anzahl der erhaltenen Polymermoleküle wird durch den Druck nicht verändert; sie hängt nur von der Bestrahlungsdosis ab. Dieser Befund zeigt, daß der Druck die Initiierungsreaktion nur wenig, die Wachstumsreaktion aber stark beeinflußt.Die Wirkung des Druckes auf die Polymerisation des festen Acrylamids wird mit der Druckabhängigkeit der Aktivierungsenthalpie (ΔH
    Notes: The effect of pressure on the radiation-induced solid state polymerization of acrylamide has been studied in a pressure range of 1 to 5000 atm. over a temperature region of 28 to 70°C. Rates of polymerization and molecular weights have been measured.It was found that the rate of polymerization is suppressed by pressure at the lower temperatures; in the contrary, the rate is accelerated near the melting point.On the other hand, it was also found that the rate of polymerization is suppressed by pressure in an initial stage of polymerization, while it is accelerated in a later stage of polymerization at the same temperature.The number of polymer chains obtained is not affected by pressure; it depends on the irradiation dose only. These results indicate that the pressure has very little effect on the rate of initiation but that the propagation rate constant is profoundly affected by pressure.The effect of the pressure on the solid state polymerization of acrylamide is attributed to the pressure dependence on the activation enthalpy (ΔH
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