ALBERT

Description: In order to fabricate a thermoelectric device on glass substrate for harvesting waste heat energy through house appliances, the Seebeck coefficient of translucent TiO 2 thin film was investigated. The TiO 2 thin film was synthesized by using hydrothermal method with F-SnO 2 coated glass as substrate. From scanning electron microscopy analysis, the synthesized TiO 2 thin film was found to be in nanometer-scale rod structure with a thickness of 4 µm. The Seebeck coefficient was measured in the temperature range of 300 – 400 K. The Seebeck coefficient is found to be in negative value which shows that synthesized film is an n-type semiconductor material, and is lower than the value of bulk-size material. This reduction in Seebeck coefficient of TiO 2 thin film is likely due to the low dimensional effect and the difference of carrier concentration.

Description: Some dominant spatial and temporal structures of the North Pacific air-sea CO2 fluxes in response to the Pacific Decadal Oscillation (PDO) are identified in four data products from four independent sources: an assimilated CO2 flux product, two forward model solutions, and a gridded pCO2 dataset constructed with a neural network approach. The interannual variability of CO2 flux is found to be an order of magnitude weaker compared to the seasonal cycle of CO2 flux in the North Pacific. A statistical approach is employed to quantify the signal-to-noise ratio in the reconstructed dataset to delineate the representativity errors. The dominant variability with a signal-to-noise ratio above one is identified and its correlations with PDO are examined. A tentative four-box structure in the North Pacific air-sea CO2 flux variability linked to PDO emerges in which two positively correlated boxes are oriented in the northwest and southeast directions and contrarily, the negatively correlated boxes are oriented in the northeast and southwest directions. This pattern is verified with the CO2 and pCO2 from four products and its relations to the interannual El Niño-Southern Oscillation (ENSO) and lower-frequency PDO are separately identified. A combined EOF analysis between air-sea CO2 flux and key variables representing ocean-atmosphere interactions is carried out to elicit robust oscillations in the North Pacific CO2 flux in response to the PDO. The proposed spatial and temporal structures of the North Pacific CO2 fluxes are insightful since they separate the secular trends of the surface ocean carbon from the interannual variability. The regional characterization of the North Pacific in terms of PDO and CO2 flux variability is also instructive for determining the homogeneous oceanic domains for the Regional Carbon Cycle and Assessment Processes (RECCAP).

Description: Some dominant spatial and temporal structures of the North Pacific air-sea CO2 fluxes in response to the Pacific Decadal Oscillation (PDO) are identified in three data products from three independent sources: an assimilated CO2 flux product and two forward model solutions. The interannual variability of CO2 flux is found to be an order of magnitude weaker compared to the seasonal cycle of CO2 flux in the North Pacific. A statistical approach is employed to quantify the signal-to-noise ratio in the reconstructed dataset to delineate the representativity errors. The dominant variability with a signal-to-noise ratio above one is identified and its correlations with PDO are examined. A tentative four-pole pattern in the North Pacific air-sea CO2 flux variability linked to PDO emerges in which two positively correlated poles are oriented in the northwest and southeast directions and contrarily, the negatively correlated poles are oriented in the northeast and southwest directions. This pattern is identified in three products, providing CO2 and pCO2. Its relations to the interannual El Niño-Southern Oscillation (ENSO) and lower-frequency PDO are separately identified. A combined EOF analysis between air-sea CO2 flux and key variables representing ocean-atmosphere interactions is carried out to elicit robust oscillations in the North Pacific CO2 flux in response to the PDO. The proposed spatial and temporal structures of the North Pacific CO2 fluxes are insightful since they separate the secular trends of the surface ocean carbon from the interannual variability. The regional characterization of the North Pacific in terms of PDO and CO2 flux variability is also instructive for determining the homogeneous oceanic domains for the Regional Carbon Cycle and Assessment Processes (RECCAP).